超细全尾砂新型胶结充填料水化机理与性能

针对全尾砂含泥质量分数较高、粒度低的特点,根据充填体作用机理,实验制备出以水淬渣为主要胶凝组分的全尾砂胶结充填材料.利用X线(XRD)和扫描电镜(SEM)对该充填材料的水化产物和微观结构进行研究.研究结果表明:该新型充填料克服水泥全尾砂充填体强度低、充填砂浆黏度大以及成本高等技术难题,抗压强度R28=5.30 MPa是水泥胶结材料的4.7倍,满足矿山充填要求.所配制的充填料有良好的流动性,可以实现浆体自流输送.新型胶结材料的主导水化产物为钙矾石和C-S-H凝胶.大量钙矾石在水化初期形成,是原材料具有较高早期强度的主要因素;钙矶石微观形貌特征为网状或针棒状结构,随着养护时间的增加,水化产物不断发育长大,孔隙逐渐被填充,浆体结构更加致密,具有良好的力学特性.     

全尾砂充填材料组份含量优化的试验研究

对砂胶比 30∶1(固体浓度 82 % )的全尾砂膏体充填材料的无测限单轴抗压强度 (特别是细粒级尾砂含量和石灰含量的优化 )进行了试验研究 结果表明 :充填体中细粒级尾砂含量越大 ,需要更多的石灰才能达到 3d和 7d目标强度 ;石灰含量从 1.0 %增加到 7.0 % ,细粒级尾砂含量从 2 5%增加到 50 % ,充填体 2 8d目标强度都容易达到 表 1,图 1,参 3     

铁铝型高水速凝全尾砂充填材料的试验研究

铁铝型高水速凝全尾砂充填材料是一种以铁铝型高水速凝材料为胶凝材料的新型充填材料．介绍了铁铝型高水速凝材料的组成及特点,分析了全尾砂的物理化学性质,重点对铁铝型高水速凝全尾砂充填材料的配比及其物理化学性质进行了试验研究．结果表明,该材料是一种成本低,适于单管输送的优良充填材料,具有在矿山广泛推广应用的价值     

基于全尾砂充填体非线性本构模型的深井充填强度指标

目前矿山深井充填体强度指标是类比浅部充填经验来确定的,为改变这种不合理局面,根据某深井开采矿山全尾砂充填体单轴压缩实验的应力-应变关系曲线,建立了全尾砂充填体峰值应力前的非线性本构模型.结合全尾砂充填体与深部围岩耦合作用下能量损耗相近的原则,得出了全尾砂充填体抗压强度设计公式.实例研究结果表明:建立的全尾砂充填体峰值应力前的非线性本构模型与实验结果吻合;深部开采全尾砂充填体强度指标与围岩原岩应力、弹性模量以及充填体本身的力学性能有关,采用非线性本构模型确定的全尾砂充填体强度指标比采用线性本构模型确定的强度指标更精确.     

膏体充填用矿渣--钢渣基胶结剂协同固化Pb2+

利用矿渣-钢渣基胶凝材料(简称冶金渣胶凝材料)代替传统充填料中使用的水泥作为胶结剂,掺入含铅尾砂制成胶结充填料试样,通过流动度和抗压强度表征其工作性能,通过Pb2+浸出质量浓度表征其固化效果,通过X射线衍射、红外光谱、差示扫描量热法等手段分析其物相组成,并与P·I 42．5硅酸盐水泥作对比.在相同条件下,冶金渣胶凝材料试样的流动度平均高出水泥50 mm,且28 d强度符合一般矿山3．0 MPa的要求.冶金渣胶凝材料试样28 d龄期铅浸出质量浓度低于地下水环境质量标准Ⅲ类水0．05 mg·L-1的限值,而水泥为0．1 mg·L-1左右.冶金渣固化铅性能优于水泥的机理在于冶金渣胶凝材料水化生成更多钙矾石.此外,冶金渣胶凝材料水化产物可能存在类沸石相,更有利于吸附固化Pb2+.     

云南某铅锌矿全尾砂膏体室内实验研究

对云南某铅锌矿采用全尾砂膏体充填方案开展了室内实验研究,分析了全尾砂基本物理化学性质(粒级组成、化学成分),并进行了全尾砂自然沉降试验、坍落度试验、全尾砂试块单轴强度试验,获得了全尾砂及全尾砂胶结料的自然沉降特性、流动性能、析水性能及强度特性.试验结果显示:全尾砂自然沉降2~3 h后,重量浓度达到72%~76%,需要添加絮凝剂加快沉降;全尾砂胶结料的重量浓度为78%~79%时,坍落度为24~17 cm,基本无析水(1%~0.6%),充填料呈膏体状态,适合长距离输送;全尾砂膏体配合比在1∶4~1∶12时,28 d单轴抗压强度达到1~4 MPa.室内实验初步表明该矿山可以采用全尾砂膏体充填方案.     

某钼矿全尾砂膏体制备控制系统方案设计

全尾砂膏体充填系统为复杂系统,为制备合格的膏体,对全尾砂胶结料的浓度及灰砂比控制要求极其严格,为此,设计合理的控制系统是制备合格的全尾砂膏体的前提条件.不同的矿山,充填工艺不同,充填材料组成及性能差别也很大,应进行控制系统专题研究与设计.本文通过对黑龙江某钼矿全尾砂膏体充填系统工艺特点及全尾砂膏体性能参数的分析,设计了充填控制系统的目标和结构,即实现对灰砂比和充填料浆浓度的控制,以及采用DCS结构.然后进一步对控制系统方案进行了设计,包括采用双闭环比值控制方案,模糊PID控制算法等,以便为进一步设计工作提供参考.     

赤泥-矿渣-水泥基全尾砂胶结充填料的性能与微观结构

为了克服胶结充填成本高,解决尾矿、赤泥大量堆存而危害环境的问题,实验制备出以赤泥为主要胶凝组分的全尾砂胶结充填材料.该充填料试块在强度上优于用水泥制备的全尾砂胶结充填料试块,抗压强度达到R28=7 MPa,满足矿山充填要求.所配制的充填料有良好的流动性、保水性好、不泌水且成本大大低于水泥胶结充填材料.利用X射线衍射(XRD)和扫描电镜(SEM)对该充填材料的水化产物和微观结构进行了研究.结果表明,原料中的矿物相经水化反应后生成了大量的钙矾石和结晶程度低的复杂凝胶,它们交织在一起使体系结构致密,具有较好的力学性能.     

尾砂充填料浆流变性能模型与试验研究

以地下矿山尾砂充填料为研究对象,试验研究与理论分析相结合的方法,利用R/S+流变仪和岩石力学试验机对充填料浆的流变性能进行试验研究.引入Papanastasiou黏塑性流体模型来表征尾砂充填料浆的黏度和切应力变化过程.研究结果表明:该黏塑性流体模型预测的结果和试验结果相吻合,因此可用于理论分析计算;得到不同的压力增长指数下切应力-切变速率曲线;尾砂充填料浆的黏度和屈服应力随料浆质量分数的增加而增大;同一质量分数下,胶结尾砂的黏度和屈服应力比全尾砂大.通过对充填料浆流变性能的研究,为矿山充填设计提供了理论和实验依据.     

全尾砂胶结充填体的强度敏感性及破坏机制

以大冶铁矿全尾砂为原材料,采用水泥为胶结材料制作全尾砂胶结充填体,采用单因素五水平设计试验,研究了全尾砂胶结充填体强度与料浆中固相质量分数、灰砂配比及龄期之间的关系,并对敏感性进行了分析.胶结充填体强度随着料浆中固相质量分数的增加遵循指数函数增长,随灰砂配比的增加呈线性增长,随龄期增加遵循指数函数的增长,其中胶结充填体强度对龄期的敏感性最高,料浆中固相质量分数次之,灰砂配比最弱.胶结充填体抗压破坏试验结果显示,充填体的破坏经历了四个阶段,分别为微裂隙闭合阶段、线弹性阶段、微裂纹扩展阶段及裂纹贯通破坏阶段.     

Markedness and its Interpretation in Language Use

Language markedness is a common phenomenon in languages, and is reflected from hearing, vision and sense, i.e. the variation in the three aspects such as phonology, morphology and semantics. This paper focuses on the interpretation of markedness in language use following the three perspectives, i.e. pragmatic interpretation, psychological interpretation and cognitive interpretation, with an aim to define the function of markedness.     

低渗透非均质砂岩油藏启动压力梯度研究

理论推导与室内实验相结合,建立了低渗透非均质砂岩油藏启动压力梯度确定方法。首先借助油藏流场与电场相似的原理,推导了非均质砂岩油藏启动压力梯度计算公式。其次基于稳定流实验方法,建立了非均质砂岩油藏启动压力梯度测试方法。结果表明:低渗透非均质砂岩油藏的启动压力梯度确定遵循两个等效原则。平面非均质油藏的启动压力梯度等于各级渗透率段的启动压力梯度关于长度的加权平均;纵向非均质油藏的启动压力梯度等于各渗透率层的启动压力梯度关于渗透率与渗流面积乘积的加权平均。研究成果可用于有效指导低渗透非均质砂岩油藏的合理井距确定,促进该类油藏的高效开发。     

On Tragic Consciousness In The Works By Ernest Hemingway

As an American modern novelist who were famous in the literary world, Hemingway was not a person who always followed the trend but a sharp observer. At the same time, he was a tragedy maestro, he paid great attention on existence, fate and end-result. The dramatis personae's tragedy of his works was an extreme limit by all means tragedy on the meaning of fearless challenge that failed. The beauty of tragedy was not produced on the destruction of life, but now this kind of value was in the impact activity. They performed for the reader about the tragedy on challenging for the limit and the death.     

Achieving Unusual States of Matter Under High Pressure

正The periodicity of the elements and the non-reactivity of the inner-shell electrons are two related principles of chemistry,rooted in the atomic shell structure.Within compounds,Group I elements,for example,invariably assume the+1 oxidation state,and their chemical properties differ completely from those of the p-block elements.These general rules govern our understanding of chemical structures and reactions.Using first principles calcula-     

Exchange-Correlation and Electronic Excitation Energies from Pairing Matrix Fluctuations

We have developed an adiabatic connection to formulate the ground-state exchange-correlation energy in terms of pairing matrix linear fluctuations.This formulation of the exchange-correlation energy opens a new channel for density functional approximations based on the many-body perturbation theory.We illustrate the potential of such approaches with an approximation based on the particle-particle Random Phase Approximation(pp-RPA).This re-     

Density Functional Theory for the Response of Periodic Systems to Electric Fields Based on the Vector Potential Approach

正The electronic and nuclear(structural/vibrational)response of 1D-3D nanoscale systems to electric fields gives rise to a host of optical,mechanical,spectral,etc.properties that are of high theoretical and applied interest.Due to the computational difficulty of treating such large systems it is convenient to model them as infinite and periodic(at least,in first approximation).The fundamental theoretical/computational problem in doing so is that     

On the Thermodynamic Limit for Responses to Static Electromagnetic Fields

For molecular systems,the quantum-mechanical treatment of their responses to static electromagnetic fields usually employs a scalar-potential treatment of the electric field and a vector-potential treatment of the magnetic field.Although the potential for each field separately is associated with the choice of an(unphysical)origin,the precise choice of the origin for the electrostatic field has little consequences for the results.This is different for the     

An affordable accurate evaluation of the binding conformations predicted by molecular docking studies in bio-system

Franck-Condon factors bridge the gap between theoretical modeling and experimental observations for molecular electronic spectroscopy and electron transfer.Under the displaced harmonic oscillator approximation,multidimensional Franck-Condon factors are decomposed into a product of many one-dimensional(1D)Franck-Condon(FC)factors,and each 1D-FC factor is associated with one Huang-Rhys factor that determines the leading contribution of     

Call for Papers

<正>"The Journal of Shanghai Normal University:Mathematics"is published by Shanghai Normal University as regular issues of The Journal of Shanghai Normal University each year from 2014 in English.The editors-in-chief of the issues are professors Yuhao Cong and Maoan Han.The Journal of Shanghai Normal University was started in 1958 with     

Journal of Donghua University ( English Edition) Contents of Volume 31

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