Reconceptualising equilibrium in Boltzmannian statistical mechanics and characterising its existence

In Boltzmannian statistical mechanics macro-states supervene on micro-states. This leads to a partitioning of the state space of a system into regions of macroscopically indistinguishable micro-states. The largest of these regions is singled out as the equilibrium region of the system. What justifies this association? We review currently available answers to this question and find them wanting both for conceptual and for technical reasons. We propose a new conception of equilibrium and prove a mathematical theorem which establishes in full generality – i.e. without making any assumptions about the system׳s dynamics or the nature of the interactions between its components – that the equilibrium macro-region is the largest macro-region. We then turn to the question of the approach to equilibrium, of which there exists no satisfactory general answer so far. In our account, this question is replaced by the question when an equilibrium state exists. We prove another – again fully general – theorem providing necessary and sufficient conditions for the existence of an equilibrium state. This theorem changes the way in which the question of the approach to equilibrium should be discussed: rather than launching a search for a crucial factor (such as ergodicity or typicality), the focus should be on finding triplets of macro-variables, dynamical conditions, and effective state spaces that satisfy the conditions of the theorem.     

Oxygen equilibrium of human myoglobins (Mb I and Mb II)

Riassunto Dalla mioglobina umana cristallizzata sono stati isolati, a mezzo dell'elettroforesi su gel di amido, due componenti puri ed omogenei: Mb I e Mb II. Dei due componenti sono state determinate, in varie condizioni sperimentali, le curve di dissociazione per l'ossigeno.

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Aided by a grant from the Rockefeller Foundation.     

The utility of Naturalness,and how its application to Quantum Electrodynamics envisages the Standard Model and Higgs boson

With the Higgs boson discovery and no new physics found at the LHC, confidence in Naturalness as a guiding principle for particle physics is under increased pressure. We wait to see if it proves its mettle in the LHC upgrades ahead, and beyond. In the meantime, I present a justification a posteriori of the Naturalness criterion by suggesting that uncompromising application of the principle to Quantum Electrodynamics leads toward the Standard Model and Higgs boson without additional experimental input. Potential lessons for today and future theory building are commented upon.     

Reduction and emergence in the fractional quantum Hall state

We present the fractional quantum Hall (FQH) effect as a candidate emergent phenomenon. Unlike some other putative cases of condensed matter emergence (such as thermal phase transitions), the FQH effect is not based on symmetry breaking. Instead FQH states are part of a distinct class of ordered matter that is defined topologically. Topologically ordered states result from complex long-ranged correlations between their constituent parts, such that the system displays strongly irreducible, qualitatively novel properties.     

Localization and the interface between quantum mechanics, quantum field theory and quantum gravity II: The search of the interface between QFT and QG

The main topics of this second part of a two-part essay are some consequences of the phenomenon of vacuum polarization as the most important physical manifestation of modular localization. Besides philosophically unexpected consequences, it has led to a new constructive “outside-inwards approach” in which the pointlike fields and the compactly localized operator algebras which they generate only appear from intersecting much simpler algebras localized in noncompact wedge regions whose generators have extremely mild almost free field behavior.Another consequence of vacuum polarization presented in this essay is the localization entropy near a causal horizon which follows a logarithmically modified area law in which a dimensionless area (the area divided by the square of dR where dR is the thickness of a light-sheet) appears. There are arguments that this logarithmically modified area law corresponds to the volume law of the standard heat bath thermal behavior. We also explain the symmetry enhancing effect of holographic projections onto the causal horizon of a region and show that the resulting infinite dimensional symmetry groups contain the Bondi–Metzner–Sachs group. This essay is the second part of a partitioned longer paper.     

States of ignorance and ignorance of states: Examining the Quantum Principal Principle

Earman (2018) has recently argued that the Principal Principle, a principle of rationality connecting objective chance and credence, is a theorem of quantum probability theory. This paper critiques Earman's argument, while also offering a positive proposal for how to understand the status of the Principal Principle in quantum probability theory.     

在非线性系统中的微观粒子的特性和非线性量子力学理论(下)

在非线性系统中由于存在着与粒子状态相关的非线性相互作用，微观粒子的状态和特征相对于线性系统而发生了很大变化。原有的线性型的量子力学理论不能很好地描述这些微观粒子的状态和特征。至此，必然要发展新的理论。本文研究了微观粒子在非线性作用下的运动特性和本性的变化，说明了在线性作用和非线性场中微观粒子的性质是明显不同的，启示我们必须建立微观粒子在非线性场中运动的新理论。接着我们研究了与微观量子效应迥然不同的宏观量子效应与非线性作用的孤立子运动的紧密关系，结合现代孤立子理论和超导与超流理论，我们首先提出了非线性量子力学的基本原理及在此基础上建立了系统、完整的非线性量子力学理论体系，并得到的一些新结论。最后我们还论证了这个理论的正确性和自洽性，它的运用范围以及它的重大意义。     

Interpretation neutrality in the classical domain of quantum theory

I show explicitly how concerns about wave function collapse and ontology can be decoupled from the bulk of technical analysis necessary to recover localized, approximately Newtonian trajectories from quantum theory. In doing so, I demonstrate that the account of classical behavior provided by decoherence theory can be straightforwardly tailored to give accounts of classical behavior on multiple interpretations of quantum theory, including the Everett, de Broglie–Bohm and GRW interpretations. I further show that this interpretation-neutral, decoherence-based account conforms to a general view of inter-theoretic reduction in physics that I have elaborated elsewhere, which differs from the oversimplified picture that treats reduction as a matter of simply taking limits. This interpretation-neutral account rests on a general three-pronged strategy for reduction between quantum and classical theories that combines decoherence, an appropriate form of Ehrenfest׳s Theorem, and a decoherence-compatible mechanism for collapse. It also incorporates a novel argument as to why branch-relative trajectories should be approximately Newtonian, which is based on a little-discussed extension of Ehrenfest׳s Theorem to open systems, rather than on the more commonly cited but less germane closed-systems version. In the Conclusion, I briefly suggest how the strategy for quantum-classical reduction described here might be extended to reduction between other classical and quantum theories, including classical and quantum field theory and classical and quantum gravity.     

Experimental : The double standard in the quantum-information approach to the foundations of quantum theory

Among the alternatives of non-relativistic quantum mechanics (NRQM) there are those that give different predictions than quantum mechanics in yet-untested circumstances, while remaining compatible with current empirical findings. In order to test these predictions, one must isolate one's system from environmental induced decoherence, which, on the standard view of NRQM, is the dynamical mechanism that is responsible for the ‘apparent’ collapse in open quantum systems. But while recent advances in condensed-matter physics may lead in the near future to experimental setups that will allow one to test the two hypotheses, namely genuine collapse vs. decoherence, hence make progress toward a solution to the quantum measurement problem, those philosophers and physicists who are advocating an information-theoretic approach to the foundations of quantum mechanics are still unwilling to acknowledge the empirical character of the issue at stake. Here I argue that in doing so they are displaying an unwarranted double standard.     

Quantum jumps,superpositions, and the continuous evolution of quantum states

The apparent dichotomy between quantum jumps on the one hand, and continuous time evolution according to wave equations on the other hand, provided a challenge to Bohr's proposal of quantum jumps in atoms. Furthermore, Schrödinger's time-dependent equation also seemed to require a modification of the explanation for the origin of line spectra due to the apparent possibility of superpositions of energy eigenstates for different energy levels. Indeed, Schrödinger himself proposed a quantum beat mechanism for the generation of discrete line spectra from superpositions of eigenstates with different energies.However, these issues between old quantum theory and Schrödinger's wave mechanics were correctly resolved only after the development and full implementation of photon quantization. The second quantized scattering matrix formalism reconciles quantum jumps with continuous time evolution through the identification of quantum jumps with transitions between different sectors of Fock space. The continuous evolution of quantum states is then recognized as a sum over continually evolving jump amplitudes between different sectors in Fock space.In today's terminology, this suggests that linear combinations of scattering matrix elements are epistemic sums over ontic states. Insights from the resolution of the dichotomy between quantum jumps and continuous time evolution therefore hold important lessons for modern research both on interpretations of quantum mechanics and on the foundations of quantum computing. They demonstrate that discussions of interpretations of quantum theory necessarily need to take into account field quantization. They also demonstrate the limitations of the role of wave equations in quantum theory, and caution us that superpositions of quantum states for the formation of qubits may be more limited than usually expected.     

A simple approach to the toad's (Bufo melanostictus) nerver muscle preparation

Summary A simple and modified dorsal approach method has been made in the toad's (Bufo melanostictus) sciatic gastrocnemius nerve-musle preparation. This method incurs less blood loss, time consumption, nerve damage and visceral spoil compared to conventional ventral approach method.     

A simple approach to the toad's (Bufo melanostictus) nerve muscle preparation.

A simple and modified dorsal approach method has been made in the toad's (Bufo melanostictus) sciatic gastrocnemius nerve-muscle preparation. This method incurs less blood loss, time consumption, nerve damage and visceral spoil compared to conventional ventral approach method.     

Klein-Weyl's program and the ontology of gauge and quantum systems

We distinguish two orientations in Weyl's analysis of the fundamental role played by the notion of symmetry in physics, namely an orientation inspired by Klein's Erlangen program and a phenomenological-transcendental orientation. By privileging the former to the detriment of the latter, we sketch a group(oid)-theoretical program—that we call the Klein-Weyl program—for the interpretation of both gauge theories and quantum mechanics in a single conceptual framework. This program is based on Weyl's notion of a “structure-endowed entity” equipped with a “group of automorphisms”. First, we analyze what Weyl calls the “problem of relativity” in the frameworks provided by special relativity, general relativity, and Yang-Mills theories. We argue that both general relativity and Yang-Mills theories can be understood in terms of a localization of Klein's Erlangen program: while the latter describes the group-theoretical automorphisms of a single structure (such as homogenous geometries), local gauge symmetries and the corresponding gauge fields (Ehresmann connections) can be naturally understood in terms of the groupoid-theoretical isomorphisms in a family of identical structures. Second, we argue that quantum mechanics can be understood in terms of a linearization of Klein's Erlangen program. This stance leads us to an interpretation of the fact that quantum numbers are “indices characterizing representations of groups” ((Weyl, 1931a), p.xxi) in terms of a correspondence between the ontological categories of identity and determinateness.     

The nucleoside-copper (II) interaction and the tautomeric forms of the nucleosides

Zusammenfassung Durch infrarotspektroskopische Messungen wird bewiesen, dass Guanosin, Desoxyguanosin und Inosin bei der Bildung von Kupfer(II)-Komplexen entgegen früheren Darstellungen in wäßriger Lösung in der Ketoform vorliegen.

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Infrared Studies of DNA, their Constituents and Anologues, Part V.     

The effects of temperature on ATPase activity and force generation in skinned muscle fibers from the Pacific blue marlin (Makaira nigricans)

Summary ATPase activity and force generation have been measured simultaneously in isolated, demembranated muscle fibers of the Pacific blue marlin (Makaira nigricans) between 0 and 30°C. Tension generation is relatively independent of temperature above 15°C and falls with a Q₁₀ of <1.5 on decreasing the temperature to 0°C. In contrast, the Q₁₀ for ATPase activity is 2.2 over the range 0–30°C. The results are interpreted in terms of the cross bridge theory of contraction.     

Class I and class II ribonuclease H activities inCrithidia fasciculata (protozoa)

Summary The protozoanCrithidia fasciculata contains two different ribonuclease H activities. These enzymes display similar physical and biochemical characteristics to their homologues in higher eukaryotes, for instance calf thymus class I and class II ribonuclease H. Class I ribonuclease H of lower and higher eukaryotes can be activated by Mg²⁺- and Mn²⁺- ions. However, the presence of Mn²⁺-ions is inhibitory for the Mg²⁺-dependent class II ribonuclease H activity ofCrithidia fasciculata and calf thymus. The protozoan class I-homologue enzyme appears to be serologically related to the class I ribonuclease H of calf thymus.