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1.
研究了异丙醇水溶液与(NH4)2SO4的双水相体系下,螯合剂PAN(1-(2-吡啶偶氮)-2-萘酚)与Ni 2+以及吐温80形成的缔合物在两相间的分配行为.结果表明,该缔合物的最大吸收波长为562nm,与PAN和异丙醇水溶液的混合液相比,最大吸收发生了97nm红移.应用该缔合物体系分离测定镍时,其线性范围为0.10~0.60mg/L,线性相关系数为0.999 2,表观摩尔吸光系数为1.7×105 L·mol-1·cm-1.利用该方法萃取测定Ni(Ⅱ)时,干扰离子铅(Ⅱ)、锌(Ⅱ)、铝(Ⅲ)、锰(Ⅱ)、钼(Ⅶ)、Fe(Ⅲ)、铬(Ⅶ)不被萃取,实现Ni(Ⅱ)与上述干扰离子的分离.  相似文献   

2.
Nanoparticles of Ce0.6Zr0.35Y0.05O2 (CZY) solid solution have been prepared by the CTAB (hexadecyl-trimethyl ammonium bromide), CTAB-EG (ethylene glycol) templating, and CTAB-EG-NaCl (in which the pores of the precursor synthesized by the CTAB-EG method is filled by a certain amount of NaCl) method, respectively. The physical properties of these materials were characterized by means of tech-niques such as X-ray diffraction (XRD), high resolution scanning electron microscopy (HRSEM), transmission electron microscopy (TEM), selected area electron diffraction (SAED), and N2 adsorp-tion-desorption measurements. The CZY samples synthesized by the above three methods display wormhole-like mesoporous morphology and cubic crystal structures. The materials are narrow in pore size distribution (averaged pore diameter = 5.3―7.1 nm), high in surface areas (95―119 m2/g), and large in pore volumes (0.16―0.18 cm3/g). It has been demonstrated that the introduction of NaCl is capable of retaining the pore structures of solid nanomaterials at high-temperature calcination.  相似文献   

3.
A novel process was developed to produce spherical copper powder for multilayer ceramic capacitors (MLCC). Spherical ultrafine cuprous oxide (Cu2O) powder was prepared by glucose reduction of Cu(OH)2. The Cu2O particles were coated by Mg(OH)2 and reduced to metallic copper particles. At last, the copper particles were densified by high-temperature heat treatment. The products were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), tap density, and thermogravimetry (TG). It is found that the shape and size distribution of the copper powder are determined by the Cu2O powder and the copper particles do not agglomerate during high-temperature heat treatment because of the existence of Mg(OH)2 coating. After densification at high temperature, the particle tap density increases from 3.30 to 4.18 g/cm3 and the initial oxidation temperature rises from 125 to 150°C.  相似文献   

4.
Without taking inducing factors into consideration, this paper adopts a quantitative analysis of the bottom factors in the Three Gorges Reservoir area, studies the relationship between the bottom factors and the development of landslides, and then zones the area according to risk levels. The bottom factors adopted in this paper include lithological characters(U1 ), gradient(U2 ), slope form (U3), difference of helght(U4 ), and slope orientation(U5 ). In 4 650 km^2 of the studied area, the areas of the very high, high, medium and low hazard degree area respectively were 57. 94 km^2 , 2 305.15 km^2, 1 241.6 km^2, 1 045.31 km^2. The methodological steps are (1) inversion statistic analysis, (2) the analysis of contribution ratio and weighing, (3) getting results via fuzzy evaluation of risk levels.  相似文献   

5.
A study on the distribution characteristics of soil organic carbon (SOC) in the alpine meadow in the Eastern Qinghai-Tibet Plateau has been carried out. The results indicate that the content of soil organic carbon (C SOC) in the topsoil of terrace meadow (TM) ((67.16 ± 1.02) g·kg−1) is more than that in the soil of upland meadow (UM) ((63.42 ± 0.65) g·kg−1), while the C SOC in upland shrubland (US) ((67.49 ± 0.83) g·kg−1) is the most abundant in the scoreh stage (September). From May to September, the C SOC in the topsoil of UM and US tends to descend, but that of TM tends to ascend. As for the distribution of the C SOC and the density of SOC in the soil in the three sample areas, the data show that the deeper the soil, the lesser the content and density of SOC. The C SOC in US is higher than that in TM and UM; the C SOC in UM is the lowest at 0–10 cm soil depth. The density of SOC in US is always the lowest among UM, TM, and US at 0–40 cm depth, which shows that the storage of carbon in UM is more than that in US in the same range; the carbon pool capacity in UM is higher than that in US in the same range. Biography: ZHANG Wei (1979–), male, Lecturer, research direction: ecology of environment.  相似文献   

6.
Co-substituted α-Ni(OH)2 was synthesized by a novel microwave homogeneous precipitation method in the presence of urea. LiNi0.8Co0.2O2 cathode material was synthesized by calcining Co-substituted α-Ni(OH)2 precursor and LiOH·H2O at 900℃for 10 h in flowing oxygen. XRD, FTIR, FESEM and electrochemical tests were used to study the physical and the electrochemical performances of the materials. The results show that the prepared LiNi0.8Co0.2O2 compound has a good layered hexagonal structure. Moreover, the LiNi0.8Co0.2O2cathode material demonstrates stable cyclability with a high initial specific discharge capacity of 183.9 mAh/g. The good electrochemical performance could be attributed to the uniform distribution of Ni^2+ and Co^2+ ions in the crystal structure and a minimal cation mixing in LiNi0.8Co0.2O2 host structure.  相似文献   

7.
The relaxation of the highly vibrationally excited CO (v = 1–8) by CO2 is studied by timeresolved Fourier transform infrared emission spectroscopy (TR FTIR). 193 nm laser photolysis of the mixture of CHBr3 with O2 generates the highly vibrationally excited CO(v) molecules. TR FTIR records the intense infrared emission of CO(v→v-1). The vibrational populations of each level of CO(v) have been determined by the method of spectral simulation. Based on the evolution of the time resolved populations and the differential method, 8 energy transfer rate constants of CO(v = 1–8) to CO2 molecules areobtained: (5.7±0.1), (5.9±0.1), (5.2±0.2), (3.4±0.2), (2.4±0.3), (2.2±0.4), (2.0±0.4) and (1.8±0.6) (1014 cm3 · molecule−1 · s−1), respectively. A two-channel energy transfer model can explain the feature of the quenching of CO(v) by CO2. For the lower vibrational states of CO, the vibrational energy transfers preferentially to the u3 mode of CO2 For the higher levels, the major quenching channel changes to the vibrational energy exchange between CO(v→v-1) and the u1 mode of CO2.  相似文献   

8.
Activated by methylaluminoxane, mononuclear bis(hydroxyindanone-iminate)nickel complexes Ni[ArN=CC2H3(CH3)C6H2(R)O]2 (Ar = 2,6-i-Pr2C6H3, R=Me(1), R=CI(2), and R=H(3)) showed good activity for the styrene polymerization. The effect of many reaction parameters including the AI/Ni ratio, temperature, and reaction time on catalytic activities of catalytic systems and the molecular weights of the obrained polystyrene was ascertained. The highest activity of 1.34×10^5g(PS)·mol^-1(Ni)·h^-1 was obtained under the optimum reaction condition. The ^13C NMR spectra of the polymers revealed that the polymer was isotactic-rich atactic polystyrene. And the coordination mechanism was confirmed by the analyses of the polymer chain end-groups.  相似文献   

9.
根据结构单元分析法,以永安镇油田永3断块沙二下亚段6砂层组61小层为例,对河口坝增生体不同级别的沉积界面进行划分;在此基础上对河口坝增生体沉积演化特点、增生体的顶面构造特征以及增生体油(气)水分布规律进行研究。结果表明:永3断块沙二下6砂层组61小层划分为6期增生体;永3断块61小层可分6期演化,6期增生体具有由西向东退积的特点;不同河口坝增生体的发育位置、范围及其顶面构造特征对增生体油(气)水分布具有重要的控制作用;大型三角洲河口坝增生体可作为独立的油气分布单元,其油气储量可以相当可观,以增生体为单元进行油(气)水分布规律研究非常必要。  相似文献   

10.
Surface soil samples collected over a high spatial resolution in eastern China were analyzed for carbon isotope composition (δ^13C) of total organic carbon (TOC) and higher plant-derived long-chain n-alkanes, with the latter reported as weighted mean values. The two sets of δ^13C values are significantly correlated and show similar trends in spatial variation. The spatial distribution of δ^13C shows less negative values in the mid-latitudes between 31°N and 40°N and more negative ones at higher and lower latitudes. This is consistent with previously reported carbon isotope data from surface soil phytoliths in the same region and suggests that the mid-latitude area provides relatively favorable growing condi- tions for C4 plants. Furthermore, δ^13C values of both TOC and long-chain n-alkanes from 12 surface soil samples collected from a small grassland in north China displayed similar carbon isotope values and the difference between paired δ^13C of a soil samples remains relatively constant. Our data demonstrate that in eastern China, soil δ^13C composition of both TOC and long-chain n-alkanes is effective indicators of C3/C4 ratios of the prevailing vegetation. This work suggests that -22‰ and -32‰ are good es- timated end members for the weighted mean δ^13C values of long-chain n-alkanes (C27, C29 and C31 n-alkanes) from soils under dominant C4 or C3 vegetation, allowing us to reconstruct paleovegetation trends.  相似文献   

11.
The vibrational energy transfer from highly vibrationally excited CO to H2O molecules is studied by time-resolved Fourier transform infrared emission spectroscopy (TR FTIR). Following the 193 nm laser photolysis of CHBr3 and O2 the secondary reactions generate CO(v). The infrared emission of CO(v → v−1) is detected by TR FTIR. The excitation of H2O molecules is not observed. By the method of the spectral simulation and the differential technique, 8 rate constants for CO(v)/H2O system are obtained: (1.7 ±0.1), (3.4 ±0.2), (6.2 ±0.4), (8.0 ±1.0), (9.0 ±2.0), (12 ±3), (16 ±4) and (18 ±7) (1013cm3 · molecule-1· s-1). At least two reasons lead to the efficient energy transfer. One is the contributions of the rotational energy to the vibational energy defect and the other is the result of the complex collision. With the SSH andab initio calculations, the quenching mechanism of CO(v) by H2O is suggested.  相似文献   

12.
Under the specially designated condition the polymerization of both tetrahydrofuran (THF) andtert-butyl methacrylate (tBMA) is a living one. The diblock copolymer, poly(tert-butyl methacrylate)-block-polytetrahydrofuran (PtBMA-b-PTHF), was successfully synthesized by means of the coupling reaction of living cationic PTHF+, SbF6 with living anionic PtBMA-, Li+. LiCI, which has a beneficial effect on the molecular weight distribution (MWD) in the anionic polymerization of (meth)acrylates, hinders the coupling reaction of living chains and cannot be used in the preparation of tBMA precursor. The hydrolysis of the aforementioned diblock copolymer under acid condition results in the amphiphilic diblock copolymer, i.e. poly(methy1 acrylic acid)-block-polytetrahydrofuran (PMAA-b-PTHF). The diblock copolymers were characterized with GPC and IR.  相似文献   

13.
The title inclusion complex with the formula [(C42H70O35)2·(C6O2H6)3·(H2O)21.2(CH3OH)2] has been crystallized and characterized by single crystal X-ray analysis. The complex crystallizes in the triclinic system, space group P1, with a = 1.5500 (1), b = 1.5536(1), c = 1.8246(1) nm, α = 113.17(2), β = 99.12(2), γ = 103.37(3)o, V = 3.7739 (4) nm3, Z = 1; Dc = 1.343 g/cm3, μ = 0.124 mm-1, F(000) = 1594, R = 0.0795 and S = 0.9639. Two independent molecules of β -cyclodextrin (β -CD) form a “head-to-head” dimer. The fairly important factor of the position and stability of the guest in the host cavity is the solvation of the polar group of the guest.  相似文献   

14.
Magnetic properties of heteropolyoxometalates   总被引:1,自引:0,他引:1  
The progress of the study on the magnetic properties of heteropolyoxometalates during the late decade is reviewed. Some anions of heteropolyoxometalates containing magnetic atoms, such as [M4(H2O)4(PW9O34)2]10- and[M4(H2O)4(P2W15O56)2]16-[M = Co(Ⅱ), Zn( Ⅱ ), Cu( Ⅱ ), Mn(Ⅱ ), Ni(Ⅱ)], and [GaW9O37M3(H2O)3]n-[M = Fe(Ⅲ), Cu(Ⅱ), Co(Ⅱ)] showed ferromagnetic and antiferromagnetic properties. The combination of heteropoly anions and organic π-donor of TTF+ (te-trathiofulvalene cation) results in a variety of magnetic properties. Furthermore, there is an interaction between the inorganic and organic components. The electrocrystallization technique can prepare the organic-inorganic salts of this kind, which will become the new member of molecular magnetic materials. Heteropoly blue is a kind of the mixed-valence complexes and its reduction electrons can be delocalized over anionic framework. The further study on the magnetic properties of heteropolyoxometalates will provide important information for the design of molecular materials.  相似文献   

15.
Conclusions  
1.  It is a successful attempt to test and study O-Si stable isotopic composition of SiO2 shells of radiolarian of sediment core below the depth of 5 000 m in the Pacific Ocean because of lacking of calcium shells below CCD in ocean. The distribution and variation, from 21.2 X 10−3 to 34.5 × 10−3 for δ18OSMOW and from 0.2 × 10−3 to 1.2 × 10−3 for δ30SiNBS-28, have certain link with and difference from those of other oceanic organisms.
2.  The relationship between δ18O and δ30Si values indicates obviously that the humeric distribution of core samples from No. 1787 station shows two groups separated by the depth of 160 cm. This distribution is also recorded by two kinds of isotopic curves (fig. 2(a), (b)), reflecting the evolutional difference of oceanic environment and stratigraphic sequence between the upper and lower layers separated by the depth of 160 cm.
3.  Through a correlation of δ18O values, the core from No. 1787 station shows that since 27 Ma, the Pacific Ocean has experienced 7 cold/warm changes, accompanied by the frequent variations of global ice volume and sea level.
  相似文献   

16.
Mnions were co-doped in yttrium aluminum garnet doped cerium(YAG:Ce) phosphors as a co-activator and host lattice element using the co-precipitation method.These ions broadened the emission spectra of the pure YAG:Ce phosphor,which is caused by the 2E-4A2,5E-5T2 or 1T2-5T2 transition.From our X-ray diffraction results,we observed that Ce3+(1.032 ) was substituted at the Y3+(0.900 ) site,and Mn4+(0.538 ) and Mn3+(0.67 ) were substituted at the Al3+(0.535 ) site.The chromaticity color co-ordinates of YAG:Ce0.06 is(0.203,0.167),and the indices of YAG:Ce0.06,Mn0.04 and YAG:Ce0.06,Mn0.08 are(0.249,0.181) and(0.233,0.194),respectively.The manganese co-doped yttrium aluminum garnet doped cerium blended with the YAG:Ce phosphor showed improved white light emission.  相似文献   

17.
The Rb(NTO)·H2O crystal has been synthesized by reaction of 3-nitro-1,2,4-triazole-5-one (NTO) with Rb2CO3 in aqueous solution. Its crystal structure has been determined. The crystal belongs to monoclinic system. Crystal structure data: space group P21 / n; a = 0.633 0(1), b = 0.824 1(2), c =1.296 4(3) nm; β= 97.90(1)°; V = 0.669 9 (2) nm3 , Z = 4, Dc = 2.306 g/cm3, μ= 7.365 nm-1, F (000) = 448. An eight coordinated compound is formed between Rb+ with oxygen atoms and nitrogen atoms. A layer structure is formed by coordination bonds and hydrogen bonds. The thermal decomposition mechanism of this coordination compound is discussed .  相似文献   

18.
By using the home-made femtosecond laser system and the time-of-flightmass spectrometer, the decay dynamics of excited carbon disulfide (CS2) and ammonia (NH3) are investigated in real time by pump-probe multiphoton ionization detection. The estimated lifetime constant of the NH3 state (514 fs) agreed quite well with the literature report. For the first time, the decay lifetime constants of the NH3 ′1A′1 state (93793 fs), the CS2 state (153 ± 10 fs), and the CS2 Rydberg state[2-3]6sσg(3Ⅱg)(948 ± 23 fs) are obtained.  相似文献   

19.
0 IntroductionThegreatattentionhasbeenpaidtorareearthorradioactiverareearthmetalcomplexesfortheirvariousbiologicactivi ties[1 3] .Forexamples,theradioactiverareearthmetal1 53SmⅢ com plexeswerewidelyusedfortumourtherapyofbrain ,liver,lung ,heartandbonetissues[4 5] ;forrareearthmetalEuⅢandTbⅢemitinguniquefluorescence ,theircompoundswereappliedfordiagnosesofvariousdiseases[6 ,7] ;forrareearthmetalGdⅢcontainingthemosthigh spinsingleelectrons,itscomplexeswereusuallyusedforcontrastagentsofmag…  相似文献   

20.
The CaLaGa3O7:Eu3+ phosphor was prepared by a chemical co-precipitation method. Field emission scanning electron microscopy (FE-SEM), laser particle size analysis, X-ray diffraction (XRD), photoluminescence (PL), and cathodoluminescence (CL) spectra were utilized to characterize the synthesized phosphor. The results revealed that the phosphor was composed of microspheres with a slight agglomerate phenomenon and was spherically shaped. The average grain size was about 1.0 μm. Eu3+ ions, as luminescent centers, substituted La3+ ions into the single crystal lattice of CaLaGa3O7 with the sites of Cs. Although the CL spectrum was greatly different from the PL spectrum, it had the strongest red emission corresponding to the 5D07F2 transition of Eu3+. Under the excitation of UV light (287 nm) and electron beams (1.0–7.0 kV), the chromaticity coordinates of the phosphor were found to be in the nearly red and orange light regions, respectively.  相似文献   

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