具有良好可再生性的新型二氧化硅磁性氧化石墨烯纳米复合材料

Graphene oxide (GO) wrapped Fe₃O₄ nanoparticles (NPs) were prepared by coating the Fe₃O₄ NPs with a SiO₂ layer, and then modifying by amino groups, which interact with the GO nanosheets to form covalent bonding. The SiO₂ coating layer plays a key role in integrating the magnetic nanoparticles with the GO nanosheets. The effect of the amount of SiO₂ on the morphology, structure, adsorption, and regenerability of the composites was studied in detail. An appropriate SiO₂ layer can effectively induce the GO nanosheets to completely wrap the Fe₃O₄ NPs, forming a core-shell Fe₃O₄@SiO₂@GO composite where Fe₃O₄@SiO₂ NPs are firmly encapsulated by GO nanosheets. The optimized Fe₃O₄@SiO₂@GO sample exhibits a high saturated adsorption capacity of 253 mg·g?1 Pb(II) cations from wastewater, and the adsorption process is well fitted by Langmuir adsorption model. Notably, the composite displays excellent regeneration, maintaining a ~90% adsorption capacity for five cycles, while other samples decrease their adsorption capacity rapidly. This work provides a theoretical guidance to improve the regeneration of the GO-based adsorbents.     

微波预处理对复杂铜矿磨矿及浮选动力学的影响

The effect of CaCO₃, Na₂CO₃, and CaF₂ on the reduction roasting and magnetic separation of high-phosphorus iron ore containing phosphorus in the form of Fe₃PO₇ and apatite was investigated. The results revealed that Na₂CO₃ had the most significant effect on iron recovery and dephosphorization, followed by CaCO₃, the effect of CaF₂ was negligible. The mechanisms of CaCO₃, Na₂CO₃, and CaF₂ were investigated using X-ray diffraction (XRD), scanning electron microscopy and energy dispersive spectrometry (SEM–EDS). Without additives, Fe₃PO₇ was reduced to elemental phosphorus and formed an iron–phosphorus alloy with metallic iron. The addition of CaCO₃ reacted with Fe₃PO₇ to generate an enormous amount of Ca₃(PO₄)₂ and promoted the reduction of iron oxides. However, the growth of iron particles was inhibited. With the addition of Na₂CO₃, the phosphorus in Fe₃PO₇ migrated to nepheline and Na₂CO₃ improved the reduction of iron oxides and growth of iron particles. Therefore, the recovery of iron and the separation of iron and phosphorus were the best. In contrast, CaF₂ reacted with Fe₃PO₇ to form fine Ca₃(PO₄)₂ particles scattered around the iron particles, making the separation of iron and phosphorus difficult.     

不同硅饱和系数水榴石的碳酸化分解动力学

Carbonated decomposition of hydrogarnet is one of the vital reactions of the calcification–carbonation method, which is designed to dispose of low-grade bauxite and Bayer red mud and is a novel eco-friendly method. In this study, the effect of the silica saturation coefficient (x) on the carbonation of hydrogarnet was investigated from the kinetic perspective. The results indicated that the carbonation of hydrogarnets with different x values (x = 0.27, 0.36, 0.70, and 0.73) underwent two stages with significantly different rates, and the kinetic mechanisms of the two stages can be described by the kinetic functions R3 and D3. The apparent activation energies at Stages 1 and 2 were 41.96–81.64 and 14.80–34.84 kJ/mol, respectively. Moreover, the corresponding limiting steps of the two stages were interfacial chemical reaction and diffusion.     

一种超重力燃烧合成制备高性能高熵合金的新方法

A new method of high-gravity combustion synthesis (HGCS) followed by post-treatment (PT) is reported for preparing high-performance high-entropy alloys (HEAs), Cr_0.9FeNi_2.5V_0.2Al_0.5 alloy, whereby cheap thermite powder is used as the raw material. In this process, the HEA melt and the ceramic melt are rapidly formed by a strong exothermic combustion synthesis reaction and completely separated under a high-gravity field. Then, the master alloy is obtained after cooling. Subsequently, the master alloy is sequentially subjected to conventional vacuum arc melting (VAM), homogenization treatment, cold rolling, and annealing treatment to realize a tensile strength, yield strength, and elongation of 1250 MPa, 1075 MPa, and 2.9%, respectively. The present method is increasingly attractive due to its low cost of raw materials and the intermediate product obtained without high-temperature heating. Based on the calculation of phase separation kinetics in the high-temperature melt, it is expected that the final alloys with high performance can be prepared directly across master alloys with higher high-gravity coefficients.     

窄板坯结晶器内连铸工艺参数对钢液流场的影响

Computational simulations and high-temperature measurements of velocities near the surface of a mold were carried out by using the rod deflection method to study the effects of various operating parameters on the flow field in slab continuous casting (CC) molds with narrow widths for the production of automobile exposed panels. Reasonable agreement between the calculated results and measured subsurface velocities of liquid steel was obtained under different operating parameters of the CC process. The simulation results reveal that the flow field in the horizontal plane located 50 mm from the meniscus can be used as the characteristic flow field to optimize the flow field of molten steel in the mold. Increases in casting speed can increase the subsurface velocity of molten steel and shift the position of the vortex core downward in the downward circulation zone. The flow field of liquid steel in a 1040 mm-wide slab CC mold can be improved by an Ar gas flow rate of 7 L·min?1 and casting speed of 1.7 m·min?1. Under the present experimental conditions, the double-roll flow pattern is generally stable at a submerged entry nozzle immersion depth of 170 mm.     

电渣重熔脱硫技术研究进展

Electroslag remelting (ESR) gives a combination of liquid metal refining and solidification structure control. One of the typical aspects of liquid metal refining during ESR for the advanced steel and alloy production is desulfurization. It involves two patterns, i.e., slag–metal reaction and gas–slag reaction (gasifying desulfurization). In this paper, the advances in desulfurization practices of ESR are reviewed. The effects of processing parameters, including the initial sulfur level of consumable electrode, remelting atmosphere, deoxidation schemes of ESR, slag composition, melting rate, and electrical parameters on the desulfurization in ESR are assessed. The interrelation between desulfurization and sulfide inclusion evolution during ESR is discussed, and advancements in the production of sulfur-bearing steel at a high-sulfur level during ESR are described. The remaining challenges for future work are also proposed.     

利用皮秒激光烧蚀制备非球形铝纳米颗粒

We report the picosecond laser ablation of aluminum targets immersed in a polar organic liquid (chloroform, CHCl₃) with ~2 ps laser pulses at an input energy of ~350 μJ. The synthesized aluminum nanoparticles exhibited a surface plasmon resonance peak at ~340 nm. Scanning electron microscopy images of Al nanoparticles demonstrated the spherical morphology with an average size of (27 ± 3.6) nm. The formation of smaller spherical Al nanoparticles and the diminished growth could be from the formation of electric double layers on the Al nanoparticles. In addition to spherical aluminum nanoparticles, triangular/pentagonal/hexagonal nanoparticles were also observed in the colloidal solution. Field emission scanning electron microscopy images of ablated Al targets demonstrated laser induced periodic surface structures (LIPSSs), which were the high spatial frequency LIPSSs (HSF-LIPSSs) since their grating period was ~280 nm. Additionally, coarse structures with a period of ~700 nm were observed.     

Mineral transition and formation mechanism of calcium aluminate compounds in CaO?Al2O3?Na2O system during high-temperature sintering

The mineral transition and formation mechanism of calcium aluminate compounds in CaO?Al₂O₃?Na₂O system during the high-temperature sintering process were systematically investigated using DSC?TG, XRD, SEM?EDS, FTIR, and Raman spectra, and the crystal structure of Na₄Ca₃(AlO₂)₁₀ was also simulated by Material Studio software. The results indicated that the minerals formed during the sintering process included Na₄Ca₃(AlO₂)₁₀, CaO·Al₂O₃, and 12CaO·7Al₂O₃, and the content of Na₄Ca₃(AlO₂)₁₀ could reach 92wt% when sintered at 1200°C for 30 min. The main formation stage of Na₄Ca₃(AlO₂)₁₀ occurred at temperatures from 970 to 1100°C, and the content could reach 82wt% when the reaction temperature increased to 1100°C. The crystal system of Na₄Ca₃(AlO₂)₁₀ was tetragonal, and the cells preferred to grow along crystal planes (110) and (210). The formation of Na₄Ca₃(AlO₂)₁₀ was an exothermic reaction that followed a secondary reaction model, and its activation energy was 223.97 kJ/mol.     

含细夹层的分矿充填层中流动特性的可视化

Ore particles, especially fine interlayers, commonly segregate in heap stacking, leading to undesirable flow paths and changeable flow velocity fields of packed beds. Computed tomography (CT), COMSOL Multiphysics, and MATLAB were utilized to quantify pore structures and visualize flow behavior inside packed beds with segregated fine interlayers. The formation of fine interlayers was accompanied with the segregation of particles in packed beds. Fine particles reached the upper position of the packed beds during stacking. CT revealed that the average porosity of fine interlayers (24.21%) was significantly lower than that of the heap packed by coarse ores (37.42%), which directly affected the formation of flow paths. Specifically, the potential flow paths in the internal regions of fine interlayers were undeveloped. Fluid flowed and bypassed the fine interlayers and along the sides of the packed beds. Flow velocity also indicated that the flow paths easily gathered in the pore throat where flow velocity (1.8 × 10?5 m/s) suddenly increased. Fluid stagnant regions with a flow velocity lower than 0.2 × 10?5 m/s appeared in flow paths with a large diameter.     

教学网无盘工作站自动登录

分析了Novell工作站站点限制原理和传统站点限制的方法 ,并利用NovellNetWare提供的系统功能调用接口技术取得网卡节点地址 ,改造传统注册过程 ,从而给出了一种Novell教学网站点限制的简便新方法 ,实现了网络工作站自动登录。     

Netware 操作系统安全性分析与对策

对Ｎｅｔｗａｒｅ操作系统的安全性作了广泛深入地分析，提出了应用系统中增强Ｎｏｖｅｌｌ网安全性的几种重要方法。     

自动登录Novell网的技术及界面设计

根据网络卡编号的唯一性特点，利用软件设计方法和工作站变量P-STATION(传回工作站的地址)的功能，介绍了能完全自动登录Novell网的网络登录原稿的技术和启动界面菜单的方法。     

Novell Netware局域网中共享安装Windows’95系统

本文介绍一般Windows’95客户机与Novell局域网连接和SBS服务器的安装方法.     

基于 IPX 协议的实时对等通信

讨论了在Ｎｏｖｅｌ网络中利用Ｎｅｔｗａｒｅ的ＩＰＸ协议实现实时对等通信的问题，分析了对接收程序进行改进的方法，介绍了ＩＰＸ连接的具体实现．在数据通信程序设计中，给出了若干重要的数据结构．     

从NetWare到Windows NT集成或迁移方案

Windows NT使用方便并且发展快速，越来越多的Netware用户迁移到Windows NT上．本文给出简便的集成和迁移方法，介绍了具体的实施步骤，并指出了在集成和迁移中应注意的问题．给出了从NetWare到Windows NT集成或迁移的两种方案，供大家参考．     

在Novell Netware中安装应用软件的研究

本文从网络的应用软件安装方面入手，介绍了在NovellNetware中安装应用软件的基本方法和步骤，并就安装过程中所出现的问题进行分析，提出了一些具体的解决方法。     

校园网邮件系统的构建与安全防范

当前所流行的邮件服务器系统软件有多种 ,各有其特点和不足 在江苏大学校园网建设中 ,基于对目录服务的集成和应用 ,我们选择了NovellNetware 文中阐述了校园网邮件系统的规划 ,介绍了GroupWise在校园网邮件系统中的应用 在邮件系统的应用过程中 ,针对所出现的系统稳定性、安全性等方面的问题 ,采取了基于QMAIL的垃圾邮件处理方案 ,并对该处理方案进行了论述 最后 ,对如何在GroupWise及QMAIL中实现多域名问题进行了探讨     

安装及管理Novell Netware网络过程中的故障处理

本文对NovellNetware进行了简单的介绍,并以实例说明其联网的安装步骤及安装应用软件过程中常见的故障,进行简单分析,指出了解决办法。同时,也对在使用管理网络过程中出现的故障进行了分析,并作技术处理,进行修复。     

Linux服务器搭建与应用

Linux提供完整网络集成,它可以轻松地与TCP／IP、WindowsNT及NovellNetware等网络集成一起。通过设置Intemet、工业标准协议和组件,这个操作系统能够充当大多数文件服务协议的服务器,并提供主要的Intemet应用软件。