跳动及滚动激励制备的碳化硼涂层表面形貌的对比

利用电子束蒸发技术蒸发碳化硼, 通过弹跳激励和滚动激励两种方案来随机滚动小球, 从而分别在玻璃和钢球心轴上制备了碳化硼涂层. 采用扫描电子显微镜对涂层表面形貌进行了分析. 同采用弹跳激励制备的涂层相比, 在用滚动激励制备的涂层表面不存在裂纹和微粒脱落现象, 其微粒生长的更大, 相互接合的更致密. 经对比证明, 在制备碳化硼涂层上, 滚动激励装置优于跳动激励装置.     

退火保温时间对碳化硼微球涂层表面形貌的影响

采用电子束蒸发镀膜技术,并结合本课题组自行设计的磁控滚动三维沉积装置,以及真空连续加料装置,在Ф1～2mm钢球上沉积碳化硼微球涂层.通过X射线光电子能谱(XPS)、扫描电子显微镜(SEM)和原子力显微镜(AFM),对退火处理中不同保温时间的碳化硼微球涂层进行表征.结果表明,微球涂层硼碳比较小,有部分B流失;不同的保温时间对微球形貌的影响比较明显.随着保温时间的增加,微球表面粗糙度逐渐增大,但致密性和力学性能同时也得到相应加强.确定保温时间为1~3h为最佳退火保温条件.     

电子束蒸发制备碳化硼球面涂层的表面氧化研究

利用电子束蒸发技术沉积制备了碳化硼微球涂层,将微球涂层依次经退火和稀硫酸腐蚀处理后得到碳化硼空心微球,并借助XRD和SEM对碳化硼微球涂层的表面氧化问题进行了研究.XRD结果显示当衬底温度在120℃附近时,碳化硼涂层部分被晶化;对退火前后和酸腐蚀后的微球涂层进行SEM分析,结果表明,退火前的涂层表面部分被氧化成B2O3,退火后B2O3覆盖在涂层表面,酸腐蚀可以去掉B2O3,得到表面光洁的碳化硼空心微球.     

强流脉冲电子束轰击粘结层表面微观形貌的研究

针对传统热障涂层在服役温度下容易失效的特点,采用大气等离子喷涂技术在镍基高温合金GH4169上制备CoCrAlY粘结层,并利用电子束蒸发镀膜技术在粘结层表面沉积一层纯铝薄膜,最后使用强流脉冲电子束对镀铝膜的粘结层表面进行轰击,制备了新型热障涂层.研究了新型热障涂层CoCrAlY粘结层表面改性后的微观结构.实验结果表明:CoCrAlY粘结层表面蒸镀Al膜并经强流脉冲电子束轰击后产生了Al相和Al_2O_3相,Co基氧化物消失;粘结层表面变得较为致密、均匀,粗糙度明显增大且分布着大量纳米尺寸的富氧化铝细泡,这些气泡可以有效提高热障涂层抗氧化性能.     

沉积时间对真空离子镀TiC涂层微磨具表面性能的影响

采用真空电弧离子镀膜方法进行微磨具表面涂层制备实验研究,实验选择不同沉积时间做单因素实验进行涂层制备.分析了不同沉积时间的涂层物相组成,研究了不同沉积时间对涂层表面形貌的影响规律,探讨了其对摩擦系数和粗糙度的影响变化规律,以及对涂层厚度的影响规律,选出合理的沉积时间制备涂层微磨具.实验结果表明:钛镀层和金刚石发生界面反应,形成稳定的碳化钛层;随着沉积时间增加,摩擦系数不断增加,而粗糙度逐渐降低,涂层厚度逐渐增加.研究结果为涂层微磨具制备与提高微磨具的耐磨性和使用寿命提供了理论参考和实验依据.     

电泳共沉积法制备金刚石/Al2O3/玻璃复合涂层的工艺

以304不锈钢为基体,采用电泳共沉积法制备复合涂层,并通过烧结方式实现涂层在基体的固化。研究电泳共沉积过程中不同悬浮液组成、沉积电压、沉积时间和Al³⁺质量分数等因素对涂层性能的影响,对涂层进行微观结构表征和力学性能测试,并使用该工艺制备抛光盘,用于蓝宝石的抛光。结果表明：当沉积电压为50 V,沉积时间为6 min,添加质量分数为0.10%的Al³⁺时,可获得光滑、均匀的金刚石/Al₂O₃/玻璃复合涂层;复合涂层经450℃烧结3 h后,表面致密均匀,硬度达521 HV,复合涂层的耐磨性、与基体的结合强度均良好;使用抛光盘对蓝宝石进行抛光,可将表面粗糙度降低90.2%。     

Mg-Zn-Zr表面Ca-P涂层的制备及其降解性能研究

本研究采用微弧氧化与电化学沉积相结合的方法在镁合金(Mg-Zn-Zr)表面制备Ca-P生物陶瓷涂层.利用XRD、SEM、划痕仪、显微镜以及电化学工作站等测试手段来表征所得到的生物陶瓷的成分组成、表面形貌、涂层与机体的结合力、涂层厚度以及涂层材料的耐腐蚀性能.结果表明:在沉积溶液相同的情况下,沉积时间都为30 min,直流电沉积电流大小制备的Ca-P生物陶瓷涂层成分近似相同,主要成分为Ca HPO4·2H2O和Ca HPO4;在沉积电流为20 m A时,直流电沉积制备的Ca-P陶瓷涂层的腐蚀电位达到最大值-1.49 V,腐蚀电流密度达到最小值0.24×10-6A·cm-2,其耐蚀性能也最强.     

真空退火对ZnS与PbS混合薄膜结构和光学性质的影响

采用电子束蒸发的方法在石英基片上一次沉积厚度约为400nm的ZnS与PbS混合薄膜多个样品,随后将不同样品在3×10-3Pa的真空中分别以100～600℃退火1h.样品的成分、结晶性能、表面形貌和光学性质分别采用X射线能量色散谱、X射线衍射仪、扫描电子显微镜、原子力显微镜和分光光度计等进行检测.结果表明,制备态样品为非晶态,300℃真空退火的样品已开始结晶;当退火温度不低于500℃时,退火过程中,混合薄膜中的PbS大量挥发,退火后样品中的PbS含量明显减小.随着退火温度从100℃升高到600℃,样品的表面粗糙度和表面颗粒尺寸是先减小、后增大;光学透射率则呈现先升高后下降再升高的变化特性;退火后混合薄膜光学性质的变化与薄膜的成分、结晶性能和表面形貌的变化密切相关.     

电子束蒸发Al2O3/SiO2复合薄膜电学性能的研究

利用离子辅助电子束蒸发技术,在玻璃基底上以交替沉积的方式制备了A12O3/SiO2叠层复合薄膜,单层介质膜膜厚分别选取54和16 nm,总厚度为560 nm.采用步进法测试得到金属电极/复合绝缘膜/金属电极(MIM)结构的I-V特性曲线,具体成分为CrCuCr/(Al2O3/SiO2)8/CrCuCr,相应的厚度为80...     

EB-PVD制备硅基SiC薄膜及其性能研究

文章采用电子束蒸发物理气相沉积(EB-PVD)技术在单晶Si片上制备SiC薄膜,通过台阶仪(surface profiler)、原子力显微镜(AFM)、半导体综合测试仪、X射线衍射(XRD)和扫描电子显微镜(SEM)对薄膜表面形貌、电学性能及其结构进行分析.结果表明:SiC薄膜越厚,表面平均粗糙度越低;退火温度越高,薄膜结晶质量越好;对SiC薄膜进行辐照的光频率越高,光电流越大.     

Markedness and its Interpretation in Language Use

Language markedness is a common phenomenon in languages, and is reflected from hearing, vision and sense, i.e. the variation in the three aspects such as phonology, morphology and semantics. This paper focuses on the interpretation of markedness in language use following the three perspectives, i.e. pragmatic interpretation, psychological interpretation and cognitive interpretation, with an aim to define the function of markedness.     

Features of Women's language

Language is a means of verbal communication. People use language to communicate with each other. In the society, no two speakers are exactly alike in the way of speaking. Some differences are due to age, gender, statue and personality. Above all, gender is one of the obvious reasons. The writer of this paper tries to describe the features of women＇s language from these perspectives： pronunciation, intonation, diction, subjects, grammar and discourse. From the discussion of the features of women＇s language, more attention should be paid to language use in social context. What＇s more, the linguistic phenomena in a speaking community can be understood more thoroughly.     

低渗透非均质砂岩油藏启动压力梯度研究

理论推导与室内实验相结合,建立了低渗透非均质砂岩油藏启动压力梯度确定方法。首先借助油藏流场与电场相似的原理,推导了非均质砂岩油藏启动压力梯度计算公式。其次基于稳定流实验方法,建立了非均质砂岩油藏启动压力梯度测试方法。结果表明:低渗透非均质砂岩油藏的启动压力梯度确定遵循两个等效原则。平面非均质油藏的启动压力梯度等于各级渗透率段的启动压力梯度关于长度的加权平均;纵向非均质油藏的启动压力梯度等于各渗透率层的启动压力梯度关于渗透率与渗流面积乘积的加权平均。研究成果可用于有效指导低渗透非均质砂岩油藏的合理井距确定,促进该类油藏的高效开发。     

On Tragic Consciousness In The Works By Ernest Hemingway

As an American modern novelist who were famous in the literary world, Hemingway was not a person who always followed the trend but a sharp observer. At the same time, he was a tragedy maestro, he paid great attention on existence, fate and end-result. The dramatis personae's tragedy of his works was an extreme limit by all means tragedy on the meaning of fearless challenge that failed. The beauty of tragedy was not produced on the destruction of life, but now this kind of value was in the impact activity. They performed for the reader about the tragedy on challenging for the limit and the death.     

Achieving Unusual States of Matter Under High Pressure

正The periodicity of the elements and the non-reactivity of the inner-shell electrons are two related principles of chemistry,rooted in the atomic shell structure.Within compounds,Group I elements,for example,invariably assume the+1 oxidation state,and their chemical properties differ completely from those of the p-block elements.These general rules govern our understanding of chemical structures and reactions.Using first principles calcula-     

Exchange-Correlation and Electronic Excitation Energies from Pairing Matrix Fluctuations

We have developed an adiabatic connection to formulate the ground-state exchange-correlation energy in terms of pairing matrix linear fluctuations.This formulation of the exchange-correlation energy opens a new channel for density functional approximations based on the many-body perturbation theory.We illustrate the potential of such approaches with an approximation based on the particle-particle Random Phase Approximation(pp-RPA).This re-     

Density Functional Theory for the Response of Periodic Systems to Electric Fields Based on the Vector Potential Approach

正The electronic and nuclear(structural/vibrational)response of 1D-3D nanoscale systems to electric fields gives rise to a host of optical,mechanical,spectral,etc.properties that are of high theoretical and applied interest.Due to the computational difficulty of treating such large systems it is convenient to model them as infinite and periodic(at least,in first approximation).The fundamental theoretical/computational problem in doing so is that     

On the Thermodynamic Limit for Responses to Static Electromagnetic Fields

For molecular systems,the quantum-mechanical treatment of their responses to static electromagnetic fields usually employs a scalar-potential treatment of the electric field and a vector-potential treatment of the magnetic field.Although the potential for each field separately is associated with the choice of an(unphysical)origin,the precise choice of the origin for the electrostatic field has little consequences for the results.This is different for the     

Call for Papers

<正>"The Journal of Shanghai Normal University:Mathematics"is published by Shanghai Normal University as regular issues of The Journal of Shanghai Normal University each year from 2014 in English.The editors-in-chief of the issues are professors Yuhao Cong and Maoan Han.The Journal of Shanghai Normal University was started in 1958 with     

Journal of Donghua University ( English Edition) Contents of Volume 31

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