Multiferroic and magnetoelectric properties of La0.1Ba0.9Fe12O19 ceramics

La0.1Ba0.9Fe12O19 powders with similar hexagonal crystal structure to Ba Fe12O19 have been successfully synthesized using polymer precursor method. The powders were suppressed into pellets, which were sintered into ceramics at 1,300 °C for 1 h. The structure and morphology of the ceramics have been determined by X-ray diffraction（XRD） and field emission scanning electron microscopy（FESEM）. Clear electric hysteresis loops upon different amplitude of external fields indicates that La0.1Ba0.9Fe12O19 is a kind of possible ferroelectric compound. The maximum remnant polarization of La0.1Ba0.9Fe12O19 ceramic is estimated to be ＊9.6 l C/cm2. The Fe O6 octahedron in its perovskite-like hexagonal unit cell as well as the shift of Fe3？off the center of octahedron are proposed to be the origin of electric polarization in La0.1Ba0.9Fe12O19. Simultaneous occurrence of large ferroelectricity and strong ferromagnetism has been observed in La0.1Ba0.9Fe12O19 ceramics. More interestingly, this compound demonstrates electronic polarization behavior being actuated by an applied magnetic field, indicating the existence of magnetoelectric（ME） coupling effect in the La0.1Ba0.9Fe12O19 ceramics. Our results may lead to new device applications such as magnetically recorded ferroelectric memory.     

Ferromagnetic and ferroelectric properties of Aurivillius phase Bi9Fe4.7Me0.3Ti3O27（Me 5 Fe,Co, Ni,Mn）

New Aurivillius phase Bi9Fe4.7Me0.3Ti3O27（Me = Fe, Co, Ni, Mn） oxides have been prepared using a citrate combustion method. X-ray diffraction on powders and high-resolution transmission electron microscopy investigation confirmed that the Bi9Fe4.7Me0.3Ti3O27 samples are with an eight-layer structure. Both ferromagnetic and ferroelectric investigations suggested that Co or Ni substitution could enhance their multiferroic properties,while Mn substitution depressed them. Among all the samples, Bi9Fe4.7Co0.3Ti3O27 sample exhibits the largest remnant polarization of Pr＊3.8 l C/cm2, and the largest remnant magnetization of Mr＊0.06 lB/f.u. with a Curie temperature about 764 K, while the Bi9Fe4.7Ni0.3Ti3O27 sample has the largest spontaneous magnetization（0.26 lB/f.u.）. The improved ferromagnetic properties ofboth Bi9Fe4.7Co0.3Ti3O27 and Bi9Fe4.7Ni0.3Ti3O27 can be ascribed to the spin canting of magnetic ion-based sublattices via the Dzyaloshinskii–Moriya interaction and also the magnetic ions exchanging interactions（Fe3–O–Co3or Fe3–O–Ni3）.     

Bi2O3—ZnO—Nb2O5三元系统中焦绿石结构及相变

文章研究了ＢｉＯ３－ＺｎＯ－Ｎｂ２Ｏ５（ＢＺＮ）三元系统中的焦绿石绘声绘色与相变。用Ｘ－射线衍射技术分析了研究样品的相结构及相组成，发现了两种焦绿石晶相及其复相结构。且随着Ｘ值的增加，晶体结构从焦绿石立方相向焦绿石单斜相逐渐过渡；焙烧温度的升高和保温时间的延长有利于焦绿石立方相的形成。     

Sialon陶瓷的常压烧结

在Si3N4,Al2O3,AlN和Y2O3混合料常压烧结过程中,由于过程反应生成SiO,CO,N2等气相物质和由于Si3N4原料在高温常压下分解压高,从而常压烧结致密化过程始终伴随着一个失重的塑致密化过程．为了解决这一问题,作者研究了填料成分、烧结温度、烧结时间等工艺条件对Sialon陶瓷常压烧结密度的影响,分析了烧结过程的物理化学机制和致密化机制．4种填料分别为Si3N4,Si3N4+SiO2,Si3N4+Al2O3+AlN和Si3N4+Al2O3+AlN+BN．被烧料典型配方为Si3N465%～70%,Al2O320%～25%,AlN10%,另加6%Y2O3．当填料成分为70%Si3N4+24%Al2O3+3%AlN+3%BN时,制得了相对密度达99%,抗弯强度达612.2MPa的常压烧结Sialon陶瓷．研究结果表明对于通式为Si6-ZAlZOZN8-Z的Sialon陶瓷,当Z=2时,其最佳烧结温度为1750℃,烧结时间为40min;Sialon的烧结过程是1个多因素控制的瞬时液相烧结过程．     

平板型多孔Al_2O_3陶瓷载体的研制

通过用固态粒子烧结法制备多孔氧化铝陶瓷 ,研究了玻璃相物质、有机成孔剂等对多孔陶瓷的孔隙率、孔径、透水率及硬度的影响 ,制得了具有较高孔隙率 (4 4%～ 6 0 % ) ,一定孔径分布及强度的多孔氧化铝陶瓷。     

Elastic anomalies near phase transitions of lead-free （Na,Bi）TiO3 and （Ba,Zr）TiO3 ferroelectric ceramics

We have investigated the temperature dependence of elastic modulus for various ferroelectric ceramics in the temperature range of 20–90°C.The Na0.5Bi0.5TiO3(NBT)ceramics has a phase transition at 200°C,thus exhibits minimal change in elastic modulus up to 90°C,while the elastic modulus of the BaZr0.07Ti0.93O3(BZT-7)shows 12.5%change at the phase transition temperature of70°C and that of the BaZr0.15Ti0.85O3(BZT-15)ceramics shows 34.6%change at the phase transition temperature of60°C.The variations of elastic modulus will affect the temperature stability of devices made by these lead-free ferroelectric ceramics.     

钨青铜陶瓷Sr_(0.5)Ba_(0.5)N_2O_6的制备结构与介电性能研究

采用固相反应法合成Sr0.5Ba0.5Nb2O6陶瓷,并对其结构、介电性能进行表征.研究结果表明,Sr0.5Ba0.5Nb2O6陶瓷为四方钨青铜结构单相,其在100℃附近存在一个明显的弥散介电峰,峰值随测试频率增加而减小,为典型的弛豫铁电相变.室温时,10kHz频率下,其介电常数约为450,介电损耗为0.121.     

Effects of temperature on hydrostatic pressure-induced FE-AFE phase transition in PbLa(Zr, Sn, Ti)O3 ceramics

Hydrostatic pressure-induced ferroelectricantiferroelectric (FE-AFE) phase transition and the pressure dependence of dielectric properties in La-doped Pb(Zr,Sn, Ti)O₃ ceramics were researched; the effects of temperature on hydrostatic pressure-induced FE-AFE phase transition and dielectric properties of the samples were studied. It was found that the temperature made the FE-AFE phase transition pressure decrease, and there existed the behavior of dielectric frequency dispersion and phase transition diffusion in the dielectric-pressure spectrum. These phenomena were very useful to enrich and develop the knowledge on the diffused phase transition behavior of polycomponent relaxor ferroelectric.     

准同型相界钛酸铋钠基铁电固溶体的电卡效应研究

利用铁电材料的电卡效应实现致冷成为当前国内外的研究热点之一.基于Maxwell关系,围绕着准同型相界组分的Bi0.5Na0.5Ti O3基无铅铁电固溶体,研究了其电卡效应,结果表明:该体系在5 k V/mm的外电场下,显示出优异的致冷特性,温度的变化量可达到1.15 K,相应的致冷强度可达0.23 K·mm/k V,在全新的固态致冷器件中显示出应用前景.     

La2 O3掺杂对BaBi4 Ti4 O15陶瓷压电性能的影响

采用传统固相烧结工艺制备了La掺杂量分别为0,0.1,0.25,0.5 mol的BaBi4Ti4O15 (BBT) 压电陶瓷.通过SEM和XRD分析了BBT陶瓷的表面形貌和物相结构;用介电常数测试仪(LCR)和准静态d33测试仪分别测量了陶瓷的介电常数,介电损耗和压电常数.结果表明:A位La掺杂并未改变BBT陶瓷的晶体结构; 虽然随着La掺杂量的增加(从0～0.5 mol),陶瓷的烧结温度有所提高(从1120℃提高到1150℃),然而它拓宽了BBT陶瓷的烧结温区(从20℃提高到50℃),并细化了陶瓷晶粒; La掺杂量为0.1时,BBLT陶瓷的压电常数比未掺杂的陶瓷增大了将近一倍(13pC/N),同时,与其它掺杂量的BBLT陶瓷相比,该掺杂量的BBLT陶瓷具有同频率下最大的介电常数及最小的介电损耗.     

Bi0.5Na0.5TiO3无铅压电陶瓷的结构有序化控制

以片状SrTiO3晶粒作为模板,使用模板晶粒生长法(TGG)控制制备[001]取向的有序化Bi0.5Na0.5TiO3压电陶瓷,同时研究了过量Bi2O3、烧结温度以及掺MnO对Bi0.5Na0.5TiO3有序度的影响.研究结果表明,过量Bi2O3的最佳掺入量为BNT粉料质量的1%;1190℃是合适的烧结温度,在1190℃下,BNT-1试样的有序度相对较高,有序度为88.2%;MnO的加入有效地提高了试样的有序度,并且降低了试样的烧结温度,同时也使得烧结温度范围变窄.在烧结温度为1170℃下,掺质量分数为0.3% MnO的BNT-1试样的有序度为91.1%.     

液相铌掺杂BaTiO3基PTCR陶瓷材料的研究

目的研究液相掺铌对BaTiO3系PTCR陶瓷材料电性能的影响。方法采用溶胶-凝胶一步法工艺和不同的降温速率。结果获得了室温电阻率2ρ5℃=28.93Ω.cm,升阻比Rmax/Rm in>1×106,阻温系数α30>15.00×10-2/℃,耐压强度Vbr>210V/mm,居里温度Tc=130℃的PTCR陶瓷材料。结论施主元素Nb以液相的形式添加分布更加均匀,材料的室温电阻率随施主元素Nb掺杂量增加呈U形变化,适量掺杂施主元素Nb可明显提高材料的PTCR特性,加快降温速率会明显削弱材料的电性能。     

纳米TiO_2微粉烧结过程中的相变与晶粒生长

分别制备无定型、锐钛矿和金红石三种形态的ＴｉＯ２纳米微粉,并对其烧结性能进行了较详细的研究,结果揭示：晶化和相变过程是晶粒生长的主要因素,硬团聚体的形状决定了烧结体的显微结构。     

Thermal shock resistance and crack growth behavior of Aurivillius phase Bi_4Ti_3O_(12)-based ferroelectric ceramics

A type of W/Cr co-doped Bi₄Ti₃O₁₂(ab. BTWC) ceramics were synthesized utilizing the traditional solid-state reaction process, and its thermal shock resistance(TSR) as well as the crack growth behavior was systematically investigated by water quenching technology. It can be found by the succeeded fractographic analysis that many edge thermal cracks began to appear in the samples subjected to thermal shock with ΔT=400°C. According to an integrated TSR model, the cr...     

Effects of BN content on the mechanical properties of nanocrystalline 3Y-TZP/Al2O3/BN dental ceramics

3Y-TZP/3wt％ Al2O3 powder was coated with varying amounts of BN using the urea and borate reaction sintering method, and then multiphase ceramics were prepared by hot pressing sintering. The micro-topography and the compositional analysis of synthesized ceramics were conducted through scanning electron microscopy, transmission electron microscopy and X-ray diffraction. A mechanical tester was used to analyze the Vickers hardness, fracture toughness, and bending strength of the synthesized ceramics. The results showed that the ceramic with a BN content of 12wt％ showed the best processability, but had diminished mechanical properties (such as fracture toughness and bending strength). The ceramic with a BN content of 9wt％ showed better processability than those with 3wt％ and 6wt％ BN. However, the fracture toughness was affected by the addition of 9wt％ BN, making this ceramic only usable as a base material for a three-unit fixed bridge. In con-trast, the ceramics with a BN content of 3wt％ or 6wt％ fulfilled the criteria for use in multi-unit restoration, but their low processability made them unsuitable for milling after sintering.     

烧结温度对多铁Bi_(0.6)La_(0.4)MnO_3陶瓷钙钛矿相的影响

采用溶胶-凝胶法制备多铁Bi0.6La0.4MnO3(BLMO)系列陶瓷样品,研究烧结温度对BLMO钙钛矿相稳定性的影响.X射线衍射(XRD)、傅里叶红外光谱(FT-IR)、差热-热重分析(TG-DTA)及扫描电子显微镜(SEM)等结果显示:当烧结温度升到533℃时,BLMO样品的钙钛矿相减弱,同时伴有Bi2Mn4O10中间相的出现,这是由BLMO相分解所致;当烧结温度升高到770℃,Bi2Mn4O10与Bi2O3反应生成稳定的BLMO钙钛矿相;进一步升高温度到925℃,样品仅有单一的BLMO钙钛矿相.研究表明:为了得到稳定的BLMO钙钛矿相,较高的烧结温度是必需的.     

YBa_2Cu_3O_（6＋x）高温超导体的临界温度与氧含量关系的逾渗理论分析

本文提出了一种局域氧有序的限制通渗模型，从理论上计算出了ＴＢａ２Ｃｕ３Ｏ６＋ｘ高温超导体临界温度Ｔｃ与氧含量之间的关系曲线，与实验曲线符合得非常好．并对Ｔｃ～ｘ实验曲线上出现的＂台阶＂现象进行了分析．随着ｘ的增加出现了两种结构相变：四方相到正交相、正交（Ⅰ）相到正交（Ⅱ）相的转变．这些转变有逾渗机制．     

矩阵分光光度（CPA）法同时测定痕量铜,铋,铁

以金属离子Ｍ,２－（３,５－二溴吡啶偶氮－２）－５－二乙氨基苯酚（３,５－ｄｉＢｒ－ＰＡＤＡＰ）和聚乙二醇辛基苯基醚（ＯＰ）的三元络合物为显色体系,用矩阵分光光度（ＣＰＡ）法研究了共存痕量铜、铁、铁３元素的测定,并对实际铅锭样品中的痕量杂质进行了测定,得到了较满意的结果。     

Bi1.7Pb0.3Sr2Ca2Cu3Ox超导体中热相变与纳米尺度结构块的研究

用变温X-射线衍射仪、扫描量热分析仪和热重分析仪对精心制作的Bi1.7Pb0.3Sr2Ca2Cu3Ox超导样品从室温到熔点温度进行了分析.实验发现样品在此温度范围有两个热量和重量反常.分析表明这两个反常与晶体结构中纳米尺度上两个不同的结构块--钙钛矿块和盐岩块有关,这对认识高温超导体的结构与性能关系有重要作用.     

Gd_2O_3的掺入对BaTiO_3陶瓷的形貌及相变等性能的影响

通过先制备钛酸钡 (BaTiO3 )的纳米粉 ,然后按一定质量比与Gd2 O3 混合 ,烧结成陶瓷。利用XRD、RAMAN技术研究了Gd2 O3 的掺入对BT陶瓷结构的影响。通过SEM、DSC技术分别观察了Gd2 O3 对BT陶瓷颗粒形貌、一级相变的影响。研究表明 :Gd2 O3 主要存在于晶界 ;由于Gd2 O3 引起的应力的作用 ,Gd2 O3 的对BT的振动模式和一级相变产生了一定的影响 ,影响最显著的是对BaTiO3 陶瓷微观颗粒的形状和大小