N,N′-双水杨醛缩二氨基乙醚的合成和晶体结构

合成了一种新的西佛碱配体N,N''双水杨醛缩二氨基乙醚,并采用x射线单晶衍射法测定了它的晶体结构。该晶体属正交晶系空间群P_bcn,a=5.667(2)Å,b=9.192(3)Å,c=31.829(11)Å,v=1658.2(7)ų,分子式为C₁₈H₂₀N₂O₃,Mr=312.36,Z=4,D_C=1.251g·cm^-3,晶体结构测定和UV,IR谱均表明分子内形成氢键。在甲醇溶液中有一个荧光发射带,λ_max=443nm。     

Mn掺杂CuCrO2纳米粉体的室温铁磁性

利用固相反应与球磨相结合的方法,制备了(Cu_1-xMn_x)CrO₂ (0≤x≤6 at%) 和 Cu(Cr_1-yMn_y)O₂ (0≤y≤6 at%)两个系列的纳米粉体.结果表明,所有样品都具有3R-CuCrO₂铜铁矿单相结构.晶格膨胀说明Mn离子已分别固溶到(Cu_1-xMn_x)CrO₂的Cu亚晶格中和Cu(Cr_1-yMn_y)O₂的Cr亚晶格中,这在X射线光电子能谱的分析中得到了进一步的证实.B位Mn掺杂样品具有室温铁磁性,磁性源于Cr³⁺-Mn³⁺离子对间以空穴为媒介的双交换相互作用.CuMO₂(M=Cr,Mn)铜铁矿纳米粉体的饱和磁化强度比文献值高出约一个数量级,并随着Mn含量的增大而逐渐减小,主要受到3个因素的共同影响:M-M离子对数目、M-M离子间距及空穴浓度.     

线性交换子的加权估计

 多线性交换子T_b(f)(x)=∫_Rⁿ∏_i=1^m(b_i(x)-b_i(y))k(x,y)f(y)dy在L^p(Rⁿ)(1K是一个标准的Calderón-Zygmund核.主要研究交换子Mf(x)=sup_x∈Q∫_Q|f(y)|dy,其中f∈L_loc(Rⁿ),x∈Rⁿ,Q是任何包含x的方体,并用Sharp极大估计得到了该多线性交换子在Herz空间的一个加权有界性.     

三核铜配合物[Cu3(TBSSB)2(BSA)2(bipy)2]·H2O的合成、晶体结构及性质研究

以牛磺酸缩5-溴水杨醛席夫碱（TBSSB）、5-溴水杨醛（BSA）、2,2''-联吡啶（bipy）为混合配体,合成了三核铜配合物[Cu₃（TBSSB）₂（BSA）₂（bipy）₂]·H₂O （1）,并对该化合物进行了元素分析、红外光谱、X-射线单晶衍射、光致发光光谱、固体漫反射光谱及分子轨道分析等表征。晶体结构分析表明,该化合物结晶属三斜晶系,Pī空间群,晶胞参数为a=10.031（2）Å,b=11.480（2）Å,c=12.913（3）Å,α=73.13（3）°,β=78.58（3）°,γ=75.24（3）°,V=1363.6（5）ų,Z=1,M_r=1533.30,Dc=1.867 g/cm³,F（000）=759,μ=4.236 mm^-1,S=0.921,R₁=0.0488,wR₂=0.0471（I > 2σ（I））,R₁=0.1812,wR₂=0.0546。Cu （2）离子与来自于两个TBSSB配体的两个氮原子和两个氧原子配位,形成正方形配位构型。Cu （1）离子与来自于一个2,2''-bipy的两个氮原子,TBSSB配体的一个氧原子,以及BSA的两个氧原子配位,形成四方锥形配位构型。该化合物分子通过O-H…Br分子内氢键和C-H…O分子间氢键相互连接形成三维超分子结构。研究发现该化合物能够发出蓝色荧光,它的带隙为2.19 eV。     

Melnikov函数在含有两个幂零尖点的双异宿环附近的展开式

考虑未扰Liénard系统ẋ=y,ẏ=-g（x）,其中deg g（x）=7,当该系统分别含有2,3,4和5个奇点时,给出了其所有的不同拓扑类型的相图,并给出了Melnikov函数在含有2个幂零尖点和1个双曲鞍点的双异宿环附近的展开式和得到极限环的条件.     

一个单核三价铬配合物的晶体结构、发光性质及热稳定性

我们重新合成了曾经报道过的反式K[Cr(C₂O₄)_2·(H₂O)₂]_2·3H₂O三价铬配合物, 并借助先进的单晶衍射仪和更先进的解析手段得到了该配合物更加精确的结构模型,该配合物属于单斜晶系,P2/n（No. 13）空间群,晶胞相关参数为：a = 7.8827 (4) Å,b = 5.7296(3) Å,c = 13.6447(7) Å,β= 103.506(5)°,Z = 2,Dc =1.980 Mg/m³,V = 599.22(5) ų。热重测试结果显示该配合物在357 K以前是稳定的,在410 nm最有效的紫外光光源的激发下,配合物在610 nm处有一个尖锐的发射峰。     

铁镍磷化物电极材料的制备及电催化析氢性能

为了解决电解水析氢过程中所用贵金属材料的高昂成本问题,采用水热-低温磷化法制备了一种低廉、环保、高效的析氢催化剂Fe_xNi_1-x-P。与传统制备方法比较,该方法在水热合成前驱体过程中,利用镍盐和铁盐与无水乙醇发生氧化还原反应,生成的OH^-可以沉淀金属离子,随后前驱体与NaH₂PO₂低温磷化制得Fe_xNi_1-x-P。通过研究发现,Fe_0.5Ni_0.5-P电极材料表现出优异的催化活性。在1.0 mol·L^-1 KOH溶液中,电流密度为10 mA·cm^-2时,电极Fe_0.5Ni_0.5-P需要的过电位仅为113 mV,1 000圈循环伏安测试后,极化曲线无明显衰减。提供了一种制备Fe_xNi_1-x-P的简便方法,为开发清洁能源系统的环境友好型催化剂提供了新思路。     

累计正海拔增量对轻型汽油车实际行驶排放试验的影响

"中国西南地区路面起伏大，对汽车实际行驶排放（real driving emission，RDE）有较大影响。为此，选择1辆满足国六排放标准的轻型汽油车在4条不同累计正海拔增量路线上进行RDE试验，分析了路段和窗口的累计正海拔增量、动力学参数v·a_pos[95]与污染物排放因子（CO、CO₂、NO_x、PN）的相关性。结果表明：在路段中，污染物排放与累计正海拔增量、v·a_pos[95]相关性不强。在窗口中，当v·a_pos[95]较大，CO排放与累计正海拔增量具有明显相关性；CO₂排放随着累计正海拔增量增大而增大，受到v·a_pos[95]影响较小；NO_x排放与累计正海拔增量、v·a_pos[95]明显不相关；当v·a_pos[95]较大，PN排放与累计正海拔增量具有明显相关性，当v·a_pos[95]较小，PN排放与累计正海拔增量明显不相关。建议对市区、市郊和高速路段的累计正海拔增量分段设限。 "     

一种含5-硝基间苯二甲酸和菲咯啉配体的超分子化合物：结构表征，光致发光和电化学性能

采用水热法合成了含混合配体的铜配合物[CuClPhen]⁺·[HL]^-·2H₂O（HL=5-硝基间苯二甲酸,Phen=1,10-菲咯啉）,其结构由单晶X射线晶体学确定。标题化合物在三斜空间群P-1的晶体化合物。标题化合物的晶体数据：C₃₂H₂₄ClN₅CuO₈,M_r = 704.54,a = 10.4044(5),b = 12.3912(9),c = 12.4632(9)Å,α = 73.859(6),β = 85.036(5),γ = 78.202(5)^°,V = 1510.09(17) ų,Z = 2, T = 293(2) K,D_c = 1.549 g/cm³,μ(MoKα) = 0.874 mm^-1,F(000) = 720.0,R = 0.0554,wR = 0.1434,GOF = 1.098。当用作超级电容器电极材料时,所制备的配合物具有高比电容、良好的循环稳定性和优良的倍率性能。在1mol/L KOH溶液中,最大比电容可达到69 F/g。在2 A/g电流密度下,10000次循环后比电容保持率为72%。标题化合物是一种潜在的红色光致发光材料。     

煤孔裂隙多尺度表征及其对渗透率的影响分析——以中国14个大型煤炭基地为例

为探究煤体不同尺度孔裂隙特征及其对渗透率的影响,从我国14个大型煤炭基地分别取样,进行氮气吸附、压汞和CT实验,并将CT扫描后的煤样进行渗流实验。结果表明,各煤样中微孔和过渡孔多为封闭孔,连通性差,不利于渗流的进行。r=10 nm和r=100 μm的孔裂隙体积占比相对较大,贡献了煤体大部分孔隙率,S2和S3中的大尺度平行板孔隙为渗流提供了充足的空间。通过划分3种实验表征的优势孔径段,提出了综合表征孔隙率和分形维数的方法,得到各煤样的孔隙率范围为1.62%~11.60%,分形维数范围为2.29~2.78。煤样渗透率在0.000 2×10^-15~ 0.652 5×10^-15 m²之间,以中低渗为主。r<50 nm、50 nm≤ r ≤8.5 μm和r>8.5 μm的孔隙率分量与渗透率的关系分别为y=0.274 1x-0.078 1、y=0.067 4x+0.023 7和y=0.003 9x^{2.598 6},其中r>8.5 μm的孔隙率分量与渗透率的相关性最强。相对于氮气吸附和压汞实验,CT实验更适用于分析孔裂隙结构对水渗的影响。     

一类2n次Kolmogorov系统的极限环

研究一类2n次Kolmogorov系统{dx/dt=x(a0-a1x a3x3-a4x4 a5xy2n-1),dy/dt=y(b1x2n-b2),极限环的存在性问题.主要讨论a5＞0和a5＜0两种情形.当a5＞0时,系统在第一象限内不存在极限环;当a5＜0时,得到了平衡点的稳定性态,系统无闭轨的充分条件以及在第一象限内存在稳定极限环的条件.     

On the Family of Thue Equation ｜x^3 ＋ mx^2y-（ m ＋ 3）xy^2 ＋ y^3｜= k

The family of cubic Thue equation which depend on two parameters ｜ x^3 ＋ mx^2 y-（m＋3） xy^2＋y^3｜=k is studied. Using rational approximation, we give a smaller upper bound of the solution of the equation, that is quite better than the present result. Moreover, we study two inequalities ｜ x^3 ＋ mx^2y-（m ＋ 3） xy^2＋y^3 ｜ =k≤2m＋3 and ｜x^3 ＋mx^2y- （m＋3）xy^2 ＋ y^3｜ = k≤ （2m＋3）^2 separately. Our result of upper bound make it easy to solve those inequalities by simple method of continuous fraction expansion.     

Integral Points on a Class of Elliptic Curve

0 IntroductionZasegairerc[h1]fodre sbcirgibientde gsreavle rpaolin tmse tohnocdsert waihnicehlli ppetircm citur ovnese btyogiving the upper bound of solution. Unfortunately,this upperbound was verylarge andsometi mes beyondthe range of com-puter searching.For a particular elliptic curvey2=x3-30x+133(1)he mentioned he can find all integral points and the largestpoint is (x,y) =(5 143 326 ,±11 664 498 677) by using Mas-ser and W櫣stholz bounds on elliptic logarithms .Although recent results on…     

Remote sensing of algal blooms using a turbidity-free function for near-infrared and red signals

HARMFUL ALGAL BLOOM ACTS UPON IMPORTANT ENVIRON-MENTAL PROBLEMS IN COASTAL WATERS.A UNIFIED AND IM-PLEMENTING METHOD FOR SURVEY AND MONITORING ALGALBLOOMS HAS BEEN DEVELOPED SINCE LAST DECADE.HOWEVER THERE IS A DATA GAP OF ABOUT TENS YEARS IN THE PERIOD W…     

Magnetoelectric and converse magnetoelectric res ponses in TbxDy1-xFe2-y alloy ＆ Pb（Mg1/3Nb2/3）（1-x）TixO3 crystal laminated composites

Measured results of magnetoelectric （ME） and converse magnetoelectric （CME） effects of TbxDy1-xFe2-y/ Pb（Mg1/3Nb2/3）（1-x）TixO3/TbxDy1-xFe2-y （TD/PMNT/TD） and PMNT/TD/PMNT laminated composites are presented. ME effect was determined by measuring laminate voltage output under a Helmholtz-generated AC field biased by a DC field （0-1 kOe） （1Oe = 79.58 A/m）. The CME effect was measured by recording the voltage induced in a solenoid encompassing the ME sample while exposed to a DC bias field and PMNT layer driven by a 10 V AC source. The ME and CME responses in the two laminated structure are linear. The highest values of ME coefficients in TD/PMNT/TD and PMNT/TD/PMNT composites are 384 mV/Oe and 158 mV/Oe, respectively, while the highest values of CME coefficients in the two composites are 118 mG/V and 162 mG/V （1 G=10^-4 T）, respectively.     

Syntheses and lyotropic liquid crystal properties of a series of sandwich-type tungstoarsenates heteropoly compounds with As/W ratio of 4/30

A series of sandwich-type tungstoarsenates heteropoly compounds with As/W ratio of 4/30, Na16[As4W30M4(H2O)2O112]·XH2O (M = Zn,Cu,Co,Ni,Mn and Cd), have been synthesized for the first time and structurally characterized by elemental analysis, IR and 183W NMR spectra. The crystal structure of Na16[As4W30Cu4(H2O)2O112]·63H2O was determined to be a triclinic system, of P1 symmetry, a = 1.2721(3) nm, b = 2.451 6(5) nm, c = 2.6450(5) nm, α= 89.90(3)°,β= 77.32(3)°, γ= 89.96(3)°, 2=2. Using tetrahepty lammonium bromide as a phase transfer reagent, [As4W30Cu4(H2O)2O112]16- was transferred from aqueous solution to organic phase (benzene), and the heteropolyanion lost the coordination water molecules to form the coordination-unsaturated ion. After lactic acid was added to the benzene solution, the coordination-saturation was recovered. By esterification reaction between lactic acid and cholesterin, the latter was attached to the heteropolyanion indirectly. Therefore, a new type of lyotropic liquid crystal was obtained, which was characterized by a polarimicroscope, DSC and variable temperature wide-angle X-ray diffraction.     

The nonwandering set of some Hénon map

For the Hénon mapT _{a, b}(x, y) = (1 −ax ² +y, bx), Benedicks and Carleson proved that for (a,b) near (2, 0) andb > 0, there exists a setE with positive Lebesgue measure, whose corresponding mapT _{a, b} possesses a strange attractor. Viana conjectured that if (a, b) ∈E, then the nonwandering set of the mapT _a, b Ω(T_{a, b}) = ∧_{a, b},Uq _a, b, where ∧_{a, b}, is the strange attractor, q_a,b is a hyperbolic fixed point in the third quadrant. It is proved that this conjecture holds true for a positive measure set E₁ ⊂E.     

Supermolecular layered double hydroxides

Research progresses in the layered double hydroxides [M _(1-x ^)/2+ M _x ³⁺ (OH)₂] ^x+ A _x ^n/n− ·mH₂O intercalated with metal coordinate ions or oxometalates in the last ten years are reviewed. These layered double hydroxides are mainly intercalated with polyoxometalate (POM) ions, a LiAl-LDH photochemical assembly containing TiO₂ and CH₃(CH₂)₁₂COO⁻ anions, together with Zn(TPPC) (porphyrin derivate) and macrocyclic ligand-containing porphyrin derivate anions. Emphasis is put on the synthesis methods for intercalation of the anions into the interlayer regions, the characterization techniques and structures for the layered compounds and the newest research progress in the fields such as catalysis. The review also forecasts the prospects of the field.