有机质谱同位素峰丰度分布的BASIC计算程序

本文报导了一个能在具有64K内存的任何微型计算机上运行并计算任何有机化合物质谱同位素峰丰度分布的计算机程序.程序是用BASIC语言编写的.利用本程序,可将小型计算器上需要花几个小时才能算完的工作在1分钟内给出结果.     

计算机据低分辨质谱数据推算分子式的方法研究

本文探讨了利用计算机解析质谱的方法,着重介绍了依据低分辨质谱数据推算有机化合物分子式的算法.     

有机质谱中应用计算机推算分子式的方法

以笔者设计的计算机程序流程，由高分辨质谱和低分辨质谱数据可推算有机化合物的分子式     

氮同位素丰度及其比值的准确测定

本文提出一种在氮的质谱分析时鉴定质谱峰被污染的方法,即质谱峰平衡法。它是利用质谱的峰值来鉴定它们是否被污染和计算出其被污染的量。从而可以进行必要的和适当的校正。而且选用适当的公式可以计算出正确的同位素丰度、同位素比和德耳塔值。 从产生质谱峰的几率推导出三个鉴定质谱峰有无污染的基本公式。给出八个计算丰度公式和两个计算同位素比公式。 本文最后用实验结果证实各式的正确性。     

感光胶片用成色剂的质谱研究

本文报告了几个典型彩色胶片用成色剂的电子轰击质谱和快原子轰击质谱的实验结果；谱图包括各个被分析成色剂样品的分子离子峰，代表各类成色剂特征结构的质谱碎片峰，官能团峰，同位素峰簇及各质谱峰的相对丰度。通过谱图解析找出了成色剂化合物的质谱碎裂规律；归纳出了利用质谱分析成色剂结构的方法。     

任意分子同位素丰度的计算及其在飞行时间质谱归属中的应用

提出了一个计算任意 分子的同位素丰度的算法，并用ＱＢＡＳＩＣ语言编写了计算程序。根据飞行时间质谱的飞行时间方程和单一质量离子峰的峰型，以及计算得到的同位素丰度，建立了一个基于比较实验和计算的同位素峰型和位置。     

残基法判定有机物

介绍了残基法在判定有机化合物的分子式中的一些应用。     

基于泊松分布模型的蛋白质串联质谱鉴定算法研究

数据库搜索方法被广泛应用于蛋白质串联质谱的鉴定之中,该方法主要包括4部分:去同位素峰、选取有效峰、产生理论图谱、对理论图谱与实验图谱进行相似度打分.其中打分函数是数据库搜索方法的核心,在此基础上探究了一种基于泊松分布模型下的蛋白质串联质谱鉴定算法,并合理的融入了峰强度信息.为了验证该算法的有效性及可靠性,将该算法搜索结果与主流鉴定商业软件Mascot和Sequest在FDR为1%的条件下进行比较,基于泊松分布模型的蛋白质串联质谱鉴定算法具有更高的鉴定量和鲁棒性.     

2-烷基噻吩和2,5-(二烷基)噻吩质谱的特征离子系列相关谱研究

一、前言质谱是现代有机结构分析中常用的分析方法。运用有机化合物的质谱确定它的结构,除了必须熟练掌握各类有机化合物的断裂方式外,通常还要借助于标准谱图进行对照。但是,绝大多数化合物目前无标准谱图可查,收集有机化合物质谱数量最多的《EPAINIH     

绿茶挥发性成分的 GC-MS 分析

利用程序升温毛细管气相色谱－质谱联用方法对一种绿茶的挥发成分进行分析鉴定，共分离出６０个组分，用峰面积归一化法算出其相对含量，用谱图检索确认出５２个组分，占总挥发成分的９８％。     

Markedness and its Interpretation in Language Use

Language markedness is a common phenomenon in languages, and is reflected from hearing, vision and sense, i.e. the variation in the three aspects such as phonology, morphology and semantics. This paper focuses on the interpretation of markedness in language use following the three perspectives, i.e. pragmatic interpretation, psychological interpretation and cognitive interpretation, with an aim to define the function of markedness.     

Features of Women's language

Language is a means of verbal communication. People use language to communicate with each other. In the society, no two speakers are exactly alike in the way of speaking. Some differences are due to age, gender, statue and personality. Above all, gender is one of the obvious reasons. The writer of this paper tries to describe the features of women＇s language from these perspectives： pronunciation, intonation, diction, subjects, grammar and discourse. From the discussion of the features of women＇s language, more attention should be paid to language use in social context. What＇s more, the linguistic phenomena in a speaking community can be understood more thoroughly.     

An Analysis of Catherine＇s Character——Wuthering Heights

Wuthering Heights, Emily Bronte＇s only novel, was published in December of 1847 under the pseudonym Ellis Bell. The book did not gain immediate success, but it is now thought one of the finest novels in the English language. Catherine is the key character of this masterpiece, because everybody and everything center on her though she had a short life. We can understand this masterpiece better if we know Catherine well.     

Lower Paleozoic oil relationships within Williston Basin, Canada

The Williston Basin is a significant petroleum province, containing oil production zones that include the Middle Cambrian to Lower Ordovician, Upper Ordovician, Middle Devonian, Upper Devonian and Mississippian and within the Jurassic and Cretaceous. The oils of the Williston Basin exhibit a wide range of geochemical characteristics defined as "oil families", although the geochemical signature of the Cambrian Deadwood Formation and Lower Ordovician Winnipeg reservoired oils does not match any "oil family". Despite their close stratigraphic proximity, it is evident that the oils of the Lower Palaeozoic within the Williston Basin are distinct. This suggests the presence of a new "oil family" within the Williston Basin. Diagnostic geochemical signatures occur in the gasoline range chromatograms, within saturate fraction gas chromatograms and biomarker fingerprints. However, some of the established criteria and cross-plots that are currently used to segregate oils into distinct genetic families within the basin do not always meet with success, particularly when applied to the Lower Palaeozoic oils of the Deadwood and Winnipeg Formation.     

低渗透非均质砂岩油藏启动压力梯度研究

理论推导与室内实验相结合,建立了低渗透非均质砂岩油藏启动压力梯度确定方法。首先借助油藏流场与电场相似的原理,推导了非均质砂岩油藏启动压力梯度计算公式。其次基于稳定流实验方法,建立了非均质砂岩油藏启动压力梯度测试方法。结果表明:低渗透非均质砂岩油藏的启动压力梯度确定遵循两个等效原则。平面非均质油藏的启动压力梯度等于各级渗透率段的启动压力梯度关于长度的加权平均;纵向非均质油藏的启动压力梯度等于各渗透率层的启动压力梯度关于渗透率与渗流面积乘积的加权平均。研究成果可用于有效指导低渗透非均质砂岩油藏的合理井距确定,促进该类油藏的高效开发。     

On Tragic Consciousness In The Works By Ernest Hemingway

As an American modern novelist who were famous in the literary world, Hemingway was not a person who always followed the trend but a sharp observer. At the same time, he was a tragedy maestro, he paid great attention on existence, fate and end-result. The dramatis personae's tragedy of his works was an extreme limit by all means tragedy on the meaning of fearless challenge that failed. The beauty of tragedy was not produced on the destruction of life, but now this kind of value was in the impact activity. They performed for the reader about the tragedy on challenging for the limit and the death.     

Design and analysis of generic LBS application developing platform

Location based services is promising due to its novel working style and contents.A software platform is proposed to provide application programs of typical location based services and support new applications developing efficiently. The analysis shows that this scheme is easy implemented, low cost and adapt to all kinds of mobile nework system.     

橡胶颗粒沥青混合料低温抗裂性试验研究

以AC-13级配为基础,将橡胶颗粒代替部分集料掺入混合料中,以低温弯曲试验为评价方法对不同橡胶颗粒掺量下沥青混合料的低温抗裂性进行研究,并引入应变能密度值对混合料的低温抗裂性进行综合评价.试验结果表明:橡胶颗粒沥青混合料试件的破坏微应变均超过2 300,满足冬寒区的技术指标;无论是否掺加橡胶颗粒,随着温度的下降,沥青混合料破坏时的最大弯拉强度增大,弯拉应变降低,劲度模量增大;弯曲应变能密度在胶粒掺量为1%左右时具有较大的弯曲应变能密度值,此时橡胶颗粒沥青混合料具有较好的低温抗裂性.     

Achieving Unusual States of Matter Under High Pressure

正The periodicity of the elements and the non-reactivity of the inner-shell electrons are two related principles of chemistry,rooted in the atomic shell structure.Within compounds,Group I elements,for example,invariably assume the+1 oxidation state,and their chemical properties differ completely from those of the p-block elements.These general rules govern our understanding of chemical structures and reactions.Using first principles calcula-     

Exchange-Correlation and Electronic Excitation Energies from Pairing Matrix Fluctuations

We have developed an adiabatic connection to formulate the ground-state exchange-correlation energy in terms of pairing matrix linear fluctuations.This formulation of the exchange-correlation energy opens a new channel for density functional approximations based on the many-body perturbation theory.We illustrate the potential of such approaches with an approximation based on the particle-particle Random Phase Approximation(pp-RPA).This re-