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1.
利用磁控溅射,将磁电阻材料La0.67Ca0.33MnO3与金属Ag,Fe等材料相结合,制成了多层膜,测得了三层膜“La0.67Ca0.33MnO3/Ag/Fe”的巨磁电阻效应。  相似文献   

2.
研究了La(2-x)Bix/3Ca1/3MnO3体系的电阻行为和磁性转变,当x=0.0,0.2时,样品表现为铁磁转变,居里温度Tc分别为265K和245K,铁磁转变伴随着半导体-金属转变,对应于磁电阻效应的极大值;当x=0.4时,样品表现为复杂的磁性转变,样品的电阻率为半导体特性,对应的磁性转变没有半导体,金属转变发生,在x=0.4和0.6两个样品中,1T外场下85K时获得大于86%的巨磁电阻效应  相似文献   

3.
镧锰系钙钛矿可脱附氧与催化氧化活性   总被引:2,自引:0,他引:2  
用热分解法合成La0.8Me0.2MnO3(Me:Na,K,Ca,Sr,Ba)和La0.8Sr0.2Mn0.7M0.3O3(M:Fe,Co,Ni,Cu)系统的钙钛矿型复合氧化物,用TPD方法研究部分取代对样品的氧吸-脱附性能的影响,对于La0.8Me0.2MnO3系列,氧的吸-脱附特性由A位的离子半径、价态和物化性质决定,对于B位取代基活性与可脱α氧量并不成比例关系,其活性的决定因素可能是B位离子的自氧化还原循环能力。  相似文献   

4.
利用9Mev的氘核轰击以铜为衬底的镀锌靶,由核反应67(d,2n)67(d,2n)67Ga产生67Ga,其产额为3.81MBq/(μA·h).用异丙醚溶剂萃取法分离出无载体、高纯度的67Ga,并制得枸橼酸镓-67注射液。在lmL注射液中,杂质元素Zn,Cu,Fe和T_i的含量分别为0.64μg,0.05μg,0.40μg和0.74μg.Ga(Ⅲ)(或67Ga)的化学产额为97.0%±0.5%;67Ga产品中无发射高能γ射线的核素66Ga存在,1mL的67Ga产品中铁含量约为0.40μg,不会影响67Ga在肿瘤中的积聚效果。  相似文献   

5.
La0.33Ca0.67MnO3钙钛矿中电荷有序的结构模型是当前凝聚态物理学研究热点之一,前人的工作在这方面有很大的分歧,本用透射电子显微术证实了横向位移的Winger晶体模型,否定了纵向位移的双条带模型,在电荷有序的La0.33Ca0.67MnO3中发现了非公度调制和在电荷有序过程中生成的位移矢量为aco/3的反相畴。  相似文献   

6.
研究了355nm脉冲激光烧蚀La2O3,MnO2,LiMn2O4,La0.67Ca0.33MnO3等金属氧化物体系产物的发光光谱,观察到了激发态La,La+,LaO以及Mn等粒子的发光谱线或谱带。在O2和Ar气氛中,各谱线(带)的强度迅速下降。激光能量密度的增加可以改变羽状物中La+,La和LaO的相对强度。对多组分金属氧化物攻蚀的结果与单组分金属氧化物类似。  相似文献   

7.
采用溶胶-凝胶工艺制备La0.7Ba0.3Mn1-xFexO3化合物.研究其磁性、导电性和磁电阻效应.结果表明,随着Fe含量的增加,电阻率增加,铁磁居里温度近似线性下降  相似文献   

8.
混合烧结磁电复合材料的研究   总被引:6,自引:0,他引:6  
分析了单相材料性能及混合比对复合材料磁电效应的影响,探讨了混合烧结磁电复合材料的相分布。选取k33大的PZT(B)为压电相、Ni(Co,Mn)Fe2O4为磁致伸缩相,采用混合烧结法,获得了磁电转换系数(dE/dH)max达0.3142V/A的磁电复合材料。  相似文献   

9.
由HMnO4和(NH4)6Mo7O24;4H2O合成了标题化合物K0.5(NH4)5.5「MnMo9O32」.6H2O用X-射线测定了晶体结构,该化合物的晶体属三方晶系,空间群R32;a=15.846(4),C=12.396(30)A,Mr=1657.28,V=2695.6A^3,Z=3,Dc=3.82g/cm^3,μ41.5=cm^-1,F(000)=2967和3024个可观测衍射「Fp≥3σ(  相似文献   

10.
本文提出以0.1M KNO3-0.01M酒石酸钠(pH=4)为支持电解质,采用玻碳汞膜电极阳极 溶出半微分电分析法,同时测定活性炭中痕量铜、铅、镉。在所选择的实验条件下,1:1000倍 Al(Ⅲ)、Ca(Ⅱ)、Mg(Ⅱ)和 l:50倍Cr(Ⅲ)、Fe(Ⅲ)、Mn(Ⅱ)对测定没有干扰。方法简便,快 速,灵敏度高.  相似文献   

11.
Language markedness is a common phenomenon in languages, and is reflected from hearing, vision and sense, i.e. the variation in the three aspects such as phonology, morphology and semantics. This paper focuses on the interpretation of markedness in language use following the three perspectives, i.e. pragmatic interpretation, psychological interpretation and cognitive interpretation, with an aim to define the function of markedness.  相似文献   

12.
理论推导与室内实验相结合,建立了低渗透非均质砂岩油藏启动压力梯度确定方法。首先借助油藏流场与电场相似的原理,推导了非均质砂岩油藏启动压力梯度计算公式。其次基于稳定流实验方法,建立了非均质砂岩油藏启动压力梯度测试方法。结果表明:低渗透非均质砂岩油藏的启动压力梯度确定遵循两个等效原则。平面非均质油藏的启动压力梯度等于各级渗透率段的启动压力梯度关于长度的加权平均;纵向非均质油藏的启动压力梯度等于各渗透率层的启动压力梯度关于渗透率与渗流面积乘积的加权平均。研究成果可用于有效指导低渗透非均质砂岩油藏的合理井距确定,促进该类油藏的高效开发。  相似文献   

13.
As an American modern novelist who were famous in the literary world, Hemingway was not a person who always followed the trend but a sharp observer. At the same time, he was a tragedy maestro, he paid great attention on existence, fate and end-result. The dramatis personae's tragedy of his works was an extreme limit by all means tragedy on the meaning of fearless challenge that failed. The beauty of tragedy was not produced on the destruction of life, but now this kind of value was in the impact activity. They performed for the reader about the tragedy on challenging for the limit and the death.  相似文献   

14.
正The periodicity of the elements and the non-reactivity of the inner-shell electrons are two related principles of chemistry,rooted in the atomic shell structure.Within compounds,Group I elements,for example,invariably assume the+1 oxidation state,and their chemical properties differ completely from those of the p-block elements.These general rules govern our understanding of chemical structures and reactions.Using first principles calcula-  相似文献   

15.
We have developed an adiabatic connection to formulate the ground-state exchange-correlation energy in terms of pairing matrix linear fluctuations.This formulation of the exchange-correlation energy opens a new channel for density functional approximations based on the many-body perturbation theory.We illustrate the potential of such approaches with an approximation based on the particle-particle Random Phase Approximation(pp-RPA).This re-  相似文献   

16.
正The electronic and nuclear(structural/vibrational)response of 1D-3D nanoscale systems to electric fields gives rise to a host of optical,mechanical,spectral,etc.properties that are of high theoretical and applied interest.Due to the computational difficulty of treating such large systems it is convenient to model them as infinite and periodic(at least,in first approximation).The fundamental theoretical/computational problem in doing so is that  相似文献   

17.
For molecular systems,the quantum-mechanical treatment of their responses to static electromagnetic fields usually employs a scalar-potential treatment of the electric field and a vector-potential treatment of the magnetic field.Although the potential for each field separately is associated with the choice of an(unphysical)origin,the precise choice of the origin for the electrostatic field has little consequences for the results.This is different for the  相似文献   

18.
Franck-Condon factors bridge the gap between theoretical modeling and experimental observations for molecular electronic spectroscopy and electron transfer.Under the displaced harmonic oscillator approximation,multidimensional Franck-Condon factors are decomposed into a product of many one-dimensional(1D)Franck-Condon(FC)factors,and each 1D-FC factor is associated with one Huang-Rhys factor that determines the leading contribution of  相似文献   

19.
<正>"The Journal of Shanghai Normal University:Mathematics"is published by Shanghai Normal University as regular issues of The Journal of Shanghai Normal University each year from 2014 in English.The editors-in-chief of the issues are professors Yuhao Cong and Maoan Han.The Journal of Shanghai Normal University was started in 1958 with  相似文献   

20.
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