基于跨黏度纤维素对磨螺杆表面的实验与仿真研究

采用摩擦学性能测试与EDEM仿真模拟相结合的方法,研究了跨黏度纤维素在不同转速和不同载荷下的摩擦学行为,以及在摩擦过程中对螺杆表面的磨损机制。跨黏度纤维素的摩擦学性能测试采用“球-盘”式摩擦磨损试验机,而对螺杆的磨损机制采用Archard Wear磨粒磨损计算公式及离散元方法构建纤维素及螺杆磨损机制模型。研究结果表明,在高转速60 r/min条件下,跨黏度纤维素的磨损规律受施加载荷大小的影响较大,15 mPa·s的摩擦系数在0.19至0.44之间,100 000 mPa·s的摩擦系数在0.25至0.52之间;在低转速10 r/min条件下,摩擦系数受法向载荷影响波动较大,15 mPa·s的摩擦系数在0.25至0.44之间,100 000 mPa·s的摩擦系数在0.24至0.58之间。通过EDEM仿真模拟发现,随着纤维素黏度增大,纤维素与螺杆表面的接触面积随之减少,螺棱在对纤维素推动的过程中,不易造成纤维素在螺槽中的相对滑动,进而减少螺槽部位的磨损。纤维素的黏度大小对润滑效果有一定影响,但并不是决定性因素;影响纤维素的润滑效果和磨损机理的主要是加载载荷,其中磨损程度随着载荷变大而加深,而...     

测量低黏度流体介质金属管浮子流量计的仿真研究

为深入研究金属管浮子流量计的工作机理,采用计算流体力学和流体力学中湍流模式理论,对金属管流量计流场进行了数值仿真研究,获得了低黏度流体介质中浮子受力及浮子在受力平衡下的流量．数值模拟与物理实验标定数据的对比表明,模拟计算的流量最大满度误差为5．469 5％,平均满度误差为2．473 1％,说明数值仿真模型能满足金属管浮子流量计设计的需要．     

接触应力对跨尺度纤维素摩擦学性能的影响

仿照大型双螺杆挤出机工作时机筒内壁与纤维素填料之间的摩擦学行为,通过实验测试与表征分析研究了不同载荷和转速条件下多尺度羟丙基甲基纤维素(HPMC)的摩擦学性能,探讨并揭示了服役工况条件和黏度因素对HPMC摩擦学性能的影响规律及其磨损机理。研究结果表明,低接触应力0.72 GPa条件下,跨尺度纤维素的磨损规律受转速的影响较大,100 mPa·s的HPMC摩擦系数最低,在15 r/min时为0.06,在60 r/min时为0.28;在高接触应力1.14 GPa条件下,400 mPa·s的HPMC摩擦系数在60 r/min时最低为0.21。低转速组的磨损机理表现为轻微黏着磨损;高转速组的磨损机理在HPMC黏度低时表现为磨粒磨损中的三体磨损,HPMC黏度高时表现为黏着磨损。     

清洁压裂液在奈曼油田的应用

清洁压裂液是一种表面活性剂凝胶压裂液,基本配方为1.8%十二烷基三甲基溴化铵CTAB+0.7%水杨酸钠NaSal,在70℃下以145.8 s-1率剪切1 h,黏度大于110 mPa*s.破胶后黏度小于5 mPa*s,残渣为0 mg/L,对导流能力的伤害率小于5%.现场试验1口井,压裂后平均日产液14.75 t,日产油7.01 t,见到了明显的压裂效果.     

水平式金属管浮子流量计的仿真与实验

利用基于计算流体力学的流量传感器设计方法实现了对适合安装于水平管道的特殊结构的金属管浮子流量计三维湍流流场的数值仿真研究．流场仿真所需的模型采用GAMBIT软件建立，通过FLUNT软件进行仿真，仿真过程中利用受力平衡来控制计算精度．数值仿真结果和物理实验结果比较，浮子受力平衡误差绝对值为2．01％时，流量误差绝对值为0．70％，证实了仿真结果的准确性．同时，利用流场仿真信息对流量传感器结构做了进一步的优化，解决了水平式金属管浮子流量计在大流量下的浮子振动问题．     

N-月桂酰基谷氨酸钾/芥酸钾复合阴离子表面活性剂蠕虫状胶束及其性能研究

以N-月桂酰基谷氨酸钾（KLAD）、芥酸钾（KEU）及两者复合体系（KAU）为研究对象,分别考察了KCl及不同有机反离子对KLAD、KEU及KAU水溶液性能的影响,优化出KLAD/KCl、KEU/苄基三丙基氯化铵（BTAC）及KAU/BTAC/KCl3种黏弹性蠕虫状胶束体系. 通过表观黏度法研究了3种体系的耐温及耐剪切性能,并对各体系的破胶性能及携砂性能进行了评价. 结果表明,T=100℃时,KLAD/KCl及KEU/BTAC体系的表观黏度（η_a）仅为19.2和37.7mPa·s,而KAU/BTAC/KCl体系的η_a高达82.5mPa·s;T=100℃且连续剪切60min后,KLAD/KCl及KEU/BTAC体系的η_a分别降至14.0mPa·s和19.3mPa·s,而KAU/BTAC/KCl体系仍保持在52.9mPa·s以上. 携砂比为10%时,3种体系的沉降速度分别为0.294,0.113及0.067cm·min-1. KAU/BTAC/KCl体系耐较高温度、耐剪切,携砂性能优越. 有机反离子BTAC与无机反离子KCl对蠕虫状胶束具有较高表观黏度产生了协同效应.      

纤维素/二氧化钛复合材料的光催化性研究

通过控制尿素分解速率来改变体系pH的方法,将钛酸丁酯水解的胶体二氧化钛吸附到天然高分子纤维素上,得到纤维素/二氧化钛复合材料.分别以紫外光或太阳光为光源,研究纤维素/二氧化钛复合材料对甲基橙水溶液的催化降解性能.用傅里叶红外光谱仪表征了复合材料的结构.结果表明:二氧化钛与纤维素形成的氢键等分子间作用力使二氧化钛被吸附到纤维素上,复合材料出现787cm 1的O Ti O键的吸收峰.纤维素与钛酸丁酯的较佳比例为20g与4.3mL.在紫外光照射100min下,复合材料对甲基橙水溶液的光催化降解率为100%;在太阳光照射150 min,复合材料对甲基橙水溶液的光催化降解率为81%;复合材料可反复降解甲基橙水溶液5次.本实验合成的纤维素/二氧化钛复合材料具有可完全生物降解、能利用太阳光、反复催化降解甲基橙水溶液的特性,可应用于处理甲基橙等染料废水.     

金属管浮子流量计的测量原理及应用

简要介绍金属管浮子流量计在流量测量时的工作原理,并给出了流量计算公式的推导及应用。     

摆臂浮子式波能装置的运动及能量转换性能

 海洋波浪能是一种清洁的海洋可再生能源,受到了广泛关注。设计和制作了一种摆臂浮子式波浪能实验装置,并在船模拖曳水池进行实验,以研究该装置的运动和能量转换性能。摆臂浮子式波浪能实验装置由两个浮子、两个摆臂以及机械传动装置和发电机组成,装置固定于拖车之上。通过水池实验测量不同工况下浮子的垂向运动加速度和发电机的输出电压,分析波高和周期对浮子运动的影响,计算装置在不同波浪条件下的能量转换效率。从实验结果可知,在波浪作用下,装置的垂荡运动性能较好,具有较高的能量转换效率。     

温敏性PAC/HPMC水凝胶的制备与性能研究

以醚-羟丙甲基纤维素(HPMC),聚阴离子纤维素(PAC)和氯化铝为原料,通过物理方法制备了一系列热缩型温敏性PAC/HPMC水凝胶,并对凝胶强度、溶胀动力学、耐盐性和温敏性进行了研究. 结果表明:PAC/HPMC水凝胶强度受到HPMC用量和相对分子质量影响. 在研究范围内,当HPMC的2.0%水溶液黏度为4Pa·s,加入量为0.10%时所制备的凝胶强度最大;与纯PAC凝胶相比,PAC/HPMC凝胶在去离子水中的平衡溶涨率有显著提高;PAC/HPMC凝胶的溶胀率随着NaCl溶液浓度的增加而减小,PAC/HPMC凝胶在相同浓度NaCl溶液中的溶涨率高于纯PAC凝胶;HPMC的存在使PAC/HPMC凝胶具有了温敏性,由于HPMC与PAC分子间存在协同效应,PAC/HPMC凝胶的LCST比HPMC的相应温度低.     

Markedness and its Interpretation in Language Use

Language markedness is a common phenomenon in languages, and is reflected from hearing, vision and sense, i.e. the variation in the three aspects such as phonology, morphology and semantics. This paper focuses on the interpretation of markedness in language use following the three perspectives, i.e. pragmatic interpretation, psychological interpretation and cognitive interpretation, with an aim to define the function of markedness.     

Features of Women's language

Language is a means of verbal communication. People use language to communicate with each other. In the society, no two speakers are exactly alike in the way of speaking. Some differences are due to age, gender, statue and personality. Above all, gender is one of the obvious reasons. The writer of this paper tries to describe the features of women＇s language from these perspectives： pronunciation, intonation, diction, subjects, grammar and discourse. From the discussion of the features of women＇s language, more attention should be paid to language use in social context. What＇s more, the linguistic phenomena in a speaking community can be understood more thoroughly.     

低渗透非均质砂岩油藏启动压力梯度研究

理论推导与室内实验相结合,建立了低渗透非均质砂岩油藏启动压力梯度确定方法。首先借助油藏流场与电场相似的原理,推导了非均质砂岩油藏启动压力梯度计算公式。其次基于稳定流实验方法,建立了非均质砂岩油藏启动压力梯度测试方法。结果表明:低渗透非均质砂岩油藏的启动压力梯度确定遵循两个等效原则。平面非均质油藏的启动压力梯度等于各级渗透率段的启动压力梯度关于长度的加权平均;纵向非均质油藏的启动压力梯度等于各渗透率层的启动压力梯度关于渗透率与渗流面积乘积的加权平均。研究成果可用于有效指导低渗透非均质砂岩油藏的合理井距确定,促进该类油藏的高效开发。     

On Tragic Consciousness In The Works By Ernest Hemingway

As an American modern novelist who were famous in the literary world, Hemingway was not a person who always followed the trend but a sharp observer. At the same time, he was a tragedy maestro, he paid great attention on existence, fate and end-result. The dramatis personae's tragedy of his works was an extreme limit by all means tragedy on the meaning of fearless challenge that failed. The beauty of tragedy was not produced on the destruction of life, but now this kind of value was in the impact activity. They performed for the reader about the tragedy on challenging for the limit and the death.     

Achieving Unusual States of Matter Under High Pressure

正The periodicity of the elements and the non-reactivity of the inner-shell electrons are two related principles of chemistry,rooted in the atomic shell structure.Within compounds,Group I elements,for example,invariably assume the+1 oxidation state,and their chemical properties differ completely from those of the p-block elements.These general rules govern our understanding of chemical structures and reactions.Using first principles calcula-     

Exchange-Correlation and Electronic Excitation Energies from Pairing Matrix Fluctuations

We have developed an adiabatic connection to formulate the ground-state exchange-correlation energy in terms of pairing matrix linear fluctuations.This formulation of the exchange-correlation energy opens a new channel for density functional approximations based on the many-body perturbation theory.We illustrate the potential of such approaches with an approximation based on the particle-particle Random Phase Approximation(pp-RPA).This re-     

Density Functional Theory for the Response of Periodic Systems to Electric Fields Based on the Vector Potential Approach

正The electronic and nuclear(structural/vibrational)response of 1D-3D nanoscale systems to electric fields gives rise to a host of optical,mechanical,spectral,etc.properties that are of high theoretical and applied interest.Due to the computational difficulty of treating such large systems it is convenient to model them as infinite and periodic(at least,in first approximation).The fundamental theoretical/computational problem in doing so is that     

On the Thermodynamic Limit for Responses to Static Electromagnetic Fields

For molecular systems,the quantum-mechanical treatment of their responses to static electromagnetic fields usually employs a scalar-potential treatment of the electric field and a vector-potential treatment of the magnetic field.Although the potential for each field separately is associated with the choice of an(unphysical)origin,the precise choice of the origin for the electrostatic field has little consequences for the results.This is different for the     

An affordable accurate evaluation of the binding conformations predicted by molecular docking studies in bio-system

Franck-Condon factors bridge the gap between theoretical modeling and experimental observations for molecular electronic spectroscopy and electron transfer.Under the displaced harmonic oscillator approximation,multidimensional Franck-Condon factors are decomposed into a product of many one-dimensional(1D)Franck-Condon(FC)factors,and each 1D-FC factor is associated with one Huang-Rhys factor that determines the leading contribution of     

Call for Papers

<正>"The Journal of Shanghai Normal University:Mathematics"is published by Shanghai Normal University as regular issues of The Journal of Shanghai Normal University each year from 2014 in English.The editors-in-chief of the issues are professors Yuhao Cong and Maoan Han.The Journal of Shanghai Normal University was started in 1958 with