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1.
应用热动力学1.5级反应的时间变量法,在20℃和30℃下研究了表面活性剂复配混合胶束溶液中,以NaHSO3为单组分引发剂的丙烯酰胺聚合反应。结果表明,阳,阴与两性离子表面活性剂复配混合胶束体系(CTAB/LSS,TTAB/LSS,SDS/LSS)对聚合反应有明显的催化作用,非与阳离子表面活性剂复配混合胶束体系(Brij35/CTAB,Brij35/TTAB,Brij35/DTAB0对该反应有小的催  相似文献   

2.
采用目视变温法及DTA法对NaNO2-NaOAc-HCOONa三元体系的固-液平衡作了研究,实验发现体系为一般共熔型,其低共熔点为160℃,5%NaNO2,50%HCOONa。  相似文献   

3.
用直接法掺加Cr2O3烧制了绿色硫铝酸盐水泥。在实验条件下,通过DTA测试发现Cr2O3能降低CaCO3的分解温度(10~19℃)和开始分解温度(27~35℃),并能促进CaO的吸收,从而使水泥所测试的各龄期强度均有提高。  相似文献   

4.
介绍氧瓶或消化分解LaCl3-EDTA和YCl3-EDTA法测定有机砷化合物中砷的新方法。Lacl3-EDTA法适用于氧瓶分解,样品含硫有干扰:YCl3-EDTA法不受SO^2-4干扰,因而不适用于以硫酸为主要消化剂的消化分解和测定,测定误差<±0.30%。  相似文献   

5.
应用DTA/T/EGD/GC在线联用技术,对倍半氧化羧乙基锗(Ge-132)在N2气氛中的热分解反应历程(室温~980℃)进行了研究。依据DTA/T/EGD/GC提供的信息,分别对220℃、350℃、650℃、800℃、900℃、980℃等反应温度下的热分解残物,应用XRD仪进行了物相鉴定,并测定了Ge-132在N2气氛中(室温~930℃)的TG/DTG曲线。对DTA曲线上显示的五个吸热效应和一个放热效应的性质作出了判断和验证,并对该热分解反应中逸出气的组成演变、残物中的Ge和GeO2晶相的析出以及GeO2在高温下转化为Ge的反应历程进行了探讨。  相似文献   

6.
制备和表征了包埋Gd-EDTA的脂质体,测定了pH,离子强度,缓冲液组成及温度对Gd-EDTA脂质体的影响,比较了Gd-EDTA脂质体和Gd-EDTA被肿瘤细胞摄入的动力学曲线。结果表明,Gd-EDTA脂质体在37℃和生理条件下最稳定,肿瘤细胞摄入Gd-EDTA脂质快速率是Gd-EDTA的8倍,而释放Gd的速率,Gd-EDTA脂质体远远低于Gd-EDTA,这些结果提供了脂质体包埋Gd-EDTA作为  相似文献   

7.
针刺补肾温阳通络法治疗糖尿病周围神经病变68例   总被引:5,自引:0,他引:5  
目的:观察针刺“补肾温阳通络”法治疗糖尿病周围神经病变(BPN)的临床疗效。方法:以气海、关元、七推夹肾、肾愈米穴,行深刺补法,结合雪芝、黄芪闰注射及电针治疗DPN患者68例,观察其对DPN患者临床症状及神经传导速度的改善作用。结果:针刺后各临床症状的改善率为75% ̄95.3%不等,神经传导速度(NCV)显著升高。结论:针刺补肾温阳通络法可有铲改善DPN校正症状及神经功能。  相似文献   

8.
在碱性介质中于 20-35℃用分光光度法研究了二羟基二过碘酸合镍(IV)配离子 (DDN)氧化天冬氨酸的动力学。结果表明,反应对[Ni(IV)]为一级,对天冬氨酸为正分数级。准 一级速率常数(Kobs)随[OH-]增加而减小,1/kobs对[io-4]有线性关系,表明二羟基一过碘酸合镍 (IV)配离子(DMN)是氧化剂的活性物种。无盐效应且未检出自由基的存在。据此提出了包括 DPN和MPN以及天冬氨酸存在前期平衡的反应机理,并求出相应的活化参数。  相似文献   

9.
研究了Pd-DMTAMB-CTMAB体系的显色条件及性质。在pH3~6时,形成稳定的配合物。λmax为695nm,对比度为175nm;ε=6.65×104,该显色体系不为EDTA所破坏,而其他金属离子的配合物会被EDTA所破坏而褪色,方法的选择性好。  相似文献   

10.
正负离子表面活性剂混合溶液的增溶作用   总被引:9,自引:1,他引:8  
采用分光光度法,测定了十六烷基三甲基溴化铵(CTAB)-十二烷基硫酸钠混合体系在不同的条件下对苯,甲苯的增溶作用。结果表明:在固定CTAB浓度为0.0001mol.L-3的条件下,改变SDS的浓度或在CTAB-SDS混合体系中改变NaBr浓度对苯、甲苯的增溶能力呈“V”字形曲线而变化,随着温度的升高,所有体系的增溶能力都呈增大趋势。  相似文献   

11.
Language markedness is a common phenomenon in languages, and is reflected from hearing, vision and sense, i.e. the variation in the three aspects such as phonology, morphology and semantics. This paper focuses on the interpretation of markedness in language use following the three perspectives, i.e. pragmatic interpretation, psychological interpretation and cognitive interpretation, with an aim to define the function of markedness.  相似文献   

12.
何延凌 《科技信息》2008,(4):258-258
Language is a means of verbal communication. People use language to communicate with each other. In the society, no two speakers are exactly alike in the way of speaking. Some differences are due to age, gender, statue and personality. Above all, gender is one of the obvious reasons. The writer of this paper tries to describe the features of women's language from these perspectives: pronunciation, intonation, diction, subjects, grammar and discourse. From the discussion of the features of women's language, more attention should be paid to language use in social context. What's more, the linguistic phenomena in a speaking community can be understood more thoroughly.  相似文献   

13.
The discovery of the prolific Ordovician Red River reservoirs in 1995 in southeastern Saskatchewan was the catalyst for extensive exploration activity which resulted in the discovery of more than 15 new Red River pools. The best yields of Red River production to date have been from dolomite reservoirs. Understanding the processes of dolomitization is, therefore, crucial for the prediction of the connectivity, spatial distribution and heterogeneity of dolomite reservoirs.The Red River reservoirs in the Midale area consist of 3~4 thin dolomitized zones, with a total thickness of about 20 m, which occur at the top of the Yeoman Formation. Two types of replacement dolomite were recognized in the Red River reservoir: dolomitized burrow infills and dolomitized host matrix. The spatial distribution of dolomite suggests that burrowing organisms played an important role in facilitating the fluid flow in the backfilled sediments. This resulted in penecontemporaneous dolomitization of burrow infills by normal seawater. The dolomite in the host matrix is interpreted as having occurred at shallow burial by evaporitic seawater during precipitation of Lake Almar anhydrite that immediately overlies the Yeoman Formation. However, the low δ18O values of dolomited burrow infills (-5.9‰~ -7.8‰, PDB) and matrix dolomites (-6.6‰~ -8.1‰, avg. -7.4‰ PDB) compared to the estimated values for the late Ordovician marine dolomite could be attributed to modification and alteration of dolomite at higher temperatures during deeper burial, which could also be responsible for its 87Sr/86Sr ratios (0.7084~0.7088) that are higher than suggested for the late Ordovician seawaters (0.7078~0.7080). The trace amounts of saddle dolomite cement in the Red River carbonates are probably related to "cannibalization" of earlier replacement dolomite during the chemical compaction.  相似文献   

14.
理论推导与室内实验相结合,建立了低渗透非均质砂岩油藏启动压力梯度确定方法。首先借助油藏流场与电场相似的原理,推导了非均质砂岩油藏启动压力梯度计算公式。其次基于稳定流实验方法,建立了非均质砂岩油藏启动压力梯度测试方法。结果表明:低渗透非均质砂岩油藏的启动压力梯度确定遵循两个等效原则。平面非均质油藏的启动压力梯度等于各级渗透率段的启动压力梯度关于长度的加权平均;纵向非均质油藏的启动压力梯度等于各渗透率层的启动压力梯度关于渗透率与渗流面积乘积的加权平均。研究成果可用于有效指导低渗透非均质砂岩油藏的合理井距确定,促进该类油藏的高效开发。  相似文献   

15.
As an American modern novelist who were famous in the literary world, Hemingway was not a person who always followed the trend but a sharp observer. At the same time, he was a tragedy maestro, he paid great attention on existence, fate and end-result. The dramatis personae's tragedy of his works was an extreme limit by all means tragedy on the meaning of fearless challenge that failed. The beauty of tragedy was not produced on the destruction of life, but now this kind of value was in the impact activity. They performed for the reader about the tragedy on challenging for the limit and the death.  相似文献   

16.
AcomputergeneratorforrandomlylayeredstructuresYUJia shun1,2,HEZhen hua2(1.TheInstituteofGeologicalandNuclearSciences,NewZealand;2.StateKeyLaboratoryofOilandGasReservoirGeologyandExploitation,ChengduUniversityofTechnology,China)Abstract:Analgorithmisintrod…  相似文献   

17.
There are numerous geometric objects stored in the spatial databases. An importance function in a spatial database is that users can browse the geometric objects as a map efficiently. Thus the spatial database should display the geometric objects users concern about swiftly onto the display window. This process includes two operations:retrieve data from database and then draw them onto screen. Accordingly, to improve the efficiency, we should try to reduce time of both retrieving object and displaying them. The former can be achieved with the aid of spatial index such as R-tree, the latter require to simplify the objects. Simplification means that objects are shown with sufficient but not with unnecessary detail which depend on the scale of browse. So the major problem is how to retrieve data at different detail level efficiently. This paper introduces the implementation of a multi-scale index in the spatial database SISP (Spatial Information Shared Platform) which is generalized from R-tree. The difference between the generalization and the R-tree lies on two facets: One is that every node and geometric object in the generalization is assigned with a importance value which denote the importance of them, and every vertex in the objects are assigned with a importance value,too. The importance value can be use to decide which data should be retrieve from disk in a query. The other difference is that geometric objects in the generalization are divided into one or more sub-blocks, and vertexes are total ordered by their importance value. With the help of the generalized R-tree, one can easily retrieve data at different detail levels.Some experiments are performed on real-life data to evaluate the performance of solutions that separately use normal spatial index and multi-scale spatial index. The results show that the solution using multi-scale index in SISP is satisfying.  相似文献   

18.
In the 19th century the society was controlled by men, and women were just appendants of them, they had not any rights and freedom. But Jane was an exception, she showed some characteristics of early feminist. Jane showed her characteristics of feminism in three aspects: rebellion, equality, and independence. These characteristics were helpful to her success, and feminism is the only way out for women of that time.  相似文献   

19.
正The periodicity of the elements and the non-reactivity of the inner-shell electrons are two related principles of chemistry,rooted in the atomic shell structure.Within compounds,Group I elements,for example,invariably assume the+1 oxidation state,and their chemical properties differ completely from those of the p-block elements.These general rules govern our understanding of chemical structures and reactions.Using first principles calcula-  相似文献   

20.
We have developed an adiabatic connection to formulate the ground-state exchange-correlation energy in terms of pairing matrix linear fluctuations.This formulation of the exchange-correlation energy opens a new channel for density functional approximations based on the many-body perturbation theory.We illustrate the potential of such approaches with an approximation based on the particle-particle Random Phase Approximation(pp-RPA).This re-  相似文献   

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