噻唑杂环偶氮分散染料的溶剂效应

测试了两个噻唑杂环偶氮分散染料在十五种溶剂中的电子光谱,发现化合物的可见吸收光谱吸收带的(?)_(max)~(UV)不仅与溶剂的折射率n有关,而且与溶剂的介电常数ε有关,即与溶剂的n~2-1/2n~2+1、(ε-n~2)(2ε+n~2)/ε(n+2)~2和ε-1/ε+2-n~2-1/n~2+2存在着良好的线性关系。     

溶剂多参数分类方法的应用探讨

按照溶剂多参数分类方法,通过不同类型溶剂中进行的诸如互变异构、顺反异构、光化学等有机反应的溶剂效应及紫外光谱吸收峰的溶剂效应的关系,用溶剂参数ET(30)、ε、n2D0进行了表征,结果表明具有很好的相关性.     

具有桥链七甲川菁染料的合成及其电子吸收光谱

合成了三个具有桥链的七甲川菁染料。研究染料结构对最大吸收波长的影响,并测定了染料在18种溶剂中的吸收光谱,发现染料的V_(max)~(ab)分别与溶剂的n~2-1/2n~2+1、(ε-n~2)(2ε+n~2)/ε(n+2)~2和((ε-1)/(ε+2))-((n~2-1)/(n~2+2))存在着良好的钱性关系。     

线性回归中高杠杆点和强影响点的一种诊断方法

1 Andrews—pregibon诊断量的密度函数考虑线性回归模型Y=Xβ ε (1) 其中X为nx(p 1)阶列满秩已知设计矩阵,β为p 1维未知参数向量,Y为n维观测向量,ε=(ε_1,ε_2,….,ε_n)~τ为n维随机误差向量。     

普朗克黑体辐射公式的由来 (摘要)——并由它导出维恩位移定律,近似计算b的数值准确到四位有效数字

1900年12月4日德国物理学家普朗克发表论文,提出能量子假设,称ε_o=hv为能量子。他在这一假设的基础上,又运用经典统计,得出普朗克黑体辐射公式。据经典统计,在相空间dτ内,振子能量为E_n=nε_o的几率与e~(-nεo'KT)成正比,所以在温度为TK时,一个线性谐振子的平均能量是: ■=sum from n=0 to ∞ E_ne~(-nε_0/KT)/sum from n=0 to ∞ e~(-nε_0/KT)=sum from n=0 to ∞ nhve~(-ahv/KT)/sum from n=0 to ∞ e~(-nhv/KT) (sum from n=0 to ∞ ne~(-nx)/sum from n=0 to ∞ e~(-nx))hv     

一类多元线性模型的一致最小方差无偏估计

本文讨论一类多元线性模型 :y=(S T′) β+e,E(e) =0 ,e=(ε′(1) ,… ,ε′(n) )′,E(ε(i) ε′(n) ) =Φ 0 ,E(ε(i) ε′(i) ε(i) ε′(i) ) =K,i=1 ,2 ,… ,n.当 y准正态分布时 ,在一定意义下得到Φ的 L S估计Φ1,以及 tr(DΦ1)为 tr(DΦ ) (D=D′)的一致对 (Φ ,k)的最小方差无偏估计 (UMVUE)的若干充要条件 .     

关于一类二项式和的整除性质的推广

Mare Chamberland和Karl Dilcher[Divisibility properties of a class of binomial sums, J. Number Theory, 120(2006)pp.349-371]研究了一类二项式和uεa,b(n)并给出了一些有趣的性质,其中uεa,b(n)=∑nk=0(-1)εk(nk)a(2nk)b,对a,b,n∈N和ε∈{0,1}.最后,他们提出了uεa,b(n)的一种推广,即uεa,b,c(n)=∑nk=0(-1)εk(nk)a(2nk)b(3nk)c,其中a,b,c,n∈N,ε∈{0,1},期望uεa,b,c(n)具有与uεa,b(n)相似的性质,但并未给出具体的性质及证明.在本文中,我们给出并证明了uεa,b,c(n)的与Wolstenholme定理有关的这部分性质.     

多维正态随机变量的几个性质

设 (X1 ,… ,Xn)和 (ε1 ,… ,εn)分别是n维正态和n维标准正态随机变量 ,研究了(X1 ,… ,Xn)与 (ε1 ,… ,εn)以及E(X1 X2 ,… ,Xn)与 (X2 ,… ,Xn)的关系 ,并且讨论把EΠni=1Xi表示成EXiXj 的问题     

一种两亲性酞菁的合成及其光谱研究

用硅胶负载法合成了一种两亲性不对称取代酞菁三-α-(2,2,4-三甲基-3-戊氧基)-β-(4’-羧基苯氧基)酞菁铜.紫外可见吸收光谱的研究表明,与脂溶性的四-α-(2,2,4-三甲基-3-戊氧基)酞菁铜相比,该两亲性酞菁的最大吸收波长和吸收带的形状受溶剂的影响更大,在水中其聚集态可以被阳离子表面活性剂解聚,而受阴离子表面活性剂的影响不大.     

因子链上幂矩阵行列式的整除性

设S＝{x1,……,xn}是由n个不同正整数组成的集合,ε∈Z ,如果n阶矩阵的第i行j列元素是S中元xi,xj的最大公因数(xi,xj)的ε次幂(xi,xj)ε,就称这个矩阵是定义在S上的最大公因数的ε次幂矩阵,简记为(S)εn;如果n阶矩阵的第i行j列元素是S中元xi,xj的最小公因倍数[xi,xj]的ε次幂[xi,xj]ε,就称这个矩阵是定义在S上的最小公倍数的ε次幂矩阵,简记[S]εn为.如果S中元素满足1≤i≤j≤n有xi|xj,就称S是一个因子链.研究了对ε∈Z ,定义在任意因子链S上的幂矩阵(S)εn和[S]εn的行列式det(S)εn与det[S]εn间的整除性.     

Markedness and its Interpretation in Language Use

Language markedness is a common phenomenon in languages, and is reflected from hearing, vision and sense, i.e. the variation in the three aspects such as phonology, morphology and semantics. This paper focuses on the interpretation of markedness in language use following the three perspectives, i.e. pragmatic interpretation, psychological interpretation and cognitive interpretation, with an aim to define the function of markedness.     

Features of Women's language

Language is a means of verbal communication. People use language to communicate with each other. In the society, no two speakers are exactly alike in the way of speaking. Some differences are due to age, gender, statue and personality. Above all, gender is one of the obvious reasons. The writer of this paper tries to describe the features of women＇s language from these perspectives： pronunciation, intonation, diction, subjects, grammar and discourse. From the discussion of the features of women＇s language, more attention should be paid to language use in social context. What＇s more, the linguistic phenomena in a speaking community can be understood more thoroughly.     

An Analysis of Catherine＇s Character——Wuthering Heights

Wuthering Heights, Emily Bronte＇s only novel, was published in December of 1847 under the pseudonym Ellis Bell. The book did not gain immediate success, but it is now thought one of the finest novels in the English language. Catherine is the key character of this masterpiece, because everybody and everything center on her though she had a short life. We can understand this masterpiece better if we know Catherine well.     

Lower Paleozoic oil relationships within Williston Basin, Canada

The Williston Basin is a significant petroleum province, containing oil production zones that include the Middle Cambrian to Lower Ordovician, Upper Ordovician, Middle Devonian, Upper Devonian and Mississippian and within the Jurassic and Cretaceous. The oils of the Williston Basin exhibit a wide range of geochemical characteristics defined as "oil families", although the geochemical signature of the Cambrian Deadwood Formation and Lower Ordovician Winnipeg reservoired oils does not match any "oil family". Despite their close stratigraphic proximity, it is evident that the oils of the Lower Palaeozoic within the Williston Basin are distinct. This suggests the presence of a new "oil family" within the Williston Basin. Diagnostic geochemical signatures occur in the gasoline range chromatograms, within saturate fraction gas chromatograms and biomarker fingerprints. However, some of the established criteria and cross-plots that are currently used to segregate oils into distinct genetic families within the basin do not always meet with success, particularly when applied to the Lower Palaeozoic oils of the Deadwood and Winnipeg Formation.     

低渗透非均质砂岩油藏启动压力梯度研究

理论推导与室内实验相结合,建立了低渗透非均质砂岩油藏启动压力梯度确定方法。首先借助油藏流场与电场相似的原理,推导了非均质砂岩油藏启动压力梯度计算公式。其次基于稳定流实验方法,建立了非均质砂岩油藏启动压力梯度测试方法。结果表明:低渗透非均质砂岩油藏的启动压力梯度确定遵循两个等效原则。平面非均质油藏的启动压力梯度等于各级渗透率段的启动压力梯度关于长度的加权平均;纵向非均质油藏的启动压力梯度等于各渗透率层的启动压力梯度关于渗透率与渗流面积乘积的加权平均。研究成果可用于有效指导低渗透非均质砂岩油藏的合理井距确定,促进该类油藏的高效开发。     

On Tragic Consciousness In The Works By Ernest Hemingway

As an American modern novelist who were famous in the literary world, Hemingway was not a person who always followed the trend but a sharp observer. At the same time, he was a tragedy maestro, he paid great attention on existence, fate and end-result. The dramatis personae's tragedy of his works was an extreme limit by all means tragedy on the meaning of fearless challenge that failed. The beauty of tragedy was not produced on the destruction of life, but now this kind of value was in the impact activity. They performed for the reader about the tragedy on challenging for the limit and the death.     

Achieving Unusual States of Matter Under High Pressure

正The periodicity of the elements and the non-reactivity of the inner-shell electrons are two related principles of chemistry,rooted in the atomic shell structure.Within compounds,Group I elements,for example,invariably assume the+1 oxidation state,and their chemical properties differ completely from those of the p-block elements.These general rules govern our understanding of chemical structures and reactions.Using first principles calcula-     

Exchange-Correlation and Electronic Excitation Energies from Pairing Matrix Fluctuations

We have developed an adiabatic connection to formulate the ground-state exchange-correlation energy in terms of pairing matrix linear fluctuations.This formulation of the exchange-correlation energy opens a new channel for density functional approximations based on the many-body perturbation theory.We illustrate the potential of such approaches with an approximation based on the particle-particle Random Phase Approximation(pp-RPA).This re-     

Density Functional Theory for the Response of Periodic Systems to Electric Fields Based on the Vector Potential Approach

正The electronic and nuclear(structural/vibrational)response of 1D-3D nanoscale systems to electric fields gives rise to a host of optical,mechanical,spectral,etc.properties that are of high theoretical and applied interest.Due to the computational difficulty of treating such large systems it is convenient to model them as infinite and periodic(at least,in first approximation).The fundamental theoretical/computational problem in doing so is that     

On the Thermodynamic Limit for Responses to Static Electromagnetic Fields

For molecular systems,the quantum-mechanical treatment of their responses to static electromagnetic fields usually employs a scalar-potential treatment of the electric field and a vector-potential treatment of the magnetic field.Although the potential for each field separately is associated with the choice of an(unphysical)origin,the precise choice of the origin for the electrostatic field has little consequences for the results.This is different for the