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1.
采用浸渍法制备了系列NiO/γ-Al2O3,NiO/TiO2-Al2O3催化剂样品,用XRD,EXAFS等方法对这些样品进行了分析.XRD相定量方法测得NiO在γ-Al2O3载体上的最大分散量为0.065gNiO/100m2Al2O3,而NiO在TiO2-Al2O3载体上的最大分散量为0.081gNiO/100m2TiO2Al2O3。EXAFS分析结果表明:TiO2的引入改变了NiO在载体表面上的分散状态.  相似文献   

2.
对纤维状催化剂ACF吸附SO2动力学进行了探讨,结果表明:ACF吸附速度快、吸附平衡时间短、平衡吸附量大;其结构变化对吸附动力学有影响;Bangham和Langmuir吸附速度方程在ACF对SO2吸附体系有一定的适用性.  相似文献   

3.
以石油中间产品为原料合成了烃基苯磺酸盐表面活性剂AS-4,AS-5,AS-6。实验表明,AS水溶液/碱/原油体系具有10^-2mN/m以下的最小界面张力,讨论了异构体组分相对含量,合成的超始原料,平均分子量对AS产物水溶液与原油的界面活性的影响。  相似文献   

4.
Al_2O_3 弥散 Ti(C,N)基金属陶瓷刀具   总被引:1,自引:0,他引:1  
在Ti(C,N)基金属陶瓷中,通过加入Al2O3弥散颗粒,使材料的硬度和高温性能都得到提高,从而获得更好的切削耐磨性。研究结果表明:Al2O3的引入使Ti(C,N)基金属陶瓷的常温强度和韧性有所下降而硬度和高温力学性能得到了改善。切削试验表明:Ti(C,N)-Al2O3系金属陶瓷比硬质合金、Al2O3-TiC复合陶瓷刀具有更好的切削性能。SEM观察表明:在Ti(C,N)-Al2O3金属陶瓷中,Al2O3与Ti(C,N)有相互抑制晶粒生长的作用,使Ti(C,N)基金属陶瓷的晶粒更细化  相似文献   

5.
本文对TiO2负载Ni、Cu和Ni—Cu合金催化剂中SMSI效应,及其对CO加氢性能的影响进行了分析研究。实验结果表明,载于TiO2上的金属组分与载体间发生了相互作用,主要表现在对H2和CO吸附的变化及还原温度的提高;载体TiO2的作用是使CO的吸附出现了线式和桥式吸附态外的卧式吸附态(M…C=O→Tin+),引起CO活化程度的提高,有利于C=O键的断裂而形成表面碳物种;双金属Ni、Cu间发生相互作用而形成了均匀的合金相,该活性组分与载体TiO2的共同作用,对CO加氢中C2物种,特别是乙烯的生成有利。  相似文献   

6.
油菜萝卜胞质不育系恢复材料Ad-6(F4)测交二代恢复株TCF2,在MS附加5m g/L6-BA+ 0.5m g/L NAA,3m g/L 6-BA+ 0.2m g/L NAA,3m g/L 6-BA+ 0.3m g/L NAA+600m g/L水解乳蛋白以及5m g/L6-BA+ 0.3m g/LNAA+ 5m g/LAgNO3 的不同培养基上诱导丛生芽,结果表明5m g/L6-BA+ 0.3m g/LNAA+ 5m g/LAgNO3 对TCF2 诱导丛生芽有较好的效果.小芽生根培养基为1/2MS效果最好.  相似文献   

7.
FLUXDYNAMICSOFTISr_2Ca_2Cu_3O_ySUPERCONDUCTORINTHETIMEWINDOWOFMILLISECONDS¥DingShiying1);WangGuoqiang1);RenCong1);LinJianwei2...  相似文献   

8.
F~-离子和Ti~(4+)离子在CaO-Al_2O_3-SiO_2系玻璃晶化时的作用   总被引:3,自引:0,他引:3  
在CaO-Al2O3-SiO2(CAS)系玻璃中单独引入F-离子或Ti4+离子,以及同时引入F-离子和Ti4+离子,通过DTA(差热分析)、XRD(X-射线衍射)、Raman、XPS(光电子能谱)和SEM(扫描电镜)方法进行了研究。结果表明在CAS系玻璃中一部分F-离子取代非桥氧离子处于玻璃网络内部,另一部分F-离子处于玻璃网络间隙,F-离子能促使CAS系玻璃分相,在稍高于Tg的某一温度热处理时,CaF2晶体首先从玻璃中析出;Ti4+离子对玻璃晶化影响不大,在稍高于Tg的某一温度热处理时,加Ti4+离子和不加Ti4+离子的玻璃首先析出的晶相均是钙长石(CaAl2Si2O8);在CAS系玻璃中同时引入F-离和Ti4+离子时,在稍高于Tg的某一温度热处理后首先析出的晶体是CaF2和钙长石(CaAl2Si2O8),F-离子和Ti4+离子混合使用能更好地促进CAS系玻璃的晶化。  相似文献   

9.
THEMOTIONPROPERTIESOFTHESTARSCONFINEDTOTHESYMMETRICAXISOFANOSCILLATIONKUZMINDISKFuYanning1,2)SunYisui1)(1)DepartmentofAstron...  相似文献   

10.
绿丰收对小白菜生长及产量的影响(简报)朱京涛1黄云祥2(1河北农业技术师范学院园艺系,2黄腐酸研究所,昌黎,066600)THEINFLUENCEOFLUFENGSHOUONTHEGROWTHANDYIELDOFSMALLCHINESECABBAGE...  相似文献   

11.
Language markedness is a common phenomenon in languages, and is reflected from hearing, vision and sense, i.e. the variation in the three aspects such as phonology, morphology and semantics. This paper focuses on the interpretation of markedness in language use following the three perspectives, i.e. pragmatic interpretation, psychological interpretation and cognitive interpretation, with an aim to define the function of markedness.  相似文献   

12.
何延凌 《科技信息》2008,(4):258-258
Language is a means of verbal communication. People use language to communicate with each other. In the society, no two speakers are exactly alike in the way of speaking. Some differences are due to age, gender, statue and personality. Above all, gender is one of the obvious reasons. The writer of this paper tries to describe the features of women's language from these perspectives: pronunciation, intonation, diction, subjects, grammar and discourse. From the discussion of the features of women's language, more attention should be paid to language use in social context. What's more, the linguistic phenomena in a speaking community can be understood more thoroughly.  相似文献   

13.
王慧 《科技信息》2008,(10):240-240
Wuthering Heights, Emily Bronte's only novel, was published in December of 1847 under the pseudonym Ellis Bell. The book did not gain immediate success, but it is now thought one of the finest novels in the English language. Catherine is the key character of this masterpiece, because everybody and everything center on her though she had a short life. We can understand this masterpiece better if we know Catherine well.  相似文献   

14.
The Williston Basin is a significant petroleum province, containing oil production zones that include the Middle Cambrian to Lower Ordovician, Upper Ordovician, Middle Devonian, Upper Devonian and Mississippian and within the Jurassic and Cretaceous. The oils of the Williston Basin exhibit a wide range of geochemical characteristics defined as "oil families", although the geochemical signature of the Cambrian Deadwood Formation and Lower Ordovician Winnipeg reservoired oils does not match any "oil family". Despite their close stratigraphic proximity, it is evident that the oils of the Lower Palaeozoic within the Williston Basin are distinct. This suggests the presence of a new "oil family" within the Williston Basin. Diagnostic geochemical signatures occur in the gasoline range chromatograms, within saturate fraction gas chromatograms and biomarker fingerprints. However, some of the established criteria and cross-plots that are currently used to segregate oils into distinct genetic families within the basin do not always meet with success, particularly when applied to the Lower Palaeozoic oils of the Deadwood and Winnipeg Formation.  相似文献   

15.
理论推导与室内实验相结合,建立了低渗透非均质砂岩油藏启动压力梯度确定方法。首先借助油藏流场与电场相似的原理,推导了非均质砂岩油藏启动压力梯度计算公式。其次基于稳定流实验方法,建立了非均质砂岩油藏启动压力梯度测试方法。结果表明:低渗透非均质砂岩油藏的启动压力梯度确定遵循两个等效原则。平面非均质油藏的启动压力梯度等于各级渗透率段的启动压力梯度关于长度的加权平均;纵向非均质油藏的启动压力梯度等于各渗透率层的启动压力梯度关于渗透率与渗流面积乘积的加权平均。研究成果可用于有效指导低渗透非均质砂岩油藏的合理井距确定,促进该类油藏的高效开发。  相似文献   

16.
As an American modern novelist who were famous in the literary world, Hemingway was not a person who always followed the trend but a sharp observer. At the same time, he was a tragedy maestro, he paid great attention on existence, fate and end-result. The dramatis personae's tragedy of his works was an extreme limit by all means tragedy on the meaning of fearless challenge that failed. The beauty of tragedy was not produced on the destruction of life, but now this kind of value was in the impact activity. They performed for the reader about the tragedy on challenging for the limit and the death.  相似文献   

17.
正The periodicity of the elements and the non-reactivity of the inner-shell electrons are two related principles of chemistry,rooted in the atomic shell structure.Within compounds,Group I elements,for example,invariably assume the+1 oxidation state,and their chemical properties differ completely from those of the p-block elements.These general rules govern our understanding of chemical structures and reactions.Using first principles calcula-  相似文献   

18.
We have developed an adiabatic connection to formulate the ground-state exchange-correlation energy in terms of pairing matrix linear fluctuations.This formulation of the exchange-correlation energy opens a new channel for density functional approximations based on the many-body perturbation theory.We illustrate the potential of such approaches with an approximation based on the particle-particle Random Phase Approximation(pp-RPA).This re-  相似文献   

19.
正The electronic and nuclear(structural/vibrational)response of 1D-3D nanoscale systems to electric fields gives rise to a host of optical,mechanical,spectral,etc.properties that are of high theoretical and applied interest.Due to the computational difficulty of treating such large systems it is convenient to model them as infinite and periodic(at least,in first approximation).The fundamental theoretical/computational problem in doing so is that  相似文献   

20.
For molecular systems,the quantum-mechanical treatment of their responses to static electromagnetic fields usually employs a scalar-potential treatment of the electric field and a vector-potential treatment of the magnetic field.Although the potential for each field separately is associated with the choice of an(unphysical)origin,the precise choice of the origin for the electrostatic field has little consequences for the results.This is different for the  相似文献   

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