Boron- and silicon-bridged bis（diphenylphosphino）-type ligands for chromium-catalyzed ethylene oligomerization

PNP-type ligands showed very good property in the catalytic systems of PNP/Cr(Ⅲ)/methylaluminoxane(MAO)for ethylene selective tetramerization toward1-octene.In this research,two PNP analogues bis(diphenylphosphino)phenylborane and bis(diphenylphosphino)dimethylsilane have been synthesized and characterized.In combination with CrCl3(THF)3as active center and MAO as cocatalyst,these ligands produced a new catalytic systems for ethylene oligomerization to linear α-olefins with catalytic activities of up to 3.07 9 106g mol-1(cat)h-1.Herein,we report the effects of the reaction temperature,ethylene pressure,and the molar ratio of Al/Cr on the catalyst activities and product selectivities.     

Comparison of Parallelization Strategies for Min-Sum Decoding of Irregular LDPC Codes

Low-Density Parity-Check （LDPC） codes are powerful error correcting codes. LDPC decoders have been implemented as efficient error correction codes on dedicated VLSI hardware architectures in recent years. This paper describes two strategies to parallelize min-sum decoding of irregular LDPC codes. The first implements min-sum LDPC decoders on multicore platforms using OpenMP, while the other uses the Compute Unified Device Architecture （CUDA） to parallelize LDPC decoding on Graphics Processing Units （GPUs）. Empirical studies on data with various scales show that the performance of these decoding processes is improved by these parallel strategies and the GPUs provide more efficient, fast implementation decoder.     

Cross-layer resource allocation based on potential game theory in multi-cell OFDMA networks

A cross-layer resource allocation scheme based on potential game （CLRA _ PG） is proposed for the downlink multi-cell orthogonal frequency-division multiple-access （OFDMA） system with universal frequency reuse.As a method to mitigate inter-cell interference （ICI）,base station coordination has been considered.In the process of the objective function modeling,this paper adopts a pricing mechanism which not only maximizes the individual utility but also considers the interference to other users.Based on the potential game theory,the objective problem is converted to a potential function which can be easily solved.The Karush-Kuhn-Tucker （KKT） conditions and the iterative water-filling algorithm are employed to solve the constraint objective optimization problem.Moreover,extensive simulations are conducted to evaluate how the pricing factors affect the algorithm.At the same time,comparing with the traditional policy,our simulation results show that the proposed scheme can significantly improve the performance of the system.     

A method to compress vibration signals using wavelet packet transformation combined with sub-band vector quantization

A novel compression method for mechanical vibrating signals,binding with sub-band vector quantization （SVQ） by wavelet packet transformation （WPT） and discrete cosine transformation （DCT） is proposed.Firstly,the vibrating signal is decomposed into sub-bands by WPT.Then DCT and adaptive bit allocation are done per sub-band and SVQ is performed in each sub-band.It is noted that,after DCT,we only need to code the first components whose numbers are determined by the bits allocated to that sub-band.Through an actual signal,our algorithm is proven to improve the signal-to-noise ratio （SNR） of the reconstructed signal effectively,especially in the situation of lowrate transmission.     

An adaptive pipelining scheme for H.264/AVC CABAC decoder

An adaptive pipelining scheme for H.264/AVC context-based adaptive binary arithmetic coding （CABAC） decoder for high definition （HD） applications is proposed to solve data hazard problems coming from the data dependencies in CABAC decoding process.An efficiency model of CABAC decoding pipeline is derived according to the analysis of a common pipeline.Based on that,several adaptive strategies are provided.The pipelining scheme with these strategies can be adaptive to different types of syntax elements （SEs） and the pipeline will not stall during decoding process when these strategies are adopted.In addition,the decoder proposed can fully support H.264/AVC high 4 ∶ 2 ∶ 2 profile and the experimental results show that the efficiency of decoder is much higher than other architectures with one engine.Taking both performance and cost into consideration,our design makes a good tradeoff compared with other work and it is sufficient for HD real-time decoding.     

A Buffer Management Scheme for Packet Queues in MANET

We introduce a new scheme of buffer management to handle packet queues in Mobile Ad hoc Networks （MANETs） for fixed and mobile nodes. In this scheme, we try to achieve efficient queuing in the buffer of a centrally communicating MANET node through an active queue management strategy by assigning dynamic buffer space to all neighboring nodes in proportion to the number of packets received from neighbors and hence controlling packet drop probabilities. Our simulation study reveals that the proposed scheme is a way to improve the buffer management for packet queues in MANET nodes in terms of packet loss ratio, transmission efficiency, and some other important system parameters.     

Acquiring synonymous attribute phrases for named entities via online encyclopedia

In this work,an approach is proposed to acquire synonymous attribute phrases of named entities （NEs） from an online encyclopedia.Synonymous attribute phrases are the phrases that express the same attribute with different surface forms for a class of NEs.Specifically,the proposed approach is composed of three stages.Firstly,the entries related to a given NE class are automatically selected from an online encyclopedia.Secondly,attribute phrases are extracted based on the statistics of phrase frequency.Thirdly,synonymous attributes are identified in a pairwise manner through a classification framework combining multiple features.The proposed approach is applied on Baidu Baike,a Chinese online encyclopedia,for four different NE classes.Experimental results show that the approach obtains an average precision of 74％ and an average F-value of 65％ for the four NE classes.In particular,thousands of synonymous attribute phrase pairs are acquired for each class,which demonstrates the effectiveness of the proposed approach.     

Impact of public name resolving services on Akamai

To enhance user perceived performance,Akamai＇ s content distribution network （CDN） utilizes the domain name system （DNS） effectively to redirect users to close-by content replicas over short time scale.The use of DNS redirection has brought a significant advantage to Akamai＇ s CDN.However,the reliance on DNS also poses a fundamental threat to Akamai＇ s content distribution model.In particular,systematic evaluation and quantification illustrates the impact of recent emerging public DNS resolving services on Akamai＇ s CDN,including the degradation of corresponding user perceived performance and the benefit damnification of collaborating internet services providers （ISPs） that host Akamai＇ s edge servers.The measurement demonstrates that a considerable penetration of public DNS resolving services （e.g.,OpenDNS and GoogleDNS） effectively corrupts the Akamai＇ s serving model,namely the large-scale server distribution and quick DNS redirection.     

Subsurface macro-inclusions and solidified hook character in aluminum-killed deep-drawing steel slabs

Subsurface macro-inclusions and hooks are detrimental to the surface quality of deep-drawing steel sheets. However, little is known about the relationship between macro-inclusions and hooks. Thus, in this work, two ultralow carbon (ULC) steel slabs and two low carbon (LC) aluminum-killed steel slabs were sampled to study the relationship between hooks and subsurface macro-inclusions, which were detected on the cross-sections of steel samples with an area of 56058 mm2 using an automated scanning electron microscopy/energy-dispersive X-ray spectroscopy system. Results show that subsurface inclusions larger than 200 μm were almost entrapped by hook structures, whereas the location of other inclusions smaller than 200 μm had no obvious dependence on the location of solidified hooks. Furthermore, the number density (ND) of subsurface inclusions larger than 200 μm decreased from 0.02 to 0 cm-2 in ULC steel as the mean hook depth decreased from 1.57 to 1.01 mm. Similar trends were also observed in LC steel. In addition, the detected inclusions larger than 200 μm were concentrated in the region near the slab center (3/8 width-5/8 width), where hook depths were also larger than those at any other locations. Therefore, minimizing the hook depth is an effective way to reduce inclusion-induced sliver defects in deep-drawing steels.     

Synthesis and Characterization of Poly[ 2, 2- （m-phenylene） -5, 5-bibenzimidazole ] in 1-butyl-3-methylimidazolium Chloride

Poly[2,2-(m-phenylene)-5,5-bibenzimidazole](mPBI)were synthesized by mixing 3,3’,4,4’-tetraaminobiphenyl and isophthalic acid in 1-butyl-3-methylimidazolium chloride([BMIM]Cl).Intrinsic viscosity of mPBI polymers was 0.67 dL/g which was measured in 96%sulfuric acid.The polymer was characterized by Fourier transform infrared spectroscopy(FTIR),nuclear magnetic resonance(1H-NMR),and thermogravimetric analysis(TGA).The effects of polymerization conditions on the intrinsic viscosity of mPBI were investigated.It showed that the molecular weight of polymer mainly depended on pre-reaction time and reaction temperature.Comparison of structure and properties of mPBI synthesized in ionic liquids(ILs)and polyphosphoric acid was also reported.It indicates that the ionic liquids are a kind of good solvents in synthesis process of mPBI and ionic liquids mainly affect molecular weight of mPBI.     

Effects of basicity and MgO content on the viscosity of the SiO2-CaO-MgO-9wt%Al2O3 slag system

The effects of basicity and MgO content on the viscosity of SiO2-CaO-MgO-9wt%Al2O3 slags with basicity from 0.4 to 1.0 and MgO content from 13wt%to 19wt%were investigated using the rotating cylinder method. A correlation between the viscosity and the slag structure was determined by Fourier transform infrared （FTIR） spectroscopy. It is indicated that the complex network structure of the slag melt is depolymerized into simpler network units with increasing basicity or MgO content, resulting in a continuous decrease in viscosity of the slag. The viscosity is strongly dependent on the combined action of basic oxide components in the slag. Under the present experimental conditions, increasing the basicity is found to be more effective than increasing the MgO content in decreasing the viscosity of the slag. At higher temperatures, the increase of basicity or MgO content does not appreciably decrease the viscosity of the slag, as it does at lower tem-peratures. The calculated activation energy of viscous flow is between 154 and 200 kJ＆#183;mol-1, which decreases with an increase in basicity from 0.4 to 1.0 at a fixed MgO content in the range of 13wt%to 19wt%.     

CH4 retrieval from hyperspectral satellite measurements in short-wave infrared: sensitivity study and preliminary test with GOSAT data

One of the important science requirements of monitoring atmospheric methane abundances from hyperspectral measurements is to establish a highly accurate retrieval algorithm.This paper aimed to describe a retrieval algorithm based on a series of sensitivity study with an effective and accurate forward model,which was applied to realize online calculation of absorption coefficient and backscattered solar radiance.The sensitivity study consisted of band selection,interference factors analysis,and retrieval model construction.The band selection analysis indicated that the 1.65 lm band(5,900–6,150 cm-1)associated with the 2.06 lm band(4,800–4,900 cm-1)retained more than 90%of the information content of CH4,CO2,and temperature,and more than 85%of that of H2O in the retrieval.Investigation of the interference factors showed that H2O,temperature,and CO2will cause unacceptable errors if they are not revised.This also showed that revising temperature and H2O with a profile model is more efficient than with a temperature offset and a H2O scale factor model.A preliminarily test using the Greenhouse gases Observing SATellite Level 1B spectral data indicated that most of the retrieval errors were less than 1%,which is acceptable for methane flux estimation.     

Influence of Te doping on the dielectric and optical properties of InBi crystals grown by directional freezing

Stoichiometric pure and tellurium (Te) doped indium bismuthide (InBi) were grown using the directional freezing technique in a fabricated furnace. The X-ray diffraction profiles identified the crystallinity and phase composition. The surface topographical features were observed by scanning electron microscopy and atomic force microscopy. The energy dispersive analysis by X-rays was performed to identify the atomic proportion of elements. Studies on the temperature dependence of dielectric constant (?), loss tangent (tanδ), and AC conductivity (σ_ac) reveal the existence of a ferroelectric phase transition in the doped material at 403 K. When InBi is doped with tellurium (4.04 at%), a band gap of 0.20 eV can be achieved, and this is confirmed using Fourier transform infrared studies. The results thus show the conversion of semimetallic InBi to a semiconductor with the optical properties suitable for use in infrared detectors.     

Microstructure, crystallography and nucleation mechanism of NANOBAIN steel

The microstructure of bainite ferrite in NANOBAIN steel transformed at different temperatures was investigated by scanning electron microscopy, transmission electron microscopy, electron back-scattered diffraction, and vickers hardness tester in detail. It is found that the average width of bainitic ferrite (BF) plates can be refined to be thinner with the reduction of temperature (473–573 K), and the bainitic ferrite plates can reach up to 20–74 nm at 473 K. Crystallographic analysis reveals that the bainitic ferrite laths are close to the Nishiyama-Wasserman orientation relationship with their parent austenite. Temperature shows a significant effect on the variant selection, and a decrease in temperature generally weakens the variant selection. Thermodynamic analyses indicates that the Lacher, Fowler and Guggenheim (LFG) model is more suitable than the Kaufman, Radcliffe and Cohen (KRC) model dealing with NANOBAIN steel at a low temperature range. The free energy change ΔGγ→BF is about ?1500 J·mol?1 at 473 K, which indicates that nucleation in NANOBAIN steel is the shear mechanism. Finally, the formation of carbon poor regions is thermodynamically possible, and the existence of carbon poor regions can greatly increase the possibility of the shear mechanism.     

Cache performance optimization of irregular sparse matrix multiplication on modern multi-core CPU and GPU

This paper focuses on how to optimize the cache performance of sparse matrix-matrix multiplication （SpGEMM）.It classifies the cache misses into two categories：one is caused by the irregular distribution pattern of the multiplier-matrix,and the other is caused by the multiplicand.For each of them,the paper puts forward an optimization method respectively.The first hash based method removes cache misses of the 1 st category effectively,and improves the performance by a factor of 6 on an Intel 8-core CPU for the best cases.For cache misses of the 2nd category,it proposes a new cache replacement algorithm,which achieves a cache hit rate much higher than other historical knowledge based algorithms,and the algorithm is applicable on CELL and GPU.To further verify the effectiveness of our methods,we implement our algorithm on GPU,and the performance perfectly scales with the size of on-chip storage.     

A study on the characterization of smoke movement in shafts with different fire source positions

In this study, experimental and numerical simulation methods were combined to simulate the changing course of the temperature and velocity fields in nine different fire scenes. The characteristics of smoke movement in shafts with different fire source position factors （h/H） were quantitatively investigated, and the non-dimensional fitting function between the fire source position factors and the maximum temperature was deduced. The results showed that the location of the neutral plane moved upward as the fire source rose, and all the generated smoke spread to the upper areas; however, there was barely any smoke in the lower areas. The maximum temperature was inversely proportional to the fire source position factor; the higher the source position is, i.e. the higher the ra- tio factor is, the lower the maximum temperature is in the shaft. The experimental verification of the fire dynamics simulator （FDS） showed good results.     

Full-scale model tests and nonlinear analysis of prestressed concrete simply supported box girders

Full-scale model tests were carried out on a 30 m span prestressed concrete box girder and a 20 m span prestressed concrete hollow slab. Failure models were prestressed reinforcement tensile failure and crashing of roof concrete, respectively. The ductility indexes of the box girder and hollow slab were 1.99 and 1.23, respectively, according to the energy viewpoint. Based on the horizontal section hypothesis, the nonlinear computation procedure was established using the limited banding law, and it could carry out the entire performance analysis including the unloading, mainly focusing on the ways to achieve the unloading curves computation through stress-strain, moment-curvature and load-displacement curves. Through the procedure, parameters that influence on the bearing capacity, deformation performance and ductility of the structures were analyzed. Those parameters were quantity of prestressed reinforcement and tension coefficients of prestressed reinforcement. From the analysis, some useful conclusions can be obtained.     

Microstructure and mechanical properties of （Ti,AI,Zr）N/（Ti,AI,Zr,Cr）N films on cemented carbide substrates

（Ti,Al,Zr）N/（Ti,Al,Zr,Cr）N bilayer films were deposited on cemented carbide （WC-8%Co） substrates by multi-arc ion plating （MAIP） using two Ti-AI-Zr alloy targets and one pure Cr target. To investigate the composition, morphology, and crystalline structure of the bilayer films, a number of complementary methods of elemental and structural analysis were used, namely, scanning electron microscopy （SEM）, energy disperse X-ray spectroscopy （EDS）, and X-ray diffraction （XRD）. Adhesive strength and mechanical properties of the films were evaluated by scratch testing and Vickers microindentation, respectively. It is shown that the resulting films have a TiN-type face-centered cubic （FCC） structure. The films exhibit fully dense, uniform, and columnar morphology. Furthermore, as the bias voltages vary from -50 to -200 V, the microhardness （max. Hv001 4100） and adhesive strength （max. 〉 200 N） of the bilayer films are superior to those of the （Ti,Al,Zr）N and （Ti,Al,Zr, Cr）N monolayer films.     

Load compensation research on twicetension for loop anchor cable of inner lining in Yellow River-crossing tunnel

The load compensation equipment for anchor cable named low retraction prestressed anchorage system with twice-tension （referred to as twice-tension anchorage system） is proposed in the paper. Calculation results of loop anchorage prestressing loss （PL） values of inner lining （IL）in Yellow River-crossing tunnel under two anchorage systems, including twice-tension anchorage system and HM （Chinese transliteration is huanmao） anchorage system, are introduced. The software ANSYS is selected to realize the three-dimensional （3D） finite element modeling to accomplish simulation and calculation works under the two anchorage systems, respectively. Stress processes of IL under the two working conditions, of which one is completed cable tensioning （CCT） and the other is water in the tunnel with the designed water pressure （DWP）, are contrasted and analyzed. Impacts of prestressing forces of anchor cables on structural safety under the two anchorage systems are contrasted. The calculation results show that the twice-tension anchorage system can reduce PL effectively and then increase prestresses of wall concrete （WC）. Meanwhile, the anchorage system has the advantages of improving security and stability of tunnel structure, reducing project costs and saving steel consumption. The research work is available to related design and construction of anchor cable, and is worthy of promotion and application.