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1.
流动注射催化光度法同时测定铁和钒的研究   总被引:1,自引:0,他引:1  
基于铁(Ⅲ)和钒(Ⅴ)对溴酸钾氧化维多利亚天蓝B褪色的催化作用及在不同反应条件下二者催化作用的差异,以反应条件作为化学计量学中的量测通道,应用CPA矩阵法对铁(Ⅲ)和钒(Ⅴ)同时测定进行了研究,建立了流动注射催化光度法同时测定铁和钒的方法.在铁(Ⅲ)和钒(Ⅴ)浓度比为1∶20~40∶1的范围内,应用该法对其混合物进行测定,回收率分别为95.5%和103.5%.  相似文献   

2.
利用流动注射技术研究了由Jones柱产生的铀(Ⅲ)与光泽精的化学发光反应.建立了痕量铀的流动注射化学发光分析法,方法的检出限为2×10-10g/mL铀,线性范围为1×10-9~1×10-5g/mL铀,相对标准偏差为1.0%(1×10-7g/mL铀,n=11).此法已用于合成海水中痕量铀的测定.同时对于反应机理也进行了研究.  相似文献   

3.
攀枝花钒钛磁铁矿是一种含有铁、钒、钛、铬、钴、钪等多种有益元素的共生矿。41年来,其以铁、钒利用为主,取得了较大进展;如今要转向以钛利用为主的理由如下。1、钛的利用远落后于铁、钒利用攀枝花年产钢能力达600万吨,钒制品年生产能力(V2O5)2万吨,铁、钒产品年销售收入200多  相似文献   

4.
发现鲁米诺的碱性溶液与还原剂盐酸羟胺反应产生化学发光, Co( Ⅱ) 可催化此化学发光反应. 研究了该体系的化学发光动力学和化学发光光谱特性, 提出了该体系的化学发光反应机理是由于盐酸羟胺首先与溶液中溶解的氧气反应形成超氧基阴离子, 超氧基阴离子氧化鲁米诺产生化学发光.  相似文献   

5.
流动注射催化光度法同时测定铁和钒的研究   总被引:3,自引:0,他引:3  
基于铁(Ⅲ)和钒(Ⅴ)对溴酸钾氧化维多利亚天蓝B褪色的催化作用及在不同反应条件下二者催化作用的差异,以及反应条件作为化学计量学中的量测通道,应用CPA矩阵法对铁(Ⅲ)和Ⅴ同时测定进行了研究,建立了流动注射催化光度法同时测定铁和钒的方法,在铁(Ⅲ)和钒Ⅴ浓度比为1:20 ̄40:1的范围内,应用该法对其混合物进行测定,回收率分别为95.5%和103.5%。  相似文献   

6.
在草酸钠存在下用紫外光照射铁(Ⅲ)溶液, 产生的铁(Ⅱ)对铬(Ⅵ)进行滴定, 并对土壤、自来水、矿泉水等实际样品进行分析, 结果令人满意  相似文献   

7.
点点滴滴     
在镍合金中添加钒、铬、镓、钨、铼、钼等金属后,可降低导热性能。大气层中的尘埃,能对我们星球的气  相似文献   

8.
研究在草酸盐离子存在下, 用紫外光照射含铁( Ⅲ) 溶液, 通过光化学反应产生的铁( Ⅱ)与溶液中的钒( Ⅴ) 作用, 采用改进的永停法进行终点检测. 结果表明, 溶液含钒的量与到达检测终点的时间呈良好的线性关系. 据此可以测定试样中钒的含量. 用BaSO4 作共沉淀剂以共沉淀的形式, 把铬( Ⅵ) 共沉淀以消除其对测定的影响.  相似文献   

9.
在碳热还原反应热力学分析的基础上,通过球团还原焙烧实验,并结合物相分析和成分分析,对含铬提钒尾渣中金属氧化物的碳热还原过程进行了系统研究。实验结果表明,在不同的还原温度下,铁、铬、钒、锰、钛等有价金属氧化物展现出不同的还原反应特征和富集迁移规律。  相似文献   

10.
研究了苹果酸羟基钛(Ⅲ)、酒石酸羟基钛(Ⅲ)和柠檬酸钛(Ⅲ)在空气、氮气下的热分解反应,从TG曲线求出热分解反应的表观动力学参数反应级数,活化能,频率因子  相似文献   

11.
Language markedness is a common phenomenon in languages, and is reflected from hearing, vision and sense, i.e. the variation in the three aspects such as phonology, morphology and semantics. This paper focuses on the interpretation of markedness in language use following the three perspectives, i.e. pragmatic interpretation, psychological interpretation and cognitive interpretation, with an aim to define the function of markedness.  相似文献   

12.
何延凌 《科技信息》2008,(4):258-258
Language is a means of verbal communication. People use language to communicate with each other. In the society, no two speakers are exactly alike in the way of speaking. Some differences are due to age, gender, statue and personality. Above all, gender is one of the obvious reasons. The writer of this paper tries to describe the features of women's language from these perspectives: pronunciation, intonation, diction, subjects, grammar and discourse. From the discussion of the features of women's language, more attention should be paid to language use in social context. What's more, the linguistic phenomena in a speaking community can be understood more thoroughly.  相似文献   

13.
理论推导与室内实验相结合,建立了低渗透非均质砂岩油藏启动压力梯度确定方法。首先借助油藏流场与电场相似的原理,推导了非均质砂岩油藏启动压力梯度计算公式。其次基于稳定流实验方法,建立了非均质砂岩油藏启动压力梯度测试方法。结果表明:低渗透非均质砂岩油藏的启动压力梯度确定遵循两个等效原则。平面非均质油藏的启动压力梯度等于各级渗透率段的启动压力梯度关于长度的加权平均;纵向非均质油藏的启动压力梯度等于各渗透率层的启动压力梯度关于渗透率与渗流面积乘积的加权平均。研究成果可用于有效指导低渗透非均质砂岩油藏的合理井距确定,促进该类油藏的高效开发。  相似文献   

14.
As an American modern novelist who were famous in the literary world, Hemingway was not a person who always followed the trend but a sharp observer. At the same time, he was a tragedy maestro, he paid great attention on existence, fate and end-result. The dramatis personae's tragedy of his works was an extreme limit by all means tragedy on the meaning of fearless challenge that failed. The beauty of tragedy was not produced on the destruction of life, but now this kind of value was in the impact activity. They performed for the reader about the tragedy on challenging for the limit and the death.  相似文献   

15.
正The periodicity of the elements and the non-reactivity of the inner-shell electrons are two related principles of chemistry,rooted in the atomic shell structure.Within compounds,Group I elements,for example,invariably assume the+1 oxidation state,and their chemical properties differ completely from those of the p-block elements.These general rules govern our understanding of chemical structures and reactions.Using first principles calcula-  相似文献   

16.
We have developed an adiabatic connection to formulate the ground-state exchange-correlation energy in terms of pairing matrix linear fluctuations.This formulation of the exchange-correlation energy opens a new channel for density functional approximations based on the many-body perturbation theory.We illustrate the potential of such approaches with an approximation based on the particle-particle Random Phase Approximation(pp-RPA).This re-  相似文献   

17.
正The electronic and nuclear(structural/vibrational)response of 1D-3D nanoscale systems to electric fields gives rise to a host of optical,mechanical,spectral,etc.properties that are of high theoretical and applied interest.Due to the computational difficulty of treating such large systems it is convenient to model them as infinite and periodic(at least,in first approximation).The fundamental theoretical/computational problem in doing so is that  相似文献   

18.
For molecular systems,the quantum-mechanical treatment of their responses to static electromagnetic fields usually employs a scalar-potential treatment of the electric field and a vector-potential treatment of the magnetic field.Although the potential for each field separately is associated with the choice of an(unphysical)origin,the precise choice of the origin for the electrostatic field has little consequences for the results.This is different for the  相似文献   

19.
Franck-Condon factors bridge the gap between theoretical modeling and experimental observations for molecular electronic spectroscopy and electron transfer.Under the displaced harmonic oscillator approximation,multidimensional Franck-Condon factors are decomposed into a product of many one-dimensional(1D)Franck-Condon(FC)factors,and each 1D-FC factor is associated with one Huang-Rhys factor that determines the leading contribution of  相似文献   

20.
<正>"The Journal of Shanghai Normal University:Mathematics"is published by Shanghai Normal University as regular issues of The Journal of Shanghai Normal University each year from 2014 in English.The editors-in-chief of the issues are professors Yuhao Cong and Maoan Han.The Journal of Shanghai Normal University was started in 1958 with  相似文献   

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