器件结构对有机薄膜器件负电阻性能的影响

研究了有机染料掺杂聚合物薄膜器件的J－U特性，发现存在明显的负电阻现象，制备了不同结构的有机染料掺杂聚合物薄膜器件进行了能级分析，表明载流子的不平衡流入对器件J－U曲线负电阻特性影响显著。     

有机电致发光器件的研究进展

有机电致发光器件是近年来国际上研究的一个热点，发展非常迅速。该器件具有自发光、响应快、发光效率高、驱动电压低、能耗低、成本低等许多优点，因此它极有可能成为下一代的平板显示终端。概述了有机电致发光(EL)器件的结构、工作原理、目前研究进展状况、出现的问题以及发展趋势等。     

有机电致发光器件的热传导特性研究

采用简化热阻模型和一维稳态有内热源的热传导方程,对有机电致发光(OLED)器件的热传导特性进行了研究.为了改善OLED器件的性能,设计并实现了一种新型结构的OLED器件.在给定OLED器件的结构、输入功率、对流换热和热物性参数等因素情况下,推导得出OLED器件运行时温度升高与输入功率,基片及各功能层薄膜的热导系数、厚度、面积等之间的关系式,建立了OLED器件内部的温度分布关系.研究结果表明,器件内的有机层和基底的传热性能是影响器件温度分布的重要因素,在功率密度为1.167×104W/m2、外界温度为300 K时,OLED器件在发光层AlQ3中可获得最高温度,其温度值比环境温度高29 K.在研发OLED器件过程中,要提高OLED器件的热稳定性,改善焦耳热效应对OLED器件性能的影响,则需要选用热物性较好的OLED有机材料,使有机层与导热性能良好的电极保持良好接触.通过实验研究,验证了理论分析的正确性.在相同的输入功率情况下,对自制备的若干Al阴极厚度不同的OLED器件进行了比较分析,验证了理论模型的有效性.研究结果对于OLED研发具有重要的价值.     

有机电致发光白光器件的研究

白光有机电致发光器件在显示领域有着极大的应用前景,受到人们广泛的关注.通过对白光有机电致发光器件的结构、工作原理、实验的可行性分析、工艺流程、存在的问题等方面进行了分析,对器件结构进行了优化设计,确定了合理的技术路线,提高白光电致发光器件中各成分的发光效率,从而得到了一种较为理想的有机白光电致发光器件.     

有机聚合物及小分子材料的电致发光器件

论述了有机聚合物及小分子材料的电致发光原理,发光二极管的结构及影响器件稳定性,寿命的原因,总结了目前该领域所取得的成果,展望了下世纪有机发光材料的应用前景和商业化可能性。     

有机电致发光器件稳定性测试系统的设计与实现

针对目前有机电致发光器件的稳定性测试系统电路复杂和成本较高等问题,设计了一种有机电致发光器件稳定性测试系统.该系统采用集成运放组建器件的驱动电源,用硅光电池俘获亮度值,并选用基于PCI总线的采集卡来采集亮度数据和电压数据.该稳定性测试系统不仅能够提供常用的恒流驱动方式,而且可以提供一种电流-电压混合源(正向恒流反向恒压)驱动.由于采用硅光电池代替传统的辉度计,因此大幅度节约了成本;基于PCI总线的采集卡的选择,降低了开发设计的难杂程度,缩短了开发周期.测试结果表明,该系统能够测试不同样品的亮度衰减和电压上升情况,性能稳定,数据可靠.     

有机电致发光器件的电极研究

介绍了有机电致发光器件的电极研究进展,着重分析了电极性能的改进机制。对于阳极,为了利干空穴的注入和可见光透射,一般应选择功函数较高的透明导电材料。由于铟锡氧化物(ITO)是目前使用最为广泛的阳极材料,所以着重探讨了对ITO膜各种处理方法的改进机理,认为虽然氧空位浓度、C污染、Sn浓度都对ITO的表面功函数有影响,但C污染是主要因素;一种较好的处理方法是既能有效清除C污染,同时又尽可能使ITO膜的电阻率降低,所以中度氧等离子体处理是一种较为理想的途径。对于阴极,为了利于电子的注入,应选择功函数较低且化学性质较为稳定的材料;层状阴极可以较好地实现这一目的,并分别从隧穿效应、界面能带弯曲及减少淬灭中心等方面解释了金属/绝缘层双层阴极的改进机理,认为这三个方面共同起了作用,但主次不一。     

有机薄膜电致发光器件的研究进展（综述）

对近几年来有机薄膜电致发光（ＥＬ）器件的研究进展进行了综合评停和分析,有机薄膜ＥＬ器件是近年来国际上研究的一个热点,该器件具有可与集成电路相匹配,直流电压低,发光亮度高,以及它与无机薄膜相比较易实现多色显示等优点。     

具有异质结的聚合物有机薄膜电致发光器件

本文报道了由一层电子传输材料ＰＰＱ和一层空穴传输材料ＰＤＤＯＰＶ构成的有机聚合物异常结发光二极管的实验结果。虽然双层器件的点亮电压高于由纯ＰＤＤＯＰＶ构成的单层器件,但是它在一定电压下,电流密度降低了一个数量级,而亮度却提高了近两个数量级。     

新型顶发射有机电致白光二极管的研究

为了提高顶发射白光有机发光二极管(top-emitting white organic light-emitting diodes,TWOLEDs)色谱稳定性，对一种拥有Ag反射镜的新型双蓝光发光单元顶发射器件展开研究，发现结构为Ag/Glass/ITO/MoO₃(5nm)/TAPC(30nm)/TCTA(5nm)/Firpic:TCTA(10%,20nm)/Firpic:TmPyPb(10%,10nm)TPBi(30nm)/LiF(1nm)/Al(0.8nm)/Ag(22nm)/Alq₃(50nm)的蓝光器件具有最佳光电性能，其最高电流效率可以达到9.76cd·A^-1。基于该结构，结合DCJTB荧光染料制备的颜色转换层实现顶发射白光器件。结果表明，当颜色转换层DCJTB浓度为2.5%时，获得了电流效率为2.45cd·A^-1，CIE色坐标为(0.338,0.337)以及显色指数CRI为72的TWOLEDs，器件微腔效应较弱且光谱随电流密度与观测角度改变仅有微弱变化。     

物理共混制备有机白光电致发光器件

将有机荧光材料NPB,Alq3,DPVBi和Rubrene分别按照一定比例进行物理共混,作为物理混合层,制备了结构为ITO/物理混合层(120 nm)/LiF/Al的有机电致发光器件,研究了物理混合层中不同Rubrene比例对器件性能的影响.结果表明:随着Rubrene共混比例增加,器件色度发生相应改变,并呈现DPVB...     

White organic light-emitting devices fabricated by spin-coating molecular materials

White organic light-emitting device (WOLEDs) employing molecular mixed host (MH) is demonstrated by spin-coating.The spin-coated film functions as light-emitting layer and hole transporting layer,with the former formed by spin-coating solution containing MH of NPB (N.N'-Bis(naphthalene-1-yl)-N,N'-bis(phenyl)-benzidine) and MADN (2-methyl-9,10-di(2-naphthyl) anthracene),blue dye (4,4'-bis[2-(4-(N,N-diphenylamino)phenyl)vinyl]biphenyl) and yellow dye (5,6,11,12-tetraphenylnaphacene).The performances of the de...     

High-efficiency fluorescent organic light-emitting devices using a phosphorescent sensitizer

To obtain the maximum luminous efficiency from an organic material, it is necessary to harness both the spin-symmetric and anti-symmetric molecular excitations (bound electron-hole pairs, or excitons) that result from electrical pumping. This is possible if the material is phosphorescent, and high efficiencies have been observed in phosphorescent organic light-emitting devices. However, phosphorescence in organic molecules is rare at room temperature. The alternative radiative process of fluorescence is more common, but it is approximately 75% less efficient, due to the requirement of spin-symmetry conservation. Here, we demonstrate that this deficiency can be overcome by using a phosphorescent sensitizer to excite a fluorescent dye. The mechanism for energetic coupling between phosphorescent and fluorescent molecular species is a long-range, non-radiative energy transfer: the internal efficiency of fluorescence can be as high as 100%. As an example, we use this approach to nearly quadruple the efficiency of a fluorescent red organic light-emitting device.     

New hybrid encapsulation for flexible organic light-emitting devices on plastic substrates

The hybrid encapsulation for flexible organic light-emitting devices on plastic substrate was investi-gated. The hybrid encapsulation consisted of four periods of AIq3/L.iF layers as the pre-encapsulation layer and a flexible aluminum foil coated with getter as the encapsulation cap. We measured the device lifetime at a continuous constant current of 20 mA/cm2, which corresponded to an initial luminance of 2000 cd/m2. The half-luminance decay time of the encapsulated device was about 458 h. More over, the hybrid encapsulation is ultrathin and flexible, ensuring device bendability.     

Management of singlet and triplet excitons for efficient white organic light-emitting devices

Lighting accounts for approximately 22 per cent of the electricity consumed in buildings in the United States, with 40 per cent of that amount consumed by inefficient (approximately 15 lm W(-1)) incandescent lamps. This has generated increased interest in the use of white electroluminescent organic light-emitting devices, owing to their potential for significantly improved efficiency over incandescent sources combined with low-cost, high-throughput manufacturability. The most impressive characteristics of such devices reported to date have been achieved in all-phosphor-doped devices, which have the potential for 100 per cent internal quantum efficiency: the phosphorescent molecules harness the triplet excitons that constitute three-quarters of the bound electron-hole pairs that form during charge injection, and which (unlike the remaining singlet excitons) would otherwise recombine non-radiatively. Here we introduce a different device concept that exploits a blue fluorescent molecule in exchange for a phosphorescent dopant, in combination with green and red phosphor dopants, to yield high power efficiency and stable colour balance, while maintaining the potential for unity internal quantum efficiency. Two distinct modes of energy transfer within this device serve to channel nearly all of the triplet energy to the phosphorescent dopants, retaining the singlet energy exclusively on the blue fluorescent dopant. Additionally, eliminating the exchange energy loss to the blue fluorophore allows for roughly 20 per cent increased power efficiency compared to a fully phosphorescent device. Our device challenges incandescent sources by exhibiting total external quantum and power efficiencies that peak at 18.7 +/- 0.5 per cent and 37.6 +/- 0.6 lm W(-1), respectively, decreasing to 18.4 +/- 0.5 per cent and 23.8 +/- 0.5 lm W(-1) at a high luminance of 500 cd m(-2).     

单一白色发光层的OLED制备与发光性能研究

研制了两种类型单一白色发光层的有机电致发光器件(OLED),即小分子Zn(BTZ)2的掺杂型器件：ITO／PVK：TPD／Zn(BTZ)2：Rubrene／Al和聚合物LPPP的混合型器件：ITO／混合型发光层／Al,获得了较高的器件亮度和发光效率,且色坐标均非常接近于白色等能点,进而对上述器件的发光和电学性能进行了初步研究。     

一种白色有机电致发光器件的发光和电学性能

以铟锡氧化物(ITO)玻璃基片为衬底,8-羟基喹啉锂(Liq)掺杂红荧烯(Rubrene)作为单一发光层,制备结构为ITO/PTV:TPD/Liq:Rubrene/Alq3/Al的白色有机电致发光器件(OLED),对4种不同掺杂浓度器件进行比较,分析了掺杂剂对器件发光亮度的影响,并对上述器件的发光和电学性能进行了研究和探讨.     

有机发光器件的研究进展及应用前景(综述)

介绍了有机电致发光器件OLED（有机发光二极管）发展的历程，论述了有机电致发光材料及其发光原理和器件结构，讨论了该领域的研究热点问题，展望了OLED在新世纪的应用前景。     

White organic light-emitting devices using Zn（BTZ）2 doped with Rubrene as emitting layer

Zn(BTZ)2 was synthesized from the complex reaction between zinc acetate dihydrate and 2-(2-hydroxyphenyl) benzothiazolate. Then Zn(BTZ)2 was used as main light-emitting material doped with different amounts of fluorescent dye Rubrene and fabricated a series of white organic light emitting devices. The configurations were as follows: ITO/PVK:TPD/Zn(BTZ)2:Rubrene/Al. The doping concentration of Rubrene in Zn(BTZ)2 was 1.2%, 0.12%, 0.08% and 0.05%, respectively. According to the EL spectra and CIE coordinates of the above devices, the optimum doping concentration (0.05%, weight percent) had been determined. The steady and bright white light emitting of the device with 0.05% doping concentration had been obtained, and the white emission covered a wide range of driving voltage (10--22.5 V). The CIE coordinates were (x=0.341, y=0.334) at the driving voltage of 20 V, which was very close to the equi-energy point (x=0.333, y=0.333), and the corresponding luminance and external quantum efficiency were 4048 Cd/m^2 and 0.63% (4.05 Cd/A), respectively. Lastly, we also discussed the emitting mechanisms of the material and the devices.