Studies of Photorefractive Crystals of Double-Doped Ce,Fe:LiNbO3

In this paper, photorefractive crystals of Ce, Fe:LiNbO3 are systematically studied. The crystals have been grown by Czochralski method. The samples with different doping concentrations and oxidation/reduction treatments have been fabricated. Their photorefractive properties were experimentally investigated by using two-beam coupling. The results show that the photorefractive efficiency depends on the dopant concentration, oxidation/reduction treatment, and light wavelength. The doping mechanism is also discussed here.     

氧化还原对掺铁LiNbO3晶体的吸收边和透过率的影响

着重研究了经过不同氧化还原处理的不同掺杂及浓度的掺铁铌酸锂晶体的吸收边和透射谱，认为晶体的能带结构随掺杂离子及离子的价态变化而变化，并解释了吸收边的有关实验结果．     

Optical Property of LiNbO3 Crystal Codoped with In, Mg and Fe

In2O3, MgO and Fe2O3 were doped in LiNbO3 and Czochralski method was used to grow In:Mg:Fe:LiNbO3 crystals. The OH- extension transmission spectra, light scattering resistance ability, two wave coupled diffraction efficiency and response time of the crystal were measured. Codoping In and Mg in crystal will improve its light scattering resistance ability and response time. Doping In can increase the ability to replace antisite Nb and decrease the doping quantity of Mg. All these are propitious to improve the optical homogeneity of crystal. Doping Fe can improve the photorefractive sensitivity for LiNbO3 crystal. We discussed the site of In, Mg and Fe in LiNbO3 crystals and the influence of the absorption peak of OH- transmission spectra on photorefractive property for LiNbO3 crystal.     

Optical Property of LiNbO3 Crystal Codoped with In, Mg and Fe

In2O3, MgO and Fe2O3 were doped in LiNbO3 and Czochralski method was used to grow In:Mg:Fe:LiNbO3 crystals. The OH- extension transmission spectra, light scattering resistance ability, two wave coupled diffraction efficiency and response time of the crystal were measured. Codoping In and Mg in crystal will improve its light scattering resistance ability and response time. Doping In can increase the ability to replace antisite Nb and decrease the doping quantity of Mg. All these are propitious to improve the optical homogeneity of crystal. Doping Fe can improve the photorefractive sensitivity for LiNbO3 crystal. We discussed the site of In, Mg and Fe in LiNbO3 crystals and the influence of the absorption peak of OH- transmission spectra on photorefractive property for LiNbO3 crystal.     

吸收及界面内反射对逆向二波混合的影响

以Shooting法为基础,研究了吸收、增益和晶体厚度对光折变晶体中逆向二波混合的影响,对近似计算所引起的误差进行了讨论。对晶体表面内反射对光束透过率的影响,提出了以Shooting法为基础的自洽计算方法,计算了透过率与晶体表面反射率的关系。     

晶体对称性与光折变耦合作用

推导了除单斜和三斜之外的17种点群电光晶体在空间电荷场作用下有效电光系数具体表达式.据此讨论了这些晶体中光折变耦合作用特点。     

有偏压光伏光折变晶体中低振幅孤子的自偏转

修正和完善了有偏压的光伏光折变晶体中空间孤子的空间电荷场理论,通过对有偏压的光伏光折变晶体中低振幅明孤子的自偏转进行的研究,得到了孤子光束中心的运动呈抛物线型,并且这束中心光的空间频率分量随传播距离发生线性移动,当光伏效应可忽略时,低振幅明的子的自偏转就转化为低振幅屏蔽孤子的自偏转,它的空间电荷场就转化为屏蔽孤子的空间电荷场;当外偏压为０时,它的空间电荷场就转化为闭路和开路光伏孤子的空间电荷场,它     

质子辐照后的KNbO3晶体的光折变响应特性

实验研究了质子辐照的KNbO₃晶体随光强变化的光折变响应特性,并测量了其光折变时间常数。实验结果揭示出在质子辐照后的KNbO₃晶体中存在着2种不同的光栅,其一是慢成分,是由晶体本身的光折变效应所产生;另一个则是快成分,是由于质子辐照后所产生的辐照效应。实验结果还反映出这2种光栅是由2种不同种类的载流子产生的。     

双掺杂LiNbO3晶体光折变效应图像存储特性

研究了系列双掺杂(Ce：Fe，Mn：Fe，Ce：Mn)以及不同后处理态(生长态、还原态和氧化态)铌酸锂晶体的透过率光谱和光折变全息存储特性．实验结果表明高掺杂铌酸锂样品的透过率光谱范围较窄；氧化态样品具有较大的透过率光谱范围；还原态样品具有较大的光折变二波耦合增益特性．难于同时获得大的波耦合增益和图像存储质量．     

光致折射晶体在光纤传感器信号检测中的应用

本文用双光束耦合理论,讨论了光致折射晶体在光纤传感器信号检测中的应用,得出了测量传感信号的理论公式.     

Ce掺杂的NiCo2O4催化氧化甲苯性能研究

NiCo₂O₄是一种很前景的甲苯氧化催化剂。本文以Ce为杂原子,利用水热法制备Ce/NiCo₂O₄催化剂,以提高NiCo₂O₄尖晶石表面活性氧生成速率。采用氢气程序升温还原(H₂-TPR)、X射线光电子能谱(XPS)、X射线衍射(XRD)、比表面积测定(BET)、以及透射电子显微镜(TEM)等表征催化剂。通过改变铈掺杂量,得到最佳掺杂比例。甲苯降解实验表明,在甲苯浓度为2538ppm,空速为10000h^_-1,催化剂体积为0.5mL 时,一次水热法制备得到的15%Ce/NiCo₂O₄催化剂降解性能最优(T₉₉=267℃),在267℃下进行催化反应72h后催化剂性能无显著变化。机理研究发现,掺杂铈可提升催化剂中高价金属含量,同时催化剂良好的氧化还原性能可加快表面活性氧生成速率,从而催化性能得以提升。     

GaAs/Al_(0.3)Ga_(0.7)As多量子阱的平方电光效应和光折变效应的研究

本文研究了半绝缘GaAs／Al0.3Ga0.7As多量子阱的电光效应和光折变效应．用光调制反射谱分析了样品的结构;用电调制透射谱测量了电吸收和电折变;用二波混合的方法测量了它的光折变性质．对两种方法得到的电吸收和电折变作了分析比较．     

体光折变栅的高阶衍射

本文探讨了在光折变晶体写入体相位栅产生高阶衍射的物理机制，在光栅的写入过程中，振幅和位相耦合分别引起光栅振幅和位相的不均匀，这两种不均匀性导致光栅波矢的附加横向分量，后者可有效地补偿高阶衍射的波矢失配，同时一旦高阶衍射在晶体表面出现，具有高增益值的光折变值晶体通过多波耦合将保证它随传播距离增长，这是在光折变晶体中形成高阶衍射光束的重要原因。     

双掺杂LiNbO_3晶体光谱和光折变特性

报道了双掺杂Ce :Fe ,Ce :Mn ,Mn :Fe生长态LiNbO3(LN)的光谱及光折变效应二波耦合增益特性 .研究表明 ,双掺杂浓度较高时 ,生长态的LiNbO3晶体的透过率光谱范围较小 ,光折变效应二波耦合增益较低 .几种双掺杂晶体都比单掺Fe晶体的光折变效应二波耦合增益低 ,表现出较强的抗光折变特性     

掺铁铌镁酸铅一钛酸铅单晶的光折变效应

采用助溶剂法生长了掺杂量分别为0．1wt％和0．01wt％的0．67PMNT-0．33PT单晶．利用二波耦合实验研究了掺铁的弛豫铁电单晶0．67Pb（Mg1／3Nb2,3）03-0．33PbTi03（PMN．PT）的光折变性能．本文测试了样品的消光光谱、电光系数、光诱吸收电场和光电导．最大的增益系数达到了21cm-1,是无掺杂的PMN-PT晶体的两倍．光栅形成速率随铁浓度的升高而降低．     

Holography in artificial neural networks

The dense interconnections that characterize neural networks are most readily implemented using optical signal processing. Optoelectronic 'neurons' fabricated from semiconducting materials can be connected by holographic images recorded in photorefractive crystals. Processes such as learning can be demonstrated using holographic optical neural networks.     

V~(5 )、Ho~(3 )共掺杂TiO_2光降解甲基橙(英文)

采用溶胶-凝胶法制备了不掺、单掺和共掺杂纳米TiO2,对样品进行了XRD和UV-Vis吸收光谱分析,并以甲基橙的光脱色反应考察了样品的光催化性能。结果发现V5 拓宽了TiO2光谱响应范围,提高了光的利用率,产生更多的电子-空穴对;Ho3 的掺杂抑制了TiO2粒径的长大,引起了晶格的畸变和膨胀,延缓了光生载流子的复合;V5 、Ho3 共掺杂时,由于两种掺杂物的共同作用,可进一步提高TiO2的光催化性能。     

硼皮金刚石聚晶中硼原子的分布及对耐热性的影响

利用中子径迹和离子探针方法,对硼皮金刚石聚晶和含硼黑金刚石聚晶中硼原子的微观结构进行了观察,验证了硼原子分布模型;并利用热重-差热分析方法,对其耐热性进行了分析,解释了硼皮金刚石聚晶的抗氧化性能及化学惰性优异的原因。     

光折变晶体中由2k反射光栅形成自泵浦相位共轭

本文给出在光折变晶体中通过受激二波混频形成自泵浦相位共轭的一种理论,在适当条件下,二波混频的耦合波方程可化为相位共轭光学中的一对耦合模方程,对于折射率光栅与条纹之间具有任意相移的光折变2k光栅,其反射的背向散射波的解是入射泵浦光的相位共轭波,产生自泵浦相位共轭的条件是背向波能最有效地吸取入射光束的功率,以至于背向散射光的强度处处等于人射光的光强;背向散射的种波应超过一定的阈值。     

Structure sensitive properties of KTP-type crystals

Adding various dopants during the growth of the parent KTiOPO4 (KTP) crystal has given rise to an extensive series of KTP-type crystals. The doped KTP or KTP-type crystals often have very subtle structural variations from pure KTP crystals. As a result of these structural changes the KTP-type crystals often exhibit different physical properties, which may be referred to as structure sensitive properties. It is possible to fine-tune the nonlinear optical properties of KTP crystals through doping. This results in a broad range of applications for KTP-type crystals.