共查询到11条相似文献,搜索用时 46 毫秒
1.
Oil cracking: An important way for highly efficient generation of gas from marine source rock kitchen 总被引:7,自引:0,他引:7
ZHAO Wenzhi WANG Zhaoyun ZHANG Shuichang WANG Hongjun WANG Yunpeng 《科学通报(英文版)》2005,50(22):2628-2635
The potentials of gas generation by kerogen in the late period and by crude oil cracking are closely related to the origin of natural gas in the high- to over mature marine area and their exploration perspectives. The carbon structure of kerogens, with different types and at different evolution stages, have been experimentally studied using the high magnetic field solid ^13C nuclear magnetic resonance technique in order to determine the oil and gas potential of kerogens. Results show that the contents of gas potential carbon(GPC) of types Ⅰ, Ⅱ, Ⅲ kerogens at the high- to over mature stage are very low, indicating their weak gas-generating capacity and limited gas production; however, the content of oil potential carbon(OPC) of the low mature type Ⅰ kerogen is much higher, implying that a large amount of crude oil generated during the oil-generating period will be the material for later gas generation by oil cracking. The kinetic experiment of gas generation by crude oil cracking shows that, when the temperature is about 160℃(R0=1.6%), the crude oil will start to produce large amounts of gas; the temperature range for major gas generation of crude oil is higher than that of the kerogens, and the gas production is 2 to 4 times higher than that of kerogens. The natural gas derived from oil cracking (called oil-cracked gas) is much abundant in methyl hexamethylene, which is quite different from the natural gas produced by thermal degradation of kerogens (named kerogen degradation gas) at high- to over mature stage. 相似文献
2.
陈中红 《山东科技大学学报(自然科学版)》2012,(3):22-31
原油裂解气可以作为重要的天然气来源,将是未来重要的勘探方向之一。对原油裂解成气研究方法、产物特征、识别标志、原油裂解程度定量表征、原油裂解成气门限、主成气期、影响因素以及中国原油裂解气区的主要勘探及研究态势进行了总结和评述。认为原油裂解成气的门限和主生气期是原油裂解气形成中的关键科学问题,尤其是在超压条件下,原油裂解成气的主生气门限、化学动力学问题及原油裂解成气定量预测等研究需要加强;盐岩及其体系中的不同矿物对原油裂解成气的影响及机理尚不明确;中国东部湖相原油裂解气研究仍显薄弱,为加强对湖相裂解气形成与分布规律的正确认识,丰富原油裂解气形成理论,缓解中国东部天然气资源短缺问题,针对中国东部陆相断陷湖盆应进一步开展原油裂解气的相关研究。 相似文献
3.
Hui Tian XianMing Xiao LiGuo Yang ZhongYao Xiao LiGuo Guo JiaGui Shen YuHong Lu 《科学通报(英文版)》2009,54(7):1217-1224
Although the gas cracked from oil has been believed to be one of the important sources in highly ma-tured marine basins, there are still some debates on its resource potentials and chemical and isotopic compositions. In this study a Cambrian-sourced marine oil sample from the Silurian reservoir of well TZ62 in the central Tarim basin was pyrolyzed using sealed gold tubes with two different pyrolysis schemes: continuous pyrolysis in a closed system and stepwise semi-open pyrolysis. The results show that the maximum weight yield of C1–5 gases occurs at EasyRo=2.3% and the residual gas poten-tial after this maturity is only 43.4 mL/g, about 12% of the yield of 361 mL/g at EasyRo=2.3%. Combined with the results of kinetic modeling, the main stage of gas generation from oil cracking is believed within the EasyRo=1.6%―2.3%. The increase in the volume yield of C1–5 gases at EasyRo>2.3% in a closed system is mainly related to the re-cracking of previously formed C2–5 wet gases, not the direct cracking of oil. The stepwise pyrolysis experiments show that the gas from the cracking of residual oil at EasyRo>2.3% is characterized by very high dryness index (higher than 92%) and heavy methane carbon isotopes ranging from -28.7‰ to -26.7‰, which is quite different from the gases from the con-tinuous pyrolysis in a closed system. The kinetic modeling of methane carbon isotope fractionation shows that the carbon isotopes of methane within the main stage of gas generation (EasyRo<2.3%) are far lighter than the carbon isotopes of the precursor oils under a geological heating rate of 2 ℃/Ma. The above observations and results provide some new clues to the accurate recognition and objective re-source evaluation of oil cracking gas in highly mature marine basins. 相似文献
4.
通过辽河探区西部凹陷原油溶解气油比变化特征及其与原油密度关系,分析了原油溶解气逸出量分布与油气成藏的关系.原油溶解气油比一般随深度增加而增大,随深度变浅而降低,与原油密度有较好的相关性.依据原油密度与原油溶解气油比相关的数学模型确定了单位质量原油溶解气逸出量及其分布特征.凹陷内部的单位质量原油溶解气逸出量相对较小,但保存条件好,有利于气藏的形成;而凹陷边缘单位质量原油溶解气逸出量一般较高,但保存条件差,对天然气成藏不利. 相似文献
5.
运用重油催化裂化十一集总动力学模型的工业应用软件 RCCLK,对催化裂化装置掺炼焦化蜡油和焦化柴油的工况进行了模拟。结果表明 ,模拟预测计算结果能较好地符合催化裂化反应规律 ,为催化裂化掺炼焦化蜡油、柴油选择合理的操作条件提供了依据 相似文献
6.
鄂尔多斯盆地北部上古生界深盆气成藏剖析 总被引:6,自引:0,他引:6
鄂尔多斯盆地北部上古生界气藏为一典型的深盆气藏,其成藏要素主要包括平缓的单斜、充足的气源、渐变的储层、低渗透储层与气源岩的紧密接触及良好的封闭条件.成藏事件的研究表明上古生界储盖配套、圈闭形成与油气生成和运聚匹配,具有较好的成藏基础.成藏模式的划分指出了该区今后油气勘探方向,即在气带范围内寻找大型地层圈闭及岩性圈闭是天然气勘探的关键,在水带内的背斜圈闭和背斜-岩性复合圈闭是天然气勘探的有利靶区. 相似文献
7.
李玉蓉 《成都理工大学学报(自然科学版)》2012,39(4):434-437
原油体积系数是新增区块储量计算必需的参数.鉴于在油田勘探开发中后期通过高压物性分析来获取体积系数通常难以实施,作者以胜利油区历年来高压物性分析的大量数据为依据,在全面分析各种影响因素的基础上,提出了一种新的基于油藏成藏规律认识的体积系数求取新方法.该方法一方面通过多元回归考虑油藏埋深、地面油密度、温度、压力等与体积系数求取相关且通过常规试油或测试就能获得的参数对体积系数的影响,另一方面通过残差类别进行修正以考虑地下影响因素(通过常规试油或测试不能获取),如气油比、饱和压力等对体积系数的影响,从而提高了体积系数求取的精度. 相似文献
8.
在对三塘湖盆地不同层位原油物性分布特征研究的基础上,结合地质条件,分析了影响原油物性特征的各种因素。原油物性不仅受原油族组成的影响,而且也受成熟度、埋藏深度、保存条件、组分重力分异作用等的影响。相对密度的影响因素较多,主要包括饱和烃、芳香烃、胶质含量、沥青质和含蜡量等,粘度主要受饱和烃、芳香烃、胶质含量的影响,沥青质和含蜡量对其影响不大。牛圈湖油田芦草沟组原油物性变化不同于其它地区和其它层位,其随深度增加而升高,主要是油气藏中烃类重力分异作用的结果。其它地区原油物性随深度增加而降低的特征主要与保存条件、水洗作用、氧化作用等因素有关。该认识对于其它地区原油物性分布特征的研究具有重要的参考价值。 相似文献
9.
重油催化裂化集总模型在指导裂化催化剂选用方面的研究 总被引:3,自引:2,他引:1
在已开发的重油催化裂化十集总动力学模型的基础上、通过实验和参数估计,分别确定了RHZ-200,ZCM-7,CRC-3三种裂化催化剂的十一集总动力学模型参数,并运用模型的工业应用软件RCCLK,对这三种催化剂进行了工业验证计算。 相似文献
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石油的次生变化对石油性质的改造有时会超过有机质来源和热成熟度作用的影响,而热蚀变是地史时期地质体中一种较为常见的次生变化。本文选取准噶尔盆地南缘原油样品系统模拟热蚀变过程,并进行数据分析,从中筛选出相关性良好的菲/甲基菲(P/MP)比值和(3-MP+2-MP)/(9-MP+1-MP)比值两项指标,它们能够很好地反映原油热变程度;根据筛选出的这两项指标,制作了判别原油热蚀变程度的图版。应用该图版分析准噶尔盆地南缘霍尔果斯和呼图壁油气田原油热蚀变程度,结果显示,霍尔果斯霍10井原油可能为原生油藏,热变程度较低,而霍浅1和霍002原油可能是由埋藏较深、热变程度高的原始油藏向上运移产生的次生油气藏;准噶尔南缘的安5井、石南31井及呼图壁气田中的呼2井原油处于正常成熟阶段,表明其所处油气藏基本上为原生油气藏。 相似文献