粤北贵东岩体内基性岩脉的成因研究

对贵东花岗岩体内的基性岩脉研究结果表明,岩脉的锶、氧、硫同位素组成均一致显示幔源衍生物特征;岩脉常量元素、微量元素以及稀土元素分析表明、岩脉经历了较完全的结晶分异作用,并遭受到一定程度的陆壳混染作用。由此得出结论,认为形成岩脉的岩浆来自起源于地幔深处并侵位于地壳浅部(<15Km)的二次岩浆房,岩浆在这里发生结晶分异作用,在其随后的上升侵位过程中经受了陆壳的混染作用。     

新疆黄山-镜儿泉铜镍成矿带典型矿床特征及成因分析

黄山-镜儿泉铜镍成矿带是我国重要的大型铜镍矿基地。岩体为洋内俯冲的增生岛弧环境产物,为北天山洋壳向北俯冲增生记录。上地幔物质形成岩浆后,在弧间相对稳定的构遣环境下得以发生充分的岩浆重力分异,随着断裂构造的多期活动,这些岩浆、含硫化物岩浆和矿浆分别沿断裂被挤压-侵入上部地壳,形成基性-超基性岩的复式杂岩体和复式矿床,从而构成有特色的硫化铜镍矿床。成岩成矿时间应该在280～510Ma之间。     

四川丹巴杨柳坪铜镍铂族元素硫化物矿床成因初探

四川丹巴杨柳坪铜镍铂族元素硫化物矿床的含矿岩体围绕杨柳坪穹状构造分布,侵位于泥盆系大理岩、炭质板岩中.自下至上岩体由蛇纹岩相、滑石岩相、次闪石岩相和蚀变辉长岩相组成.似层状浸染状矿体分布于岩体底部蛇纹岩相内,透镜状块状矿体则分布于底部及底板围岩中,后者与前者在空间上有密切的依存关系.矿石中主要硫化物矿物为磁黄铁矿、镍黄铁矿和黄铜矿;块状矿石中还发现辉砷钴矿,以及砷铂矿、碲锑钯矿等铂族元素矿物.野外关系表明杨柳坪含矿镁铁-超镁铁岩体为火山通道相浅成岩体.含矿岩体和大石包玄武岩的地球化学特征表明两者为同源岩浆产物,与其它地区峨眉山玄武岩地球化学特点的相似性,表明它们也是峨眉地幔柱活动的产物.当玄武岩浆上升到浅成岩浆房中时,随着岩浆分离结晶作用的进行,硫化物从玄武岩浆中熔离出来并向下聚集是主要成矿作用.     

Continental mantle signature of Bushveld magmas and coeval diamonds

The emplacement of the 2.05-billion-year-old Bushveld complex, the world's largest layered intrusion and platinum-group element (PGE) repository, is a singular event in the history of the Kaapvaal craton of southern Africa, one of Earth's earliest surviving continental nuclei. In the prevailing model for the complex's mineralization, the radiogenic strontium and osmium isotope signatures of Bushveld PGE ores are attributed to continental crustal contamination of the host magmas. The scale of the intrusion and lateral homogeneity of the PGE-enriched layers, however, have long been problematical for the crustal contamination model, given the typically heterogeneous nature of continental crust. Furthermore, the distribution of Bushveld magmatism matches that of seismically anomalous underlying mantle, implying significant interaction before emplacement in the crust. Mineral samples of the ancient 200-km-deep craton keel, encapsulated in macrodiamonds and entrained by proximal kimberlites, reveal the nature of continental mantle potentially incorporated by Bushveld magmas. Here we show that sulphide inclusions in approximately 2-billion-year-old diamonds from the 0.5-billion-year-old Venetia and 1.2-billion-year-old Premier kimberlites (on opposite sides of the complex) have initial osmium isotope ratios even more radiogenic than those of Bushveld sulphide ore minerals. Sulphide Re-Os and silicate Sm-Nd and Rb-Sr isotope compositions indicate that continental mantle harzburgite and eclogite components, in addition to the original convecting mantle magma, most probably contributed to the genesis of both the diamonds and the Bushveld complex. Coeval diamonds provide key evidence that the main source of Bushveld PGEs is the mantle rather than the crust.     

Evidence from gabbro of the Troodos ophiolite for lateral magma transport along a slow-spreading mid-ocean ridge

The lateral flow of magma and ductile deformation of the lower crust along oceanic spreading axes has been thought to play a significant role in suppressing both mid-ocean ridge segmentation and variations in crustal thickness. Direct investigation of such flow patterns is hampered by the kilometres of water that cover the oceanic crust, but such studies can be made on ophiolites (fragments of oceanic crust accreted to a continent). In the Oman ophiolite, small-scale radial patterns of flow have been mapped along what is thought to be the relict of a fast-spreading mid-ocean ridge. Here we present evidence for broad-scale along-axis flow that has been frozen into the gabbro of the Troodos ophiolite in Cyprus (thought to be representative of a slow-spreading ridge axis). The gabbro suite of Troodos spans nearly 20 km of a segment of a fossil spreading axis, near a ridge-transform intersection. We mapped the pattern of magma flow by analysing the rocks' magnetic fabric at 20 sites widely distributed in the gabbro suite, and by examining the petrographic fabric at 9 sites. We infer an along-axis magma flow for much of the gabbro suite, which indicates that redistribution of melt occurred towards the segment edge in a large depth range of the oceanic crust. Our results support the magma plumbing structure that has been inferred indirectly from a seismic tomography experiment on the slow-spreading Mid-Atlantic Ridge.     

Finding of ancient materials in Cathaysia and implication for the formation of Precambrian crust

U-Pb dating for fifty-six detrltsl zircons from a paragneiss in Nanxiong area, northern Guangdong Province, Indicates that the latest Neoproterozoic sediments in Cathaysia hinterland are composed of numerous Grenvillian and Necerchaean clasUc materials, as well as some Mesoproterozolc detritus. Minor Paleoarchaean （3.76 Ga） and Mesoarchaean （3.0-3.2 Ga） zircons, which are the oldest zircons In South China, also are firstly found in the sediments, suggesting that the Cathaysia Block may contsln very old materials. The Hf isotope compositions of thirty-seven zircons reveal that these clastlc materials have different origins. Minor zircons crystslllzed from magma generated from relatively juvenile crust, while the parental magma of most zircons was derived from ancient crust. Integration of U-Pb dating and Hf Isotope analysis of these zircons suggests that the generation of juvenile crust in the Cathaysia block mainly occurred at 2.5-2.6 Ga. Mesoarchaean （3.0-3.3 Ga）, late Paleoproterozolc （-1.8 Ga） and Paleoarchaean （-3.7 Ga） may also be important episodes of crustal growth. Grenvllllan magmatism is extremely Intense, but it mainly involved recycling of ancient crustal components with little formation of Juvenile crust. The marked presence of -2.1 Ga Hf model ages and the absence of the zircons with crystsllizatlon ages at -2.1 Ga suggest that the parental magma of many zircons was probably derived from the mixed source consisting of Neoarchaean and late Paleoproterozoic materlals.     

Late Mesozoic interaction between crust and mantle in coastal area of Zhejiang-Fujian

This paper summarizes the lithogeochemical features of composite lavas, dikes and plutons composed of early Cretaceous associated basic-acidic igneous rocks from the coastal area of Zhejiang-Fujian. On the basis of the studies on Nd, Sr, Pb isotopic signatures and geochemical characteristics of large ion lithophile elements (L1LE) , light rare earth elements (LREE) and high field strong elements ( HFSE) of these contemporary basic-acidic igneous rocks, it is considered that the source enrichment caused by the subduction of Pacific plate and contamination of crustal rocks and melts during ascending process may lead to the formation of basaltic magmas with a high LILE concentration. These late Mesozoic composite basic-acidic igneous rocks are the products of the interactions between crust and mantle in active continental margin.     

3062矿床稀土及成矿元素地球化学

本文在15个样品分析结果的基础上,论述赋矿火山岩中稀土及成矿元素地球化学特征,矿化火山岩中REE比非矿化火山岩中REE含量高;矿石中特别富集重稀土元素。矿石中主要共存元素是U,Th,Ti,Mo,Pb等。其中U,Th,Mo可以综合利用。成矿物质来源于硅铝壳,成矿元素的富集与岩浆分异作用有密切的关系。     

内蒙古大苏计斑岩型钼矿赋矿岩体的锆石U-Pb年龄与地球化学特征研究

为研究内蒙古大苏计斑岩型钼矿床赋矿岩体的形成年龄、地球化学特征及构造背景, 对3种岩体(石英斑岩、花岗斑岩和正长花岗岩)的样品进行锆石U-Pb定年和主量元素、微量元素分析。结果显示, 石英斑岩、正长花岗岩和花岗斑岩分别形成于231, 227和225 Ma, 为印支期产物。3种岩体属于高钾钙碱性−钾玄质系列, 为高分异的I型花岗岩。岩石组合特征与区域地质背景揭示, 大苏计地区在印支期处于伸展环境, 软流圈上涌导致不同深度的地壳发生部分熔融作用, 产生与大苏计斑岩型钼矿成矿相关的母岩浆。这些母岩浆向上运移过程中萃取前中生代形成的矿源层中的成矿元素, 并在结晶分异过程中不断地富集钼元素, 当岩浆挥发分达到过饱和时发生流体相与熔体相的分离, 钼进入流体相。岩浆热液沿裂隙充填, 在演化过程中发生沸腾作用, 导致大量钼和石英沉淀, 形成大苏计钼矿床。     

The discovery of eclogite dikes in low-greenschist facies volcaniclastic rocks of the Dabie Mountains

Conclusions  

湘东北地区脉型金矿床的活化转移

通过综合分析湘东北地区冷家溪群中金的分布规律、矿石和围岩的稀土元素及同位素地球化学特征等，论证了湘东北地区的脉型金矿床是分散在冷家溪群中的金在冷家溪群的构造－热改造演化过程中活化转移而成的，长距离的活化转移主要发生在武陵－加里东期，在印支－燕山期又发生了再活化转移，活化和再活化转移都是通过流体来进行的．     

Survival times of anomalous melt inclusions from element diffusion in olivine and chromite

The chemical composition of basaltic magma erupted at the Earth's surface is the end product of a complex series of processes, beginning with partial melting and melt extraction from a mantle source and ending with fractional crystallization and crustal assimilation at lower pressures. It has been proposed that studying inclusions of melt trapped in early crystallizing phenocrysts such as Mg-rich olivine and chromite may help petrologists to see beyond the later-stage processes and back to the origin of the partial melts in the mantle. Melt inclusion suites often span a much greater compositional range than associated erupted lavas, and a significant minority of inclusions carry distinct compositions that have been claimed to sample melts from earlier stages of melt production, preserving separate contributions from mantle heterogeneities. This hypothesis is underpinned by the assumption that melt inclusions, once trapped, remain chemically isolated from the external magma for all elements except those that are compatible in the host minerals. Here we show that the fluxes of rare-earth elements through olivine and chromite by lattice diffusion are sufficiently rapid at magmatic temperatures to re-equilibrate completely the rare-earth-element patterns of trapped melt inclusions in times that are short compared to those estimated for the production and ascent of mantle-derived magma or for magma residence in the crust. Phenocryst-hosted melt inclusions with anomalous trace-element signatures must therefore form shortly before magma eruption and cooling. We conclude that the assumption of chemical isolation of incompatible elements in olivine- and chromite-hosted melt inclusions is not valid, and we call for re-evaluation of the popular interpretation that anomalous melt inclusions represent preserved samples of unmodified mantle melts.     

福建明溪锆石巨晶中的斜锆石、锆石矿物包裹体及其成因启示

福建明溪是我国和火山岩有关的锆石巨晶的典型产地.通过对该地的锆石巨晶晶体形态及其包裹体的研究发现,福建明溪锆石巨晶四方柱明显较双锥发育,表面有熔蚀结构,内部结构均匀;锆石巨晶中发现的斜锆石包裹体和其它产地斜锆石相比具有贫大离子半径元素U,Th,Y,Zr/Hf高的特点.巨晶中的锆石包裹体的拉曼光谱有两种不同类型,其中一类锆石包裹体的拉曼谱和变质及热处理锆石相似,说明锆石巨晶形成时曾经历过变质作用过程.锆石巨晶及其包裹体特征暗示锆石巨晶不是玄武岩结晶产物,和伴生的刚玉巨晶相比其来源可能更深,是壳一幔物质相互作用产物.     

郯庐断裂带中生代火山活动与深部过程

郯庐断裂带中生代火山活动主要发生在早白垩世 ,形成了一套以橄榄安粗岩系为主的火山岩。火山岩岩石化学特征、地球化学特征与断裂带外明显不同 ,以富碱富钾、富轻稀土元素为特征 ,具有较高的 ISr值和明显偏低的εNd值 ,表明火山活动不仅与地壳混染有关 ,而且与深部地幔以及断裂带的演化有密切的关系。研究显示该区岩浆起源于地幔底侵、壳幔相互作用下的壳幔过渡带 ,也反映此时的断裂带切入到壳幔边界。     

川西拗陷中段蓬莱镇组物源的地球化学示踪

探讨川西拗陷中段上侏罗统蓬莱镇组物源问题。采用地球化学示踪方法,通过岩石薄片、痕量元素和稀土元素等综合分析,结合前人的研究成果,对蓬莱镇组源区背景属性和物源特征进行研究。结果表明:研究区蓬莱镇组砂岩碎屑组分以石英为主,其次是长石及各种岩屑;REE配分模式与大陆上地壳稀土元素配分模式基本一致,轻稀土元素富集,Eu负异常较为明显。其源区的构造环境是从海相过渡到陆相,最后演化成复杂的源区。川西拗陷中段蓬莱镇组有龙门山、大巴山-米仓山多个物源区,北部的主要物源区为大巴山-米仓山,南部的物源区为龙门山,中部则为混源区。     

Frozen magma lenses below the oceanic crust

The Earth's oceanic crust crystallizes from magmatic systems generated at mid-ocean ridges. Whereas a single magma body residing within the mid-crust is thought to be responsible for the generation of the upper oceanic crust, it remains unclear if the lower crust is formed from the same magma body, or if it mainly crystallizes from magma lenses located at the base of the crust. Thermal modelling, tomography, compliance and wide-angle seismic studies, supported by geological evidence, suggest the presence of gabbroic-melt accumulations within the Moho transition zone in the vicinity of fast- to intermediate-spreading centres. Until now, however, no reflection images have been obtained of such a structure within the Moho transition zone. Here we show images of groups of Moho transition zone reflection events that resulted from the analysis of approximately 1,500 km of multichannel seismic data collected across the intermediate-spreading-rate Juan de Fuca ridge. From our observations we suggest that gabbro lenses and melt accumulations embedded within dunite or residual mantle peridotite are the most probable cause for the observed reflectivity, thus providing support for the hypothesis that the crust is generated from multiple magma bodies.     

Petrology, geochemistry and geodynamics of basic granulite from the Altay area, North Xinjiang, China

The basic granulite of the Altay orogenic belt occurs as tectonic lens in the Devonian medium- to lower-grade metamorphic beds through fault contact. The Altay granulite (AG) is an amphibole plagioclase two-pyroxene granulite and is mainly composed of two pyroxenes, plagioclase, amphibole and biotite. Its melano-minerals are rich in Mg/(Mg Fe^2 ),and its amphibole and biotite are rich in TiO2. The AG is rich in Mg/(Mg Fe^2 ), Al2O3 and depletion of U, Th and Rbcontents. The AG has moderate ∑REE and LREE-enriched with weak positive Eu anomaly. The AG shows island-arc pattern with negative Nb, P and Ti anomalies, reflecting that formation of the AG may be associated with subduction. Geochemical and mineral composition data reflect that the protolith of the AG is calc-alkaline basalt and formed by granulite facies metamorphism having peak P-T conditions of 750℃-780℃ and 0.6-0.7 Gpa. The AG formation underwent two stages was suggested. In the early stage of oceanic crustal subduction, calc-alkaline basalt with island-arc environment underwent granulite facies metamorphism to form the AG in deep crust, and in the late stage, the AG was thrust into the upper crust.     

北祁连东段西、南华山中酸性侵入岩地球化学特征

北祁连东段西、南华山中酸性侵入岩以花岗岩和花岗闪长岩为主,SiO2质量分数在66.23%~77.13%之间,具有钙碱系列的岩石组合特征和地球化学特征.微量元素Pb、Sr和La明显富集,Cs、Nb、Ti等元素呈现不同程度亏损,显示混合源岩浆的特征.∑REE的质量分数为(100.80~121.03)×10-6,低于世界酸性岩平均值.稀土配分模式呈右倾型,δEu=0.31~0.33,有负Eu异常,与北秦岭加里东期岛弧型花岗岩地球化学特征相似.中酸性岩体总体表现为壳幔混合型岩浆结晶分异的产物,反映北祁连地区中奥陶世末处于具沟-弧-盆体系的俯冲背景.     

Platinum-group elements for the Kudi ophiolite, western Kunlun

The analyses of PGE characteristics for the Kudi ophiolite, western Kunlun, are reported in this note. The Ir-depieted anomalous ancient upper mantle represented by the Kudi mantle peridotites had been percolated and mixed by remelted oceanic crust material from a supra-subduction zone, leaving the rocks relatively enriched in Pd. The PGE contents in the Kudi cumulate pyroxenites and gabbros vary from 2.4 to 23.94 ng/g, and the highest values are in pyroxenites. The Pd/lr ratios increase from the pyroxenites to the gabbros. The PGE patterns for the Kudi cumulate rocks are steeply positively sloped. The Pd enrichment in these rocks is similar to that in pyroxenites from the Thetford ophiolite and the Troodos ophiolite. The Kudi diabase and basalts have low PGE contents and positively sloped PGE patterns, and are comparable with the upper pillow lavas from the Troodos ophiolite, indicative of the environment of back-arc spreading center in a supra-subduction zone.     

五台山晚太古代花岗岩的成因及其动力学意义

五台山晚太古代花岗岩（～2.540 Ga）,主要由花岗闪长岩、二长花岗岩、少量的英云闪长岩、奥长花岗岩组成,全岩化学分析表明它们具有中～高钾钙碱性花岗质岩浆性质,LILE富集和高的 w(Rb)/w(Sr) (即: Rb/Sr)比值,相对较低的 w(Sr)/w(Y)、w(La)_n/w(Yb)_n、w(Nb)/w(Ta) 和 w(Zr)/w(Hf) 比值,右斜式稀土配分模式,Nb、Ta、Ti亏损,但是它们均表现了Nd T_DM＝2.54～2.72 Ga和明显的正ε_Nd(t)值。这些地球化学特征表明其钙碱性花岗质岩浆形成于晚太古代大洋岛弧环境,来源于弧下玄武质初生地壳的部分熔融,并经历了一定程度的结晶分异。由于晚太古代洋壳向大洋岛弧俯冲、脱水,引起上覆地幔楔的部分熔融形成弧下初生地壳玄武质物质,这些弧下玄武质物质在少于37km环境下部分熔融形成五台山晚太古代钙碱性花岗质岩浆。