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1.
Y-TZP和氮气压力对GPSSi_3N_4性能的影响   总被引:1,自引:0,他引:1  
本文研究了Y-TZP(3mol%Y2O3)和氮气压力对GPSSi3N4陶瓷材料的烧结性能和力学性能、相组成及微观结构的影响,添加5wt%、10wt%、15wt%、20wt%Y-TZP的氨化硅复合材料在1770~1800℃,氮气压力分别为1MPa、2MPa、3MPa下烧成,获得相对密度>95%的烧结体。实验结果表明:添加<10wt%的Y-TZP及增大氮气压力有利于改善氰化硅陶瓷材料的烧结性能;Y-TZP可提高Si3N4基体的断裂韧性,添加15wt%TZP的Si3N4材料断裂韧性可达8.33MPam1/2,与基体相比提高30%,微裂纹增韧和第二相粒子增韧为主要增韧机理.  相似文献   

2.
综述了SiC颗粒弥散强化Si3N4基陶瓷材料的研究近况,根据Si3N4和SiC的不同烧结机理对Si3N4/SiCp复相陶瓷材料烧结机理以及SiCp的掺入对材料可烧结性的影响进行了理论上的探讨将SiCp粒子的尺寸对Si3N4/SiCp复相陶瓷材料显微结构和力学性能的影响与材料可烧结性之间的关系进行了分析通过比较热压Si3N4/SiCp复相陶瓷材料和Si3N4/纳米SiCp复相陶瓷材料中SiCp含量对材料显微结构和力学性能的影响,对SiCp弥散强化Si3N4基陶瓷材料的强化效果和强化机理进行了初步的分析  相似文献   

3.
综述了SiC闰弥散强化Si3N4基陶瓷材料的研究近况,根据Si3N4和SiC的不同烧结机理对Si3N4/SiCp复相陶瓷材料烧结机理以及SiCp的掺入对材料可烧结性的影响进行了理论上的探讨。将SiCp粒子的尺寸对Si3N4/SiCp复相陶瓷材料显微结构和力学性能的影响与材料可烧结性之间的关系进行了分析,通过比较热压Si3N4/SiCp复相陶瓷材料和Si3N4/纳米SiCp复相陶瓷材料中SiCp一地  相似文献   

4.
Si3N4-MgO-CeO2陶瓷烧结过程中的致密化与相变   总被引:3,自引:0,他引:3  
氮化硅陶瓷有极大的应用潜力,但由于其强共价键,很难烧结致密化。采用了一种新的MgO-CeO2复合烧结助剂,利用X射线衍射、透射电镜等手段研究了MgO-CeO2复合烧结助剂对氮化硅陶瓷致密化和相变过程的影响,结果发现对Si3N4-MgO-CeO2陶瓷,在1450℃就会有大量液相出现,1500~1550℃为快速致密化阶段,而α-Si3N4→β-Si3N4相变主要发生在1550~1600℃,相变过程滞后于致密化过程。常压烧结Si3N4-MgO-CeO2陶瓷,强度达948MPa,因此,MgO-CeO2是一种非常有效的氮化硅的烧结助剂。  相似文献   

5.
碱土云母可切削玻璃陶瓷的研究   总被引:5,自引:1,他引:5  
基于Ba0.5Mg3(Si3AlO10)F2-Mg2Al4Si5O18-Ca3(PO4)2系统,制备出了含Ba碱土云母为主晶相的可切削玻璃陶瓷,弯曲强度σb=229MPa,断裂韧性KIC=2.48MPa.m^1/2,钻孔速度大于7mm/min。优良性能的获得借助于Ba云母玻璃陶瓷可控的微观组织,即相互交错的云母晶体和“卷心菜”的组织特征。  相似文献   

6.
作者首次发现了Si3N4-MgO-CeO2系陶瓷在烧结过程中玻璃相自动析晶这一独特现象.对于Si3N4-MgO-CeO2系陶瓷在1450℃,MgO-CeO2就会与Si3N4颗粒表面的SiO2反应形成硅酸盐液相,冷却后则成为玻璃相保留在烧结体中;当烧结温度高于1550℃时,作者发现,CeO2仍留在玻璃相中,但MgO会自动析晶出来,其结果是大大减少了烧结体中严重影响其高温性能的玻璃相的含量,对于提高烧结氮化硅陶瓷的高温性能有重要作用  相似文献   

7.
研究了热压烧结Al2O3/nano-SiC复相陶瓷的力学性能及显微结构。研究表明,纳米SiC的引入显著地改善了材料的力学性能,在SiC添加体积分数为10%时,Al2O3/nano-SiC复相陶瓷抗弯强度σf达峰值为869MPa,断裂韧性KIc也达峰值为6.7MPa·m0.5,比纯Al2O3基体材料分别提高138%和81%。TEM观察表明:纳米SiC晶粒主要存在于Al2O3基体晶粒内部,形成独特的“晶内型”结构。当受外力作用时,既能因弥散的纳米颗粒诱发穿晶断裂,且穿晶断裂时,还能因晶内存在第二相颗粒而引起裂纹偏转,起到增强增韧作用。  相似文献   

8.
研究了在ZrO2含量在15wt%晶须含量对Al2O3/TiN/ZrO2/SiCw复合材料的显微结构与力学性能的影响。当SiCw含量由10wt%增加到30wt%时,弯曲强度σf和断裂韧性KIC最高可达1134MPa和12.26MPa.m^1/2。用SEM,TEM观察分析了复合材料的表面抛光组织,断口形貌和微观结构。试验结果表明,复合材料强韧化机制主要为晶拔拔出,相变增韧,裂纹偏转和晶须与基体界面解高  相似文献   

9.
热蚀刻技术是制备陶瓷材料SEM样品的一种新方法,通过对TZP系复相陶瓷和Al2O3-SiCnano纳米复相陶瓷折系统实验,总结了最佳热蚀条件。结果表明:适合的热蚀刻条件可以显示晶界和“内晶型”结构中晶内纳米相的分布,是一种方便实用的陶瓷材料SEM样品的制备方法。  相似文献   

10.
研究了SiC片晶(SiCp)强化Si3N4基复合材料及其力学性能和增韧机理。研究结果表明,加入SiCp使Si3N4材料的强度明显提高,并在SiCp含量(SiCp)=0.20(SiCp的体积分数)时有一峰值,SiCp加入量进一步增加使强度有较大降低。SEM观察表明,裂纹偏转、片晶桥接是主要增韧机理,片晶拔出、基体细化等亦对断裂韧性的增加作出贡献,其作用与晶须增韧的机理相似。  相似文献   

11.
Language markedness is a common phenomenon in languages, and is reflected from hearing, vision and sense, i.e. the variation in the three aspects such as phonology, morphology and semantics. This paper focuses on the interpretation of markedness in language use following the three perspectives, i.e. pragmatic interpretation, psychological interpretation and cognitive interpretation, with an aim to define the function of markedness.  相似文献   

12.
何延凌 《科技信息》2008,(4):258-258
Language is a means of verbal communication. People use language to communicate with each other. In the society, no two speakers are exactly alike in the way of speaking. Some differences are due to age, gender, statue and personality. Above all, gender is one of the obvious reasons. The writer of this paper tries to describe the features of women's language from these perspectives: pronunciation, intonation, diction, subjects, grammar and discourse. From the discussion of the features of women's language, more attention should be paid to language use in social context. What's more, the linguistic phenomena in a speaking community can be understood more thoroughly.  相似文献   

13.
王慧 《科技信息》2008,(10):240-240
Wuthering Heights, Emily Bronte's only novel, was published in December of 1847 under the pseudonym Ellis Bell. The book did not gain immediate success, but it is now thought one of the finest novels in the English language. Catherine is the key character of this masterpiece, because everybody and everything center on her though she had a short life. We can understand this masterpiece better if we know Catherine well.  相似文献   

14.
The Williston Basin is a significant petroleum province, containing oil production zones that include the Middle Cambrian to Lower Ordovician, Upper Ordovician, Middle Devonian, Upper Devonian and Mississippian and within the Jurassic and Cretaceous. The oils of the Williston Basin exhibit a wide range of geochemical characteristics defined as "oil families", although the geochemical signature of the Cambrian Deadwood Formation and Lower Ordovician Winnipeg reservoired oils does not match any "oil family". Despite their close stratigraphic proximity, it is evident that the oils of the Lower Palaeozoic within the Williston Basin are distinct. This suggests the presence of a new "oil family" within the Williston Basin. Diagnostic geochemical signatures occur in the gasoline range chromatograms, within saturate fraction gas chromatograms and biomarker fingerprints. However, some of the established criteria and cross-plots that are currently used to segregate oils into distinct genetic families within the basin do not always meet with success, particularly when applied to the Lower Palaeozoic oils of the Deadwood and Winnipeg Formation.  相似文献   

15.
理论推导与室内实验相结合,建立了低渗透非均质砂岩油藏启动压力梯度确定方法。首先借助油藏流场与电场相似的原理,推导了非均质砂岩油藏启动压力梯度计算公式。其次基于稳定流实验方法,建立了非均质砂岩油藏启动压力梯度测试方法。结果表明:低渗透非均质砂岩油藏的启动压力梯度确定遵循两个等效原则。平面非均质油藏的启动压力梯度等于各级渗透率段的启动压力梯度关于长度的加权平均;纵向非均质油藏的启动压力梯度等于各渗透率层的启动压力梯度关于渗透率与渗流面积乘积的加权平均。研究成果可用于有效指导低渗透非均质砂岩油藏的合理井距确定,促进该类油藏的高效开发。  相似文献   

16.
As an American modern novelist who were famous in the literary world, Hemingway was not a person who always followed the trend but a sharp observer. At the same time, he was a tragedy maestro, he paid great attention on existence, fate and end-result. The dramatis personae's tragedy of his works was an extreme limit by all means tragedy on the meaning of fearless challenge that failed. The beauty of tragedy was not produced on the destruction of life, but now this kind of value was in the impact activity. They performed for the reader about the tragedy on challenging for the limit and the death.  相似文献   

17.
Location based services is promising due to its novel working style and contents.A software platform is proposed to provide application programs of typical location based services and support new applications developing efficiently. The analysis shows that this scheme is easy implemented, low cost and adapt to all kinds of mobile nework system.  相似文献   

18.
正The periodicity of the elements and the non-reactivity of the inner-shell electrons are two related principles of chemistry,rooted in the atomic shell structure.Within compounds,Group I elements,for example,invariably assume the+1 oxidation state,and their chemical properties differ completely from those of the p-block elements.These general rules govern our understanding of chemical structures and reactions.Using first principles calcula-  相似文献   

19.
We have developed an adiabatic connection to formulate the ground-state exchange-correlation energy in terms of pairing matrix linear fluctuations.This formulation of the exchange-correlation energy opens a new channel for density functional approximations based on the many-body perturbation theory.We illustrate the potential of such approaches with an approximation based on the particle-particle Random Phase Approximation(pp-RPA).This re-  相似文献   

20.
正The electronic and nuclear(structural/vibrational)response of 1D-3D nanoscale systems to electric fields gives rise to a host of optical,mechanical,spectral,etc.properties that are of high theoretical and applied interest.Due to the computational difficulty of treating such large systems it is convenient to model them as infinite and periodic(at least,in first approximation).The fundamental theoretical/computational problem in doing so is that  相似文献   

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