A New Route to Hyperbranched Macromolecules :Syntheses of Photosensitive Poly(aroylarylene)s via Regioselective Polycyclotrimerization of Bis(aroylacetylene)s

1Introduction Because of their unique molecular architecture, hyperbranched polymers (hb-Ps) are envisioned to exhibit novel properties, unachievable by their linear congeners, and to serve as advanced functional materials. Realization of the full potential of hb-Ps calls for the exploration of new, versatile methods for their syntheses.     

The Mechanism of Cumene Peroxidation Catalyzed by Cobalt（ Ⅱ ）-Chelated Copolymer

1 Introduction The functionalised polymers, especially for chelating polymer, have been employed to considerable effects in organic synthesis for several decades. The use of polymer groups as ligands permits the ligand surroundings to be varied and regulation of the catalytic properties of the complexes because of the flexibility of the polymer chains, their ability to adopt various conformations, and the possibility of creating various spatial distributions of metal centers immobilized on the…     

Women＇s Image of Nurturers in Anderson＇s Stories

Women＇s image of nurturers is successfully portrayed in Sherwood Anderson＇s stories.Anderson places hopes on women for two reasons：Women retain nurturing impulses which benefit men,and with their tenderness,understanding and love they can comfort the frustrated,defeated men;Women are less defeated by modern life and with their wisdom and ability to deal with the realities of life,they may help men out of their impotence and frustration.This paper gives a detailed analysis of the female characters＇image of nurturers in these stories.     

Solid Polymer Electrolytes Based on Cross-linkable Oligo （oxyethylene） -Branched Oligo （organophosphazenes）

Solid polymer electrolytes have attracted considerable interest because of their potential application in secondary high energy density lithium batteries. The poly（ethylene oxide）（PEO） has been widely studied as the classical polymer matrix for solid polymer electrolytes. However, the poor room temperature conductivity due to its crystalline is the principal problem to be overcomed. This has prompted many researchers to attempt to modify the properties of PEO.     

Effect of Chemical Structure on Molecular Properties of Hyperbranched Polycarbosilanes

1 Results In spite of the increased interest to the synthesis of hyperbranched polymers,there is a lack of studies of conformational properties of their macromolecules.Structural features of hyperbranched polymers are responsible for new properties that distinguish them from linear compounds and open unique possibilities for their applications.The knowledge of the "structure-properties" relationships is of fundamental value,it also can be helpful when developing new technologies and new materials. The goal of the work is to study hydrodynamic and molecular properties of hyperbranched polymers depending on their molar mass (MM) and on the linear chain length between the branching points of macromolecules.     

Stylistic Analysis of The Nightingale and the Rose

Oscar Wilde accomplished great success in conducting one of his works The Nightingale and the Rose This essay tries to analyze its article success in various stylistic levels, which is supposed to be helpful for teachers to conduct their classroom teaching of the material. Furthermore, this essay is bond to be very useful for those English majors by providing a guideline for their deeper and further appreciation of the article.     

Work toughening effect in Zr_（41）Ti_（14）Cu_（12.5）Ni_（10）Be_（22.5） bulk metallic glass

Work hardening is a well-known phenomenon occurring in crystalline metals during deformation,which has been widely used to increase the strength of metals although their ductility is usually reduced simultaneously. Here we report that the plastic strain of Zr41Ti14Cu12.5Ni10Be22.5 (at.%) bulk metallic glasses has been increased from 0.3% for the as-cast sample to 2.5%-8.0% for samples that have experienced pre-deformation under constrained conditions. The pre-deformed glassy alloys possess more free volume and abundant introduced shear bands,which are believed to promote the activation of shear bands in post-deformation and result in an increase in plasticity. The orientation of the pre-introduced shear bands relative to the loading direction will affect the deformation behavior of pre-deformed samples. The present results show that pre-deformation of this glassy alloy will result in work toughening. This work toughening effect can be removed by isothermal annealing at a sub-Tg (glass transition) temperature,which causes annihilation of free volume and healing of shear bands.     

Evaluation of the Websites and Software Used by English Teachers of Secondary School

As many English teachers of secondary school have raised awareness of exploring the use of ICT in EFL classes, their basic skills for using the technological tools have been developed. In the meantime, their abilities of utilizing resources form a variety of websites and software also need to be improved. Hence, Great importance has been attached to the evaluation of the websites and software packages.     

Structure Changes of Silk Fibroin（SF） by Blending with Poly（ε-caprolactone）（PCL）：Characterization of SF and PCL Blended Electrospinning Films

The mechanical properties and water solubility of electrospinning SF films limit their use as biomaterials. In order to develop a tissue engineering biomaterial with both satisfying biological properties and sufficient biomechanical properties,blended films composed of silk fibroin（ SF） and poly（ ε-caprolactone）（ PCL） were fabricated by electrospinning in this study. Scanning electron microscope（ SEM）, X-ray diffraction（ XRD）,thermal analysis,Fourier transform-infrared（ FT-IR）,Raman spectra,mechanical testing,and water solubility were used to characterize the morphological, structural and mechanical properties of the blended electrospinning films. Results showed that the diameter of the blended fiber was distributed between 600 and1000 nm,and the fiber diameter increased as the PCL content increased. There is no obvious phase separation due to the similarity and intermiscibility,as well as the interactions（ mainly hydrogen bonds）, between the two polymers. Meanwhile, the secondary structures of SF changed from random coils and Silk I to Silk II because of the interactions between SF and PCL. For this reason,the tensile strength and elongation at break of the electrospinning films improved significantly,and the water solubility decreased. In conclusion,the blended electrospinning films fabricated in this study showed satisfying mechanical properties and water insolubilities,and they may be promising biomaterials for applications in tissue engineering for blood vessels,nerve conduits,tendons,ligaments and other tissues.     

Three-dimensional recon- struction and analysis of structure characteristics on senile plaques of Alzheimer’s disease

Alzheimer‘s disease is a progressive neurodegenerative disorder characterized by the presence of senile plaques primarily composed of amyloid β in brain. Abnor-mal secretion and aggregation of amyloid β are the key events in pathogenesis of Alzheimer‘s disease. Reduction of amyloid β production and inhibition of amyloid β aggregation to form senile plaques are hopeful strategies for the treatment and prevention of Alzheimer‘s disease. In the present study, the silver and immunohistochemical staining methods were applied to discover senile plaques in the hippocampus of Alzheimer‘s disease patients, and then images were processed and three-dimensionally reconstructed by Matlab and AVS software. The structure characteristics of senile plaques were measured through correlation function calculation and fractal dimension by a computer-aided method. Diffuse plaque had no amyloid center, but classic plaque presented compact central core structure; two types of plaques were both of porous structure, but the sizes of their pores were significantly different. Furthermore, there was difference in fractal dimension value between the diffuse plaque and classic plaque in the two staining methods. The comparison of structure characteristics between two types of plaques indicated that they developed independently. Establishment of the methods for reconstructing the three-dimensional structure of senile plaque and analyzing their structure characteristics is helpful for further study on the aggregation mechanism of senile plaque.     

Impact of gamma radiation and salinity on growth and K^＋/Na^＋ balance in two populations of Medicago sativa （L.） cultivar Gabbs

The perennial Medicago sativa cv. Gabes is widely grown on saline soils in Tunisian oases. Morphological and physiological analyses of two populations （Mareth and Gannouch） were conducted in order to study the effect of salinity and gamma radiation （350 Gy） interaction on two populations of this species. It has been shown that the two irradiated populations of Medicago sativa are fairly tolerant to salt at growth phase compared to the non-irradiated. Exposure to gamma irradiation （350 Gy）, alone or in combination with salt stress, increased significantly （p 〈 0.001） shoot number, stem height and chlorophyll b pigment especially for the Gannouch population, while no change occurred for the Mareth population. The presence of salt to 9 g/1 affected significantly the root biomass and induced a reduction of shoot development of both control and irradiated alfalfa populations. For all treatments, plants of two populations remained able to produce and to allocate dry matter to the different organs. The survey of Na^＋/K^＋ ratio showed that the growth of the aerial organs of two non-irradiated populations was at least determined by a selectivity in favour of the K^＋ ions （r^2 = 0.97 and r^2 = 0.59 for Mareth and Gannouch non-irradiated populations, respectively）. However, the rather weak correlation detected for the irradiated populations, particularly for the irradiated Gannouch, seems to be the consequence of the effect of irradiation that improved potassium availability, essential element for growth and development. Results also showed that the two irradiated populations, especially the Mareth, accumulated Na^＋ ions in its photosynthetic organs. This accumulation was associated with an improvement of foliar water content at a level of salinity around 5 g/1. Such a mechanism reflects probably an inclusive behaviour of the plants and a good aptitude to use the dominant ions （Na^＋） for the osmotic adjustment. However, the non-irradiated populations are unable to adjust their internal os     

A New Model of Damped Vibration Absorber

A new model for an untuned damped vibration absorber is put forward here in accordance with some actual mechanical structures,and its performance or responses to various system parameters of the model are also fully discussed.Generally speaking,machines should be designed to avoid working at their resonant frequencies.For some modern machines their working speeds often exceed their first even second resonant frequency,so,it is the same important for them to pass through their resonant frequencies steadily during starting or shutting down.In the paper the max peaks of the main system vibration amplitude and force transmissibility,as well as their corresponding peak frequencies are emphasized.     

Analysis of Top Chinese Contractors’ Developmental Tracks and Evaluation of Their Strategic Selection of International Construction Markets

The past decade has witnessed a rapid development of the international construction market. This research aims to investigate top Chinese contractors＇ developmental tracks and evaluate their strategic selection of international construction markets over the period from 2001 to 2006, based on the modified Boston Consulting Group Matrix （BCG）. Results from 2001 to 2005 indicate that Asia and Africa, which were ＂question marks＂ markets for top Chinese contractors （abbreviated as TCCs） , have the most potential to become ＂stars＂ markets; other question marks markets such as the Middle East and Europe are found not to be of potential; ＂dogs＂ markets such as the U. S. , Canada and Latin America should be relinquished progressively unless there is renewed growth opportunity over the next two years. Compared to developmental tracks of top contractors from some advanced countries, TCCs＇ investment and development strategy in Africa seems to be sustainable and intensive ; TCCs＇ exit strategy for the Middle East appears deter- mined and swift, while their strategy in Asia seems to be lacking in persistence. Furthermore, the data of 2006 indicates that TCCs improve their performance in Asia and Africa, and Africa has become a ＂stars＂ market for TCCs. This research sheds important lights and insights into the prevailing process of internationalization of TCCs and provides a strategic direction for their selection of international construction market. What is more, this research is also valuable to other Chinese contractors who are seeking the opportunity to enter the international construction markets.     

Study on Dyeing of a Novel,Pro-environment Polylactic Acid （PLA） Fiber Yarn

Seventeen disperse dyes including anthraquinone, azo, methine, nitro, and quinoline dyes were applied to dye the Polylactic Acid （PLA） yarns at different conditions, and the dyebath exhaustion was determined. The result shows that C.I. disperse red 167, C.I. disperse orange 30, and C.I. disperse blue 284 have dye-uptakes greater than 80%. Therefore, they can be used as the three principal dyes for PLA yams. The experiment discovered that the dyes, because of their Monoazo and ester group contents, have a higher dye-uptake for the PLA fiber. The research on the optimization of dyeing techniques suggests that PLA yarn can obtain a high level of dyeing effectiveness at the following conditions： pH 4- 5, dyeing temperture 110℃ for 30- 40 min. Color fastness to perspiration, and waterwashing fastness increased 1 - 1.5 by the addition of the abstergent FB during the reduction clearing.     

Study on the behaviors of poly（p-phenylene benzobisoxazole） in coagulation

Poly（p-phenylene benzobisoxazole）（PBO） is a candidate of high performance materials for many applications. PBO materials＇ properties are considered to be closely related to their fabrication process, especially coagulation. In this paper, the coagulation effect on the chemical and microstructure of PBO was investigated with the help of a PBO model compound, 2, 2＇-（ 1,4-phenylene） bis （5-amino-6-benzoxazolole）. During coagulation, the hetero-cyclic ring of the PBO structure was experienced cleavage and even being broken down completely under some extreme conditions. Wide-angle X-ray diffraction （WAXD） analysis showed that different coagulants could cause the microstructure difference in PBO materials. In a slow coagulation process, PBO molecular chains aligned more orderly in the side-by-side direction （200）.     

Photosynthetic recovery of desiccated intertidal seaweeds after rehydration

Intertidal seaweeds experience periodical desiccation and rehydration to different extents due to the tidal cycles and their vertical distributions. Their photosynthetic recovery process during the rehydration may show different patterns among the seaweeds from different zonations or depths at intertidal zone. In this study 12 species of seaweeds collected from the upper, middle, lower and sublittoral zones were examined. The relationship of the photosynthetic recovery to vertical distribution was assessed by comparing their patterns of photosynthetic and respiratory performances after rehydration following desiccation. Both the photosynthesis and dark respiration declined during emersion, showing certain degrees of recovery after re-immersion into seawater for most species, but the extents were markedly different from one species to the other. The species from upper intertidal zone after being rehydrated for 1 hour, following 2 hours of desiccation, achieved 100% recovery of their initial physiological activity, while most of the lower or sublittoral species did not achieve full recovery. It is the ability to withstand desiccation stress (fast recovery during rehydration), but not that to avoid desiccation (water retaining ability) that determines the distribution of intertidal seaweeds. Such physiological behavior during rehydration after desiccation reflects the adaptive strategy of intertidal seaweeds against desiccation and their capability of primary production in the process of rehydration.     

Analysis of the Protein Electrophoresis Patterns of Curvularia Lunata in Maize and Immunological Detection of the Pathogenic Culture

Twelve isolates of Curvularia lunata and six related species from maize or other host plants are examined for the analysis of polyacrylamide gel electrophoresis (SDS-PAGE) patterns of their soluble proteins,Differences exist significantly among different species and the same species.There is a special protein band for Curvularia at relative mobility value 0.177(Rf 0.177) and a special protein band for C.lunata at Rf 0.225,Two kinds of rpimary antibodies to C.lunata are used to indirect ELISA and Avidin-Biotion-peroxidase Complex(ABC) immunoassay to evaluate their detecting sensitivity and specificity,The sensitivity of ABC immuno- assay is higher than indirect ELISA.APAbs to C.lunata is special to C.lunata.     

Medium optimization for enhanced production of cytosine-substituted mildiomycin analogue （MIL-C） by Streptoverticillium rimofaciens ZJU 5119

Cytosine-substituted mildiomycin analogue （MIL-C） was produced effectively by supplementing cytosine into the culture of Streptoverticillium rimofaciens. In order to improve the yield of MIL-C, statistically-based experimental designs were applied to optimize the fermentation medium for S. rimofaciens ZJU 5119. Fifteen culture conditions were examined for their significances on MIL-C production using Plackett-Burman design. The Plackett-Burrnan design and one-variable-at-a-time design indicated that glucose and rice meal as the complex carbon sources, and peanut cake meal and NH4NO3 as the complex nitrogen sources were beneficial for MIL-C production in S. rimofaciens ZJU 5119. The results of further central composition design （CCD） showed that the optimal concentration of glucose, rice meal and peanut cake meal were 18.7 g/L, 64.8 g/L and 65.1 g/L, respectively. By using this optimal fermentation medium, the MIL-C concentration was increased up to 1336.5 mg/L, an approximate 3.8-fold improvement over the previous concentration （350.0 mg/L） with un-optimized medium. This work will be very helpful to the large-scale production of MIL-C in the future.     

The specific contribution of object’s origin on artifacts categorization

Gelman and Bloom found that adults and children＇s object naming was sensitive to how an object was created （man-made or not）, but they did not reveal on which specific level of conceptual system this effect was. Using a free-naming task and a force-choice task, two experiments were conducted to test a hypothesis that this effect was specifically on domain level （＂artifact/non-artifact＂ distinction）, in Experiment 1, participants were asked to name shortly-depicted objects, rate their confidence, and report their reasons for each naming response. Resuits showed that most of the naming responses in ＂man-made＂ condition were in artifact domain, and most in ＂natural＂ condition were in non-artifact domain, although in both conditions names were very divergent on basic level. In Experiment 2, another group of participants were asked to choose one from two names （one in artifact domain and the other in non-artifact domain） to match the same shortly-depicted objects presented in the first experiment. Results of Experiment 1 on domain level were replicated in Experiment 2. These convergent findings supported the hypothesis that the effect of object＇s origin is specifically on domain level of conceptual system of objects. Reasons explicitly reported for naming responses in Experiment 1 suggested that participants might automatically infer objects＇ functions in ＂man-made＂ condition but not in ＂natural＂ condition. Here the function-based hypothesis of artifacts classification is discussed.     

Calculation of Random Response Spectral Moments of Elastic-viscoelastic Combined Systems

In random vibration analysis, the importance of spectral moments of the response stems from their relevance to system performance prediction. Usually, spectral moments are obtained by the frequency domain method. In present paper, the random response spectral moments of elastic-viscoelastic combined systems are calculated by complex modal analysis in the time domain. The analytical form results are obtained for random response spectral moments of an elastic-viscoelastic combined system to a stationary white noise excitation. The method presented is simple and easy to apply. It is hoped that this study would pave a way for the analysis of reliability of elastic-viscoelastic combined systems subjected to random excitations.