金刚石薄膜场致发射材料的特性与应用

主要论述金刚石薄膜场致发射材料的性能，包括了多晶金刚石薄膜、类金刚石薄膜（DLC）、纳米结构金刚石薄膜、用酸处理后的金刚石薄膜等的性能，给出了几种典型的金刚石薄膜场致发射阴极结构。     

金刚石合成研究进展

金刚石在工业、科技、国防等领域具有非常重要的应用前景,本论文论述了宝石级金刚石、微晶金刚石以及纳米金刚石人工合成方法一进最近的研究进展,并对金刚石产品未来的发展做了展望。     

国内金刚石绳锯

阐述了金刚石绳锯的基本组成、工作原理、金刚石串珠绳的结构以及金刚石串珠的类型，通过对我国几种主要金刚石绳锯的介绍，总结了国内金刚石绳锯和串珠制造形式的发展现状，分析了目前我国金刚石绳锯发展的不足，展望了其发展趋势以及广阔的应用前景。     

球形金刚石的生长机理研究

用热丝化学气相沉积设备研究了钢渗铬层、P-Si（100）基片和三氧化二铝基底表面形成的球形金刚石．研究结果表明：在不适合球形金刚石形成的工艺爷件下,在P-Si（100）基片和三氧化二铝表面沉积的晶形很好的金刚石膜中也存在球形金刚石团块（称为异常长大金刚石团块）;首次使用金刚石“异常晶核”解释了异常长大金刚石团块的形成．球形金刚石膜由异常长大金刚石团块组成．异常长大金刚石团块的形成不但与沉积工艺参数有关,而且与CVD金刚石生长特性有关．     

金刚石/硅复合材料的制备和导热性能

为探索新型热沉用散热材料,采用高温高压方法烧结制备了金刚石/硅复合材料,并研究了金刚石大小粒度混粉、金刚石含量、渗硅工艺以及金刚石表面镀钛对复合材料的致密度和导热性能的影响.结果表明:在大粒度金刚石粉中掺入小粒度金刚石粉、渗硅和金刚石表面镀钛处理都可提高金刚石/硅复合材料的致密度和热导率;随着金刚石含量增大,复合材料热导率提高;其中75/63μm镀钛金刚石颗粒与40/7μm金刚石颗粒的混粉,当混粉质量分数为95%时,在4～5GPa、1400℃高温高压渗硅烧结,金刚石/硅复合材料的热导率可高达468.3W·m-1·K-1.     

金刚石与钢体的盐浴焊

用氯基盐浴作为加热方法,实现了金刚石表面金属钛的渗覆以及金刚石与20Ni4Mo钢的焊接。试验中采用了Ni基合金作为中间过渡层金属。试验结果表明:盐浴加热既可有效地避免金刚石在高温下的石墨化,又不影响金刚石的性能;利用金属Ti和Ni形成低溶点共晶,来实现金刚石与钢体的接触熔化焊,大大降低了加热温度,为金刚石工具的焊接技术开辟了一条有效途径。金刚石与钢盐浴焊具有加工成本低、操作简便、连接强度高的优点。     

直流电弧等离体喷射CVD金刚石生长面的浸润性研究

为了开展CVD金刚石生长面的浸润性研究,采用直流电弧等离体喷射技术,制备了纳米金刚石自支撑膜、微米金刚石自支撑膜以及毫米单晶金刚石.结果发现：对于相同的金刚石生长表面,接触角按甘油、饱和葡萄糖水溶液、饱和NaCl水溶液和蒸馏水的顺序逐渐增大,表明所制备金刚石的表面对各液体的浸润性逐渐变差;而对于同种滴液,接触角在不同的金刚石表面表现出不同的大小,说明不同的CVD金刚石对于同种液体具有不同的浸润性.而表面能的计算结果表明纳米金刚石自支撑膜生长面的表面能最高,其次是微米自支撑金刚石膜,而单晶金刚石的表面能最小.     

陶瓷磨削中金刚石砂轮磨损形式及其生成原因

设计并进行了模拟金属结合剂金刚石砂轮磨削陶瓷的试验．在扫描电镜下，对金刚石砂轮块磨损形貌进行直接观察研究，揭示砂轮磨损形式．利用摩擦学系统分析方法，对磨削系统中的关键要素，如金刚石砂轮、陶瓷工件、空气介质及冷却液等对金刚石砂轮磨损的影响进行了探讨，研究了金刚石砂轮磨损的生成原因     

对桃源县青林地区金刚石砂矿开发利用前景浅析

本文介绍了桃源县青林地区金刚石砂矿成矿特征、开发利用现状,并对开发前景进行分析,区内金刚石砂矿及伴生矿金矿资源丰富,督粮冲金刚石砂矿经正式勘探,探明金刚石砂矿储量7.8万克拉,伴生砂金矿储量179kg。金刚石应用于国民经济建设的各个领域,金刚石将以无可替代的优越性能取代单晶硅,成为下一个划时代的材料。金刚石砂矿床是金刚石次生矿床,对于我国金刚石矿产资源比较贫乏而言,本文为该地区金刚石砂矿开发利用提供建设性参考。     

MPCVD法金刚石薄膜的生长影响因素

金刚石具有许多优异的性能，但天然金刚石的价格也比较昂贵。金刚石薄膜的各种性质与天然金刚石几乎相同，具有非常广阔的工业前景。本文采用乙醇和氢气作为工作气源，利用微波等离子体化学气相沉积法，在较低的温度下制备了金刚石薄膜，并研究了反应气压对金刚石薄膜生长的影响。     

Discovery of submicron diamonds within kimberlite in Liaoning Province, China and its significance

Conclusions Although the natural microdiamonds in the non-kimberlite have been well studied by Sobolev, the discovery of submicron diamonds in the kimberlite and not in the form of inclusion is still the first time in the world. Different from the common growth of the kimberlite e-clogite/peridotite with the diamond, the submicron diamonds grow together with the very thin dispersive materials with platina and blende structures. The growth process of the thin lath-shaped diamond crystals from the aggregative parent materials is observed. The densities of the aggregative parent materials are different from place to place within the microspace. The submicron diamonds and their parasitized diamonds formed in different generations.     

CL and FTIR analysis on the diamonds in Wafangdian, Liaoning Province

The CL images show that the internal structures of the diamonds in Wafangdian, Liaoning Province is classified as three types: simple growth girdle zone, multi-stage growth complex girdle zone, and rare agate-like structure. These internal features reflect the complexity of growth processes of the diamonds. The FTIR analyses in micro area on diamond plates reveal the heterogeneity of the impurities of nitrogen and hydrogen. The variety of nitrogen contents and nitrogen aggregation states have been revealed not only in different diamonds from one kimberlite pipe but also in different zones of one diamond. The extent of conversion A defects to the aggregated B form is a function of the nitrogen aggregation temperature (TNA), mantle residence time (tMR), and nitrogen concentration of diamond. The interval of 0.6-0.7Ga from core to rim of diamond growth is obtained by using the FTIR curves and some geological data. The long period of diamond growth is identical with the feature in CL image.     

山东郯城地区金刚石砂矿地质地貌特征

郯城金刚石砂矿属冲积层产状被破坏的阶地砂矿，金刚石产在残余二阶地冲积砂砾层中，金刚石颗粒大，宝石级金刚石较多，是宝石工业的重要原料基地。     

人工合成金刚石技术比较

静压法是当前工业合成金刚石的主要的合成手段,合成工业用金刚石主要采用静压法中的静压触媒法,合成宝石级金刚石主要采用静压晶种触媒法生产,通过静压法中的直接变换法,纯净的多晶石墨棒可以在短时间内转化为多晶金刚石,二十世纪八十年代还出现了一种在低压下生长金刚石的新方法——化学气相沉积法(CVD),目前只能用于制备金刚石薄膜,本文通过总结比较各种金刚石合成技术,提出了利用激光控制金刚石生长的设想,使用这种方法将提高金刚石的质量,     

Variations in carbon isotopic composition in the subcontinental lithospheric mantle beneath the Yangtze and North China Cratons: Evidence from in-situ analysis of diamonds using SIMS

The components and evolution of subcontinental lithospheric mantle beneath the North China Craton and the Yangtze Craton is a current topic in the geological study of China and the carbon isotopic composition of diamond is one of the most direct probes into cratonic lithospheric mantle processes.In this paper,in-situ SIMS(Secondary Ion Mass Spectrometry) techniques were used to analyze the carbon isotope compositions at different internal growth zones of diamonds from Shandong and Liaoning in the North China Craton and Hunan in the Yangtze Craton.It was found that the carbon isotopic range of diamonds from the North China Craton are rather distinct from those of the Yangtze Craton;the former has a range of 6.0‰ to 2.0‰(relative to VPDB) with an average value of 3.0‰ in their core areas,which is consistent with global peridotitic diamonds;the diamonds from the Yangtze Craton,however,have a carbon isotopic range from 8.6‰ to 3.0‰ with an average value of 7.4‰ in their core areas,being more consistent with global eclogitic diamonds.The variations of carbon isotope ratios between different internal growth zones in individual diamonds were different in the three diamond localities studied.There was a clear correlation between changes in carbon isotopic composition and phases of diamond dissolution and new growth,while no correlation was observed between δ13C and internal inclusions.The variations suggest that the carbon isotopic compositions of mantle fluids were changing during the process of diamond crystallization,and that the heterogeneity of the carbon isotopic composition in mantle carbon reservoirs was a more important factor than carbon isotope fractionation in controlling the carbon isotopic compositions and their variation in diamonds.In addition,the preliminary results of in-situ nitrogen analyses demonstrated that the variation of carbon isotopic compositions between the core and outer growth zones does not correlate with nitrogen abundances,implying either that diamonds crystallized in an open environment or that the carbon isotopic composition and nitrogen contents in mantle fluids were controlled by other,not yet understood factors.The experimental results provide hints that the isotopic composition of carbon and its original sources were different in metasomatic fluids controlling diamond formation in the mantle beneath the North China Craton and the Yangtze Craton.     

Research on a New Type of Diamond Saw Plate

With the developing of stone material, diamond saw pl ate is used widely, and in order to increase cutting efficiency and life-span o f diamond saw plate, there are a lot of research jobs of segment for diamond saw plate. Layered segment for diamond saw plate is to divide single segment into s everal cutting tools by its structure, then increases rock-cutting faces. For i mpregnated man-made diamond saw plate, the bonding strength of diamonds with ma trix material has great effect on its life and service....     

金刚石产品的脉冲激光制备与应用

详细介绍了用脉冲激光法制备金刚石产品的发展过程 ,并总结了脉冲激光沉积 (PLD)、液体靶脉冲激沉积 (LYPLD)以及脉冲激光诱导液 -固界面反应 (PLIIR)等几种典型的实验方法、实验装置以及所取得的成果 在脉冲激光沉积法 (PLD)制备金刚石薄膜方面重点总结了最近比较新颖的液体靶脉冲激光沉积技术 ,而在金刚石纳米晶的制备方面综述了脉冲激光诱导液 -固界面反应法 ,此法在制备亚稳态纳米晶体方面显示出了较独特的优越性 图 4,参 1 6     

Fe-Ni-C粉末触媒体系金刚石的合成与表征

利用FeNi粉末触媒在六面顶压机上进行工业金刚石单晶的合成与表征. 结果表明: 在Fe-Ni-C体系合成了优质的六面体、 六-八面体及八面体金刚石单晶; 金刚石{111}晶面的生长属于二维层状生长机制; 金刚石中的包裹体主要由FeNi合金组成.     

熔射沉积金属与金刚石结合界面的实验

通过实验研究,提出空气状态下采用等离子熔射金属焊接金刚石的新方法.将等离子体熔化的钛金属熔滴,喷射至经王水浸蚀的,采用热压烧结方法制备的金刚石节块表面,然后制备自然断口以观其微观状态.通过SEM照片,研究断口中金刚石经过热压烧结与熔射沉积后的金属与金刚石界面微观状态;分析比较被熔射金属包镶的金刚石与被热压烧结的金属粉末包镶的金刚石,以及与其包镶体之间的结合强度的差异.最后,对金属与金刚石之间的界面形成机制进行初步的探讨.     

基于ANSYS有限元的Ag-Cu-Ti合金钎焊金刚石磨粒残余应力分析与优化研究

研究金刚石包埋深度分别为20%、40%、50%、60%、80%的钎料对单层钎焊金刚石工具性能的影响。利用有限元软件ANSYS对Ag-Cu-Ti合金钎焊金刚石过程中形成的残余应力进行数值模拟,采用线性和静态的分析方法。研究结果表明,最大应力值位于金刚石和钎料界面结合处的最底部,应力从金刚石底部到顶部逐渐减小,金刚石受拉应力,钎料和工具基体受压应力。当金刚石的包埋深度介于20%与40%之间时,钎焊残余应力最小。