Characteristics of strontium isotopes and their implications in the Qixing Cave of Guizhou,China

The strontium isotopic compositions (87Sr/86Sr) of samples including soils, bedrock, soil waters, drip waters and their corresponding speleothems in the Qixing Cave (QXC), Guizhou Province, China, were systemically measured and analyzed. The results indicate that there are significant Sr isotopic differences among samples. The mean 87Sr/86Sr ratios in drip water for the samples 1#, 4# and 9# were 0.709568, 0.709139 and 0.708761, respectively, which possibly result from different flow paths, residence times, and other hydrogeological processes in the unsaturated zone overlying QXC. Meanwhile, levels of 40.8%, 57.6% and 72.4% of Sr in drip waters for 1#, 4# and 9#, respectively, were derived from bedrock dissolution, which was calculated by the mixture model of the two end-members (soil and bedrock). There is, however, no positive correlation between the relative proportion from bedrock dissolution (δ13C value is 1.8‰) and drip water δ13CDIC values. The mean drip water δ13CDIC value in 1# is the heaviest (–4.5‰) with the lowest contribution rate of bedrock dissolution, whereas the value in 9# is the lightest (–9.3‰) with the highest contribution rate of bedrock dissolution. The proportion from host rock dissolution in 4# is higher than that in 1# and lower than that in 9#, while its mean drip water δ13CDIC value (–8.6‰) is higher than that of 9# and lower than that for 1#. This suggests that the prior calcite precipitation (PCP) processes in the unsaturated zone overlying the cave are responsible for the δ13CDIC value differences between different drip waters, and not bedrock dissolution. Furthermore, this study also demonstrates that the 87Sr/86Sr ratios of speleothems in the 1# and 4# mainly reflect the variation in the relative proportions from the soil system (soil water) and bedrock dissolution overlying the cave. It is, therefore, feasible to use the strontium isotopic signals of speleothems as an indicator for soil chemical weathering intensity, and consequently as a monsoon proxy in the study area.     

四川盆地西部海相碎屑岩-陆相碎屑岩的转换过程

四川盆地是一个叠合盆地,经历了海相碳酸盐岩到海相碎屑岩、海相碎屑岩到陆相碎屑岩的转换和变迁.这两个转换过程最终结束均发生在四川盆地西部.海相碎屑岩到陆相碎屑岩的转换发生在晚三叠世末,相对应的地层单位为上三叠统须家河组.通过对须家河组厚度和沉积相变化,以及龙门山前砾岩的分布特征研究,认为这一转换主要发生于须家河组沉积末期(T_3x~4-T_3x~6),时间上随地区不同而不同,空间上具有由北往南的先后顺序.这揭示龙门山造山带的造山隆升过程具有由北往南的特点.这一转换过程导致川西前陆盆地内南、北段油气地质条件存在差异.寻找河口沙坝、三角洲平原河道砂等形成的优质储层应是须家河组油气勘探的关键.     

Evidence from carbon isotope measurements for biological origins of individual longchainn-alkanes in sediments from the Nansha Sea, China

Carbon isotopes are measured for individual long-chain n-alkanes in sediments from the Nansha Sea. The features of carbon isotopic compositions of individual n-alkanes and their origins are studied. The results show that the long-chain n-aikanes have a light carbon isotopic composition and a genetic feature of mixing sources, and low-latitude higher plants and microbes are considered to be their main end member sources. Based on the abundances and carbon isotopic compositions of individual n-alkanes, the fractional contributions of the two end member sources to individual n-aikanes are quantitatively calculated by using a mixing model. The obtained data indicate that the fractional contributions of the two biological sources are different in the three samples. A trend is that the contribution of microbes increases with the depth. These results provide the theory basis and quantitatively studied method for carbon isotopic applied research of individual n-alkanes.     

Origin of ore-forming fluids of the Dachang Sn-polymetallic ore deposit: Evidence from helium isotopes

The ore genesis model for the Dachang Sn- polymetallic ore deposit has long been in dispute, and the major debate focuses on whether the stratiform and massive orebodies formed during the Yanshanian magmatic-hydro- thermal event or they were products of Devonian syn-sedimentary exhalative-hydrothermal event. This note presents new helium isotope data from fluid inclusions of four pyrites and one fluorite. The pyrites were collected from the stratiform and massive orebodies in the deposit, and their 3He/4He ratios are significantly higher than 1, ranging from 1.7 to 2.5 Ra, which indicates a mantle component in the responsible hydrothermal fluids. It is suggested that the ore-forming fluids were a mixture of deep circulating seawater and a mantle-derived fluid, which are similar to many of those modern submarine hydrothermal fluids. In contrast, the fluorite, collected from a granite-related hydrothermal vein in the deposit, shows a low 3He/4He ratio of 0.7 Ra, which indicates no mantle component involvement in the fluids. Hence, the helium isotope data indicate that the two kinds of fluids from the Dachang deposit may have different origins. Together with other geological and geochemical evidence, it is suggested that the stratiform and massive ore formation has no genetic relation to the Yanshanian granite. Rather, they were likely formed during Devonian submarine exhalative-hydrothermal processes.     

Chondritic osmium isotopic composition of late Archean convecting upper mantle：Evidence from Zunhua podiform chromitites,Hebei, North China

The Os isotopic composition and evolution of con-vecting upper mantle (CUM) are an important and diffi-cult scientific issue related to the distributions of PGEs inearth’s interior and the accretion history of the earth. De-termination of 187Os/188Os of modern CUM has been at-tempted via analyses of abyssal peridotites, mid-oceanridge basalts (MORB), MORB glasses and sulfides. Abyssal peridotites, which are mantle samples re-covered from the ocean ridges, represent the upperm…     

第四纪湖相介形类组合的古气候与古环境意义:以洞庭盆地介形类现生种为例

本文在分析国内外第四纪湖相介形类组合古气候与古环境意义研究现状基础上,初步研究了洞庭湖湘阴近岸介形类现生种分布与生态特征.国外在第四纪湖相介形类古气候与古环境研究方面做了大量工作,取得了丰富成果.而国内该方面工作仅主要集中青藏高原及其邻区,其它地区鲜见.国外在详细介形类现生种生态调查基础上,建立基于其的环境参数转换函数,并在第四纪古气候与古环境定量重建中发挥了重要作用.然而我国现生种生态调查依然薄弱,主要表现在1)仅主要集中青藏高原等少数地区,其它地区还很少;2)生境数据绝大多为定性或半定量,很少定量;3)很少按季节采样.洞庭湖湘阴近岸包含3个属种,分别为未定种、Metacypris bellareticulata及Darwinula sp.,它们的生态要求为电导率240μs/cm,溶氧量10.45 mg/L,p H值8.1,水深0.5-1 m,水温10℃.     

中国三叠系陆相砂岩中自生绿泥石的形成机制及其与储层孔隙保存的关系

研究了中国三叠系陆相砂岩中自生绿泥石的产状、成因及其与储层发育的关系,证明了以孔隙环边衬里方式产出的绿泥石是深埋地层中孔隙保存的重要机制,环边绿泥石的沉淀及其在成岩过程中的再生长不仅提高了岩石的机械强度和抗压实能力,还降低了自生石英在碎屑颗粒上的成核数量并抑制石英的次生加大,从而使砂岩中的原生和次生孔隙得以保存.砂岩中自生绿泥石的成因还表明这种产状的绿泥石是三角洲前缘推进的良好标志,同时也说明中国中新生代的湖泊可能并不是真正的淡水湖泊,它们或多或少具有一定的盐度,其对海源流体具有继承性.     

Mo isotopes in the Lower Cambrian formation of southern China and its implications on paleo-ocean environment

Over the past decade, as one of nontraditional stable isotopes, Mo isotope has developed rapidly and now become an important geochemical proxy to trace paleo-oceanic and atmospheric evolution through geological history. In this paper, Early Cambrian formations in southern China are investigated. The results indicate that δ 97/95Mo values of Early Cambrian seawater may have been larger than 1.4‰, values that are close to those of the modern ocean. It was also found that the variations in Mo isotope composition in samples from two sections （Huangjiawan and Gezhongwu in Guizhou） were closely related to changes in redox conditions during sedimentary processes. Combining our results with existing data, a preliminary model for the evolution of seawater Mo isotope composition through geological history was provided. It indicated that Mo isotopic variations were generally consistent with the evolution of atmospheric oxygen.     

Fine grain IRSL and GLSL dating of late Quaternary sediments from North China

A possible approach to assess the fine grain OSL dating is discussed through comparison of equivalent dose (D_E) values and ages obtained by IRSL and GLSL of fine grains for 31 sediment samples from North China. The IRSL and GLSL were measured with the same aliquots for each sample, i.e. shine-down was by 100 s of IRSL (880 nm) followed by 100 s of GLSL (514 nm) on the same discs. The D_E values and ages found by IRSL are in good agreement with those by GLSL within 1—2σ for 80% samples, especially for aeolian loess samples. Considering that IRSL from feldspar differs obviously from GLSL dominated from quartz in dose response, thermal stability and optical bleaching characteristic, the agreement between the D_E values may be taken as evidence that the two clocks of IRSL and GLSL had been well reset during deposition. The consistent ages of IRSL and GLSL, in turn, may be referred to an indicator to evaluate the fine grain OSL dating of sediments.     

Temperature variations in the past 6000 years inferred from δ18O of peat cellulose from Hongyuan, China

Trends of the temperature variations recorded in δ18O in Hongyuan peat cellulose are similar to those recorded in δ 18O of Jinchuan peat cellulose and inδ18O of Dunde ice core. Climate events have been identified to be globallyhomogeneous. Two notable climate transition periods have been detected in the past 6000 years, namely 4000 aBP with climate shifting from cold to warm and 1500aBP with climate shifting from warm to relatively cold. Power spectrum analysiswas performed to investigate the periodical signals in the δ18O time series. Typical periodicities of 1200-1087 a, 752 a, 444 a, 325 a, 213 a, 127-123 a, 88a, 79 a were discovered, indicating an integrated influence on Hongyuan climatefrom solar, monsoon and ocean activities. Solar forcing has been addressed to be the main driving forcing of Hongyuan climate.     

Hydrogen isotopic compositions and their environmental significance for individual n-alkanes in typical plants from land in China

Hydrogen isotopes of n-alkanes in grasses, tree leaves and reeds from six regions with latitudes of 20° to 39°N in China are measured by GC-TC-IRMS analytical technique in order to understand their hy- drogen isotopic compositions and environmental significance. The results show that a difference in δ D values (from -42.1‰ to -66.6‰) of n-alkanes exists among the same kinds of plants from various re- gions. Hydrogen isotopic compositions of most even carbon numbered n-alkanes in every plant are slightly hea...     

Intergrowth texture in Au-Ag-Te minerals from Sandaowanzi gold deposit, Heilongjiang Province: Implications for ore-forming environment

Sandaowanzi gold deposit,Heilongjiang Province,is the only single telluride type gold deposit so far documented in the world,in which 90% of gold is hosted in gold-silver telluride minerals.Optical microscope observation,scanning electron microscope,electron probe and X-ray diffraction analysis identified abundant intergrowth textures in the Au-Ag-Te minerals,typified by sylvanite-hosting hessite crystals and hessite-hosting petzite crystals.The intergrown minerals and their chemistry are consistent,and the hosted minerals are mostly worm-like or as oriented stripes,evenly distributed in the hosting minerals,with clear and smooth interfaces.These suggest an exsolution origin for the intergrowth texture.With reference to the phase-transformation temperature derived from synthesis experiments of tellurides,the exsolution texture of Au-Ag-Te minerals implies that the veined tellurides formed at 150-220℃.The early stage disseminated tellurides formed at log f(Te 2) from 13.6 to 7.8,log f(S 2) from 11.7 to 7.6,whereas the late stage veined tellurides formed at log f(Te 2) ranging from 11.2 to 9.7 and log f(S 2) from 16.8 to 12.2.     

45钢固体粉末法稀土、硼、铬、铝共渗工艺研究

研究了RE_Mg合金对固体粉末法硼、铬、铝共渗层成分、组织和性能的影响 .发现随着RE_Mg合金加入量的增加 ,渗层中Al2 O3的量不断增多 ,当RE_Mg合金加入量为 5 %时 ,渗层中出现连续致密分布的Al2 O3黑区组织 ,对此进行了性能测试和机理探讨     

Origin of ore-forming fluid in the Piaotang tungsten deposit in Jiangxi Province: Evidence from helium and argon isotopes

The Piaotang tungsten deposit in Jiangxi Province is one of the most important tungsten deposits in the South China Tungsten Metallogenic Province.In this study,we selected wolframite and chalcopyrite from the main mineralizing stage of the Piaotang tungsten deposit,and analyzed the helium and argon isotopic compositions in fluid inclusions of these minerals.The results show a 3He/4He ratio of 0.17 to 0.86 R/Ra,which fall within the range between continental crust(0.01―0.05 R/Ra) and air-saturated water(1 R...     

The age measures and its layer sequence tratigraphy of Late Quaternary sediment in Lushan Dajiaochang of China

Through the scientific investigation on Lushan for a long time, detailed studies have been carried out on the geologic stratum section of Late Quaternary in Dajiaochang. The series age data of complete stratigraphic section and full time formation since 400 kaBP were based on the results of the analyses using the dating methods with various instruments such as the ancient geomagnetism, electronics spin resonance （ESR）, 36C1 and lumines- cence dating, etc. Corresponding to these data, it identified the paleomagnetic polarity events including Biwa- III event （320 kaBP）, Biwa- 1I event （260 kaBP）, Biwa- I event （180 kaBP, scarcity due to the disturbance of the iron dish）, Blake event （100 kaBP） and Laschamp event （20 kaBP, didn＇t grow due to the activities of the surface）, etc. Combined with the sequence stratigraphy, layer type characteristics and its sediment environment, the strati- graphic can be divided into 4 stages of development respectively ： Stage [ is the climate period of glacial epoch （200-400 kaBP）; stage 11 is the climate period of interglacial epoch （100-200 kaBP）; stage llI is the climate peri- od of periglacial epoch （10-100 kaBP）; stage IV is the climate period ofpostglacial epoch （0-10 kaBP）.     

Strontium isotopic signature of hydrothermal sedimentation from Early Cambrian barite deposits in east Guizhou,China

The ore genesis model for barite deposits in east Guizhou Province has been in dispute and the major debate focuses on whether they are product of the submarine hydrothermal sedimentation. This note presents new strontium isotope data from 19 samples of Dahebian and Yuping barite deposits, and their ^87Sr/^86Sr ratios are significantly lower than that of the coeval seawater. The ^87Sr/^86Sr ratios of 17 samples out of 19 samples rang from 0.708310 to 0.708967, indicating that they might be related to the mantel admixture. Two isotopic ratios in this study are higher than those of coeval seawater (0.7090), collected from late-stage barite mineral vein of interpenetrative strata and a barite nodule bearing hypidiomorphic granular pyrite, which indicates that they might be related to the continental admixture. The study provides Sr isotopic evidence not only for the submarine hydrothermal exhalative genesis of Dahebian and Yuping barite deposits, but also for distinguishing the barite mineralization of late stage.     

德兴铜厂斑岩铜矿流体过程

从德兴斑岩铜矿床中蚀变矿物、包裹体记录及同位素组成的时空变化，示踪成矿热液流体来源、演化过程及迁移途径。氧、锶同位素空间变化表明，虽然与铜厂斑岩铜矿成矿过程有关的热液流体至少有3种，包括高温岩浆流体、来自深部围岩的非岩浆流体和大气降水，但是起主导作用的是岩浆流体。岩浆流体通过沸腾作用或不混溶作用而形成，它携带成矿物质从深部向上部及边部迁移、聚集，并在演化过程中引起围岩蚀变和金矿矿化。铜厂地区存在着两种不同成因的伊利石，热液成因的伊利石以1M型、结晶度较差的含膨胀层为特征,而沉积浅变质成因的伊利石以2M1型、结晶度完好和不含膨胀层为特征，而且前在空间上分布在离接触带不到2km的范围内，从而指示了热液流体活动的空间规模。Nd、Sr同位素在空间上的变化则表明，在成矿流体作用过程中，Nd同位素相对稳定，斑岩的εNd变化在－0．76－－3．60范围内，表明岩浆系壳－幔混合来源。而Sr同位素初始比由斑岩体内部向围岩接触带则呈有规律升高带附近富集而成的。     

中国严寒地区村镇物理环境研究进展

 室外物理环境是严寒地区村镇建设中的薄弱环节,交通噪声凸显、传统声景消失、风环境恶劣是村镇物理环境建设中亟待解决的主要问题。本文从村镇噪声控制、乡村声景营造和村镇风环境改善等方面,概述“十二五”国家科技支撑计划课题的研究进展,并从村镇用地形态、规划布局模式、主干路等级及形式、住宅院落设计、绿化植物配置、保护利用自然声等方面,提出相关的改善技术及策略。