具有桥链七甲川菁染料的合成及其电子吸收光谱

合成了三个具有桥链的七甲川菁染料。研究染料结构对最大吸收波长的影响,并测定了染料在18种溶剂中的吸收光谱,发现染料的V_(max)~(ab)分别与溶剂的n~2-1/2n~2+1、(ε-n~2)(2ε+n~2)/ε(n+2)~2和((ε-1)/(ε+2))-((n~2-1)/(n~2+2))存在着良好的钱性关系。     

用阿基米德滚刀加工渐开线齿形的原理误差计算

分析了阿基米德滚刀加工渐开线齿形的原理误差,推导出滚刀切削刃连续位置的包络线方程及齿形误差的计算式:θ=(nβ)/(Hcos αcos λ)r2sin2α+2r2ha+ha2-((ρnβ)/(Hcos αcos λ))2-1+cos-1((H)/(ρnβ)cos αcos λ)-α△fF=ρ{[(1)/(cos α)((nβ)/(Hcos λ)-(1)/(r2))r22sin2α+2r2ha+ha2]-[((ρnβ)/(Hcos αcos λ))2-1-((ρ)/(r2cos α))2-1]+[cos-1((H)/(ρnβ)cos αcos λ)-cos-1((r2cos α)/(ρ))]}所用的方法,也可用于其它齿形的范成法.     

对称群的特征的计算

§1.引言设?_n是n个文字的n!阶对称群,x_ρ~(λ)表示划分(λ)=(λ_1,λ_2…,λ_s)对应于?_n的类ρ=(1~(α_1)2~(α_2)…n~(α_n))的特征,这里?我们知道,求x_ρ~((λ))与用α_1,α_2,…,α_l的多项式表示x_ρ~((nl,(μ)))的问题是密切相关的,且后者的应用此前者更为广泛,这里1≤l相似文献   

多元线性模型中一个协差阵函数的二次估计问题

考虑多元线性模型Y=X_1HX′_2+■,其中■=(ε_((1)),…,ε_((n)))′满足ε_((i)),i=1,…,n独立,ε_((i))～EC_p(0,Σ,φ)即ε_((i))服从椭球等高分布,Eε_((i))=0,Eε_((i))ε′_((i))=(ER~2/p)Σ,其中Σ≥0未知,φ已知且φ(?)Φ_p={φ(·)|φ(t_1~2+…+t_p~2)是一个特征函数},随机变量R≥0,R■φ.在α=ER~4/p(p+2)-(ER~2/p)~2≠0的条件下,对给定的矩阵C=C＇,得出了tr(CΣ)一致(关于Σ≥0)最小方差不变二次无偏估计(简称最优估计)存在的充要条件以及其具体形式.     

调幅波平均功率的讨论

本文通过积分证明了调幅波 u(t)=V_0.(1+m_a cos(aπ)/(T_n)t)cos((2π)/(T_0))t的平均功率P_调=(V_0~2)/(2R_1)(1+(1/2)m~2).指出了文献[3]中的错误之处.最后,用帕斯瓦尔定理对调幅波的平均功率做了进一步的简明解释.     

有限域上由两个广义对角多项式所确定的簇中的有理点

设Fq为有限域,f_l=a_(l1)x(~d~(l)_(11))_(11)…x~(d~((l))_(1_(k1)))_(1_(k1))+a_(l2)x~(d~((l))_(21))_(21)…x~(d~((l))_(2k_2)_(2k_2))+…+a_(ln)x~(d~((l))_(n1))_(n1)…x~(d~((l))_(nk_n)_(nk_n)+c_l(l=1,2)为F_q上的一组广义对角多项式,用N_q(V)表示由f_l(l=1,2)确定的族中的F_q有理点的个数.作者利用Adolphson和Sperber的牛顿多面体理论与指数和工具,证明了ord_qN_q(V)≥max{「∑~n_(i=1)1/d_i」-2,0,其中d_i=max{d~(1)_(ij),d~(2)_(ij)|1≤j≤k_i},1≤i≤n.     

论拟凸函数的相邻系数

1.设函数f_k(z)=z|+∑_(n-1)~∞a_(n+1)~((k)z~(k_n+1)在单位圆|z|<1内解析,并存在一函数g(z)=b_1z+b_2z~2+…(|b_1|=1)在|z|<1内解析,且g(z)/b_1∈S~*,使Re{zf′(z)/g(z)}>0。则设f(z)为拟凸函数,记其族为S_c~((k))·熟知S_c~((k))S·设f_k(z)=z+a_(n+1)~((k))z~(kn+1)∈S。要找出最好的α使下面的不等式成立:     

解析函数的单叶半径

对于单位圆|z|<1中的单叶函数f(z)=z+a_2z~2+…∈S,一个尚未解决的问题是:g(z)=1/2(zf(z))’在圆|z|<1/2中是否具有单叶性?目前最好的结果是1978年S.W.Barnsrd所得到的:当f(z)∈S时,2g(z)=(zf(z))’必在|z|≤0.49中是单叶的.对于星象函数,或者近于凸象函数,这个问题已经解决.对于后次对称的单叶函数f(z)=z+a_(k+1)~((k))Z~(k+1)+a_(2k+1)~((k))Z~(2k+1)+…,开始两项σ_2(z)=z+a_(k+1)~((k))Z~(k+1)及三项σ_3(Z)=σ_2(Z)+a_(2k+1)~((k))Z~(2k+1)在圆|Z|~k相似文献   

广义Baskakov-Bézier算子的逼近

定义了广义Baskakov-Bézier算子,并应用一阶Ditzian-Totik模和K泛函得到了广义Baskakov-Bézier算子逼近的正、逆定理以及等价定理,即∣V_(n+a)~*(f,x)-f(x)∣=O((ч)~(1-λ)(x)/√n)~(δ/2))当且仅当ω_(ч)~λ(f,t)=O(t~δ),其中,0≤λ≤1,0＜δ＜1,(ч)(x)=√x(1+βx)     

方差估计以及两个方差分量同时估计的可容许性

考虑线性模型 EY_(n×i)=X_(n×)β_(n×i) DY=σ~2V,V≥0,σ~2>0未知 (*)以及方差分量模型 EY_(n×i)=X_(n)β_(n×i) DY=σ_1:V_i+σ_2V_2,V_i≥0,V_2≥0,σ_i,σ_2>O未知 (**)其中γ(X_(n×m)=n,对模型(*)令D={d(A)=Y＇AY,A≥0}损失函数为L~(1)(d(A),σ~2)=σ~(-4)(Y＇AY-σ~2)~2,对模型(**)令D~(2)={d(A_i,A_2)=(Y＇A_iY,Y＇A_2Y),A_i≥0,A_2≥0},损失函数为L~(2)(d(A_i,A_2),(σ_i,σ_2))=σ_i(Y＇A_iY-σ_i)~2+σ_2(Y＇A_2Y-σ_2)~2,本文对模型(*)给出了d(A)为σ~2的D~(1)容许估计的充分条件,对模型(**)给出了在V_i+V_2>0的限制下,d(A_i,A_2)为(σ_i~2,σ_2~2)的D~(2)容许估计的充分条件。分别推广了文[3],[5]中的有关结果。     

Markedness and its Interpretation in Language Use

Language markedness is a common phenomenon in languages, and is reflected from hearing, vision and sense, i.e. the variation in the three aspects such as phonology, morphology and semantics. This paper focuses on the interpretation of markedness in language use following the three perspectives, i.e. pragmatic interpretation, psychological interpretation and cognitive interpretation, with an aim to define the function of markedness.     

低渗透非均质砂岩油藏启动压力梯度研究

理论推导与室内实验相结合,建立了低渗透非均质砂岩油藏启动压力梯度确定方法。首先借助油藏流场与电场相似的原理,推导了非均质砂岩油藏启动压力梯度计算公式。其次基于稳定流实验方法,建立了非均质砂岩油藏启动压力梯度测试方法。结果表明:低渗透非均质砂岩油藏的启动压力梯度确定遵循两个等效原则。平面非均质油藏的启动压力梯度等于各级渗透率段的启动压力梯度关于长度的加权平均;纵向非均质油藏的启动压力梯度等于各渗透率层的启动压力梯度关于渗透率与渗流面积乘积的加权平均。研究成果可用于有效指导低渗透非均质砂岩油藏的合理井距确定,促进该类油藏的高效开发。     

On Tragic Consciousness In The Works By Ernest Hemingway

As an American modern novelist who were famous in the literary world, Hemingway was not a person who always followed the trend but a sharp observer. At the same time, he was a tragedy maestro, he paid great attention on existence, fate and end-result. The dramatis personae's tragedy of his works was an extreme limit by all means tragedy on the meaning of fearless challenge that failed. The beauty of tragedy was not produced on the destruction of life, but now this kind of value was in the impact activity. They performed for the reader about the tragedy on challenging for the limit and the death.     

Achieving Unusual States of Matter Under High Pressure

正The periodicity of the elements and the non-reactivity of the inner-shell electrons are two related principles of chemistry,rooted in the atomic shell structure.Within compounds,Group I elements,for example,invariably assume the+1 oxidation state,and their chemical properties differ completely from those of the p-block elements.These general rules govern our understanding of chemical structures and reactions.Using first principles calcula-     

Exchange-Correlation and Electronic Excitation Energies from Pairing Matrix Fluctuations

We have developed an adiabatic connection to formulate the ground-state exchange-correlation energy in terms of pairing matrix linear fluctuations.This formulation of the exchange-correlation energy opens a new channel for density functional approximations based on the many-body perturbation theory.We illustrate the potential of such approaches with an approximation based on the particle-particle Random Phase Approximation(pp-RPA).This re-     

Density Functional Theory for the Response of Periodic Systems to Electric Fields Based on the Vector Potential Approach

正The electronic and nuclear(structural/vibrational)response of 1D-3D nanoscale systems to electric fields gives rise to a host of optical,mechanical,spectral,etc.properties that are of high theoretical and applied interest.Due to the computational difficulty of treating such large systems it is convenient to model them as infinite and periodic(at least,in first approximation).The fundamental theoretical/computational problem in doing so is that     

On the Thermodynamic Limit for Responses to Static Electromagnetic Fields

For molecular systems,the quantum-mechanical treatment of their responses to static electromagnetic fields usually employs a scalar-potential treatment of the electric field and a vector-potential treatment of the magnetic field.Although the potential for each field separately is associated with the choice of an(unphysical)origin,the precise choice of the origin for the electrostatic field has little consequences for the results.This is different for the     

An affordable accurate evaluation of the binding conformations predicted by molecular docking studies in bio-system

Franck-Condon factors bridge the gap between theoretical modeling and experimental observations for molecular electronic spectroscopy and electron transfer.Under the displaced harmonic oscillator approximation,multidimensional Franck-Condon factors are decomposed into a product of many one-dimensional(1D)Franck-Condon(FC)factors,and each 1D-FC factor is associated with one Huang-Rhys factor that determines the leading contribution of     

Call for Papers

<正>"The Journal of Shanghai Normal University:Mathematics"is published by Shanghai Normal University as regular issues of The Journal of Shanghai Normal University each year from 2014 in English.The editors-in-chief of the issues are professors Yuhao Cong and Maoan Han.The Journal of Shanghai Normal University was started in 1958 with     

Journal of Donghua University ( English Edition) Contents of Volume 31

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