A Revolution that never happened

If we define scientific revolutions as changes of scientists' ontologies, types of causal explanation, and paradigmatic types of methods and instruments, Antoine-Laurent Lavoisier's contribution to chemistry did not amount to a scientific revolution. Contrary to the received view that Lavoisier initiated a “chemical revolution,” which is accepted by Chang and Kusch, I argue that Lavoisier shared with the phlogistonists their “flat ontology” of chemical substance, established decades before the 1770s, their types of explaining chemical transformation, and their quantitative methods. Based on my historical reconstruction, I criticize Chang's argument that the late eighteenth-century phlogistic systems and Lavoisier's system belonged to two different theoretical traditions. As a consequence, I also question Chang's argument that the acceptance of Lavoisier's system can be explained in terms of dominance of “compositionism” over “principlism.”     

Lavoisier and his Last Printed Work: The Mémoires de physique et de chimie (1805)

On the basis of a significant number of unpublished documents, here published for the first time, the article reconstructs the historical and scientific origins of Lavoisier's Mémoires de physique et de chimie. Because of the paucity of primary sources available so far, this work has previously received little attention and its 'publication' is commonly attributed to Madame Lavoisier's effort to revive the memory of her husband. In contrast with this image, this article suggests that Madame Lavoisier had only a subsidiary role and that Armand Séguin's contribution to both the editing and the scientific organization of the Mémoires needs a historical reassessment. Lavoisier's collaboration with Séguin, dating from 1792, resulted in a work the aim of which was far more ambitious than that of collecting already published memoirs. Furthermore, it is argued that the contents of the first volume of the Mémoires indicate an important evolution in Lavoisier's chemical theory.     

Failed utopias and practical chemistry: the Priestleys,the Du Ponts,and the transmission of transatlantic science, 1770–1820

ABSTRACT

Eighteenth-century events, replete with Dickensian dualities, brought two Enlightenment families to America. Pierre-Samuel du Pont and Joseph Priestley contemplated relocating their families decades before immigrating. After arriving, they discovered deficiencies in education and chemistry. Their experiences were indicative of the challenges in transmitting transatlantic chemistry. The Priestleys were primed to found an American chemical legacy. Science connected Priestley to British manufacturers, Continental chemists, and American statesmen. Priestley's marriage into the Wilkinson ironmaster dynasty, and Lunar Society membership, helped his sons apprentice, and befriend manufacturer-chemist Thomas Cooper. However, ideological persecution forced them from England. Priestley's plans for his sons to inherit Wilkinson's ironworks evaporated; in America, efforts to establish manufactories, colonies, farms, and a college miscarried. Cooper taught college chemistry, but his materialism provoked dismissals. The Du Ponts were unlikely founders of an industrial-chemistry empire. Du Pont's philosophy promulgated that agriculture, not industry, produced wealth. Eleuthère-Irénée apprenticed in France's gunpowder administration, however, plans for his succession died and director Antoine Lavoisier, a family friend, was executed. E.-I. and Du Pont's arrest precipitated relocation to America. Du Pont's utopian colony and schemes proved unrealistic. Nevertheless, E.-I.'s gunpowder manufactory—utilizing transatlantic contacts and privileged knowledge of advanced French chemistry—succeeded through practical application.     

Hypothesis and experiment in the early development of Kekulé's Benzene theory

This article attempts a contextual study of the origin and early development of August Kekulé's theory of aromatic compounds. The terminus a quo is essentially August Hofmann's coining of the modern chemical denotation of ‘aromatic’ in 1855; the terminus ad quem is the first full codification of Kekulé's theory in the sixth fascicle of his Lehrbuch der organischen Chemie, published in the summer of 1866. Kekulé's theory is viewed in context with the earlier and concurrent experimental work of such chemists as Hermann Kolbe, Friedrich Beilstein, Rudolph Fittig, and Hugo Müller. The reception of the theory is briefly examined. Attention is paid to the role of Kekulé's molecular models and of his celebrated dream anecdote of the snake that seizes its own tail. The episode is used as a case study for the continuity of scientific progress, and to illustrate the close reciprocal interactions of hypothesis and experiment in the evolution of a scientific theory.     

Spheres of Influence: Illustration,Notation, and John Dalton's Conceptual Toolbox, 1803–1835

In the early years of the nineteenth century, the English chemist John Dalton (1766–1844) developed his atomic theory, a set of theoretical commitments describing the nature of atoms and the rules guiding their interactions and combinations. In this paper, I examine a set of conceptual and illustrative tools used by Dalton in developing his theory as well as in presenting it to the public in printed form as well as in his many public lectures. These tools—the concept of ‘atmosphere’, the pile of shot analogy, and Dalton's system of chemical notation—served not just to guide Dalton's own thinking and to make his theories clear to his various audiences, but also to bind these theories together into a coherent system, presented in its definitive form in the three volumes of A New System of Chemical Philosophy (1808, 1810, and 1827). Despite these links, Dalton's contemporaries tended to pick and choose which of his theories to accept; his system of notation failed to be adopted in part because it embodied the whole of his system indivisibly.     

Pauling's Defence of Bent-Equivalent Bonds: A View of Evolving Explanatory Demands in Modern Chemistry

Linus Pauling played a key role in creating valence-bond theory, one of two competing theories of the chemical bond that appeared in the first half of the 20th century. While the chemical community preferred his theory over molecular-orbital theory for a number of years, valence-bond theory began to fall into disuse during the 1950s. This shift in the chemical community's perception of Pauling's theory motivated Pauling to defend the theory, and he did so in a peculiar way. Rather than publishing a defence of the full theory in leading journals of the day, Pauling published a defence of a particular model of the double bond predicted by the theory in a revised edition of his famous textbook, The Nature of the Chemical Bond. This paper explores that peculiar choice by considering both the circumstances that brought about the defence and the mathematical apparatus Pauling employed, using new discoveries from the Ava Helen and Linus Pauling Papers archive.     

The analytical concept of a chemical element in the work of Bergman and Scheele

In Thomas Thomson's System of chemistry of 1802 Bergman and Scheele are actually considered as creators of the analytical concept of an element. With regard to this, a detailed investigation of the work of Bergman and Scheele shows that Thomson's statement contains mistakes as well as inadmissable simplifications and generalizations. It is correct, however, that Bergman in 1774–1777 specifically anticipated in essential aspects the analytical element concept proposed by Lavoisier in 1787–1789.     

The Transformation of Aristotle's Mechanical Questions: A Bridge Between the Italian Renaissance Architects and Galileo's First New Science

The reception process of Aristotle's Mechanical Questions during the early modern period began with the publication of the corpus aristotelicum between 1495 and 1498. Between 1581 and 1627, two of the thirty-five arguments discussed in the text, namely Question XIV concerning the resistance to fracture and Question XVI concerning the deformation of objects such as timbers, became central to the work of the commentators. The commentaries of Bernardino Baldi (1581–1582), Giovanni de Benedetti (1585), Giuseppe Biancani (1615) and Giovanni di Guevara (1627) gradually approached the doctrine of proportions of the Renaissance architects, some aspects of which deal with the strength of materials according to the Vitruvian conception of scalar building. These aspects of the doctrine of proportions were integrated into the Aristotelian arguments so that a theory of linear proportionality concerned with the strength of materials could be formulated. This very first theory of strength of materials is the theory to which Galileo critically referred in his Discorsi where he published his own theory of strength of materials. Economic and military constraints are determined as the fundamental reasons for the commentators’ commitment to developing a theory of strength of materials that later linked Galileo's work to the practical knowledge of the architects and machine-builders of his time.     

Early nautical charts

Christian Wilhelm Blomstrand, Professor of Chemistry and Mineralogy at Lund University from 1862 to 1895, was one of the important chemists of the second half of the nineteenth century. His theoretical ideas and experimental accomplishments contributed to advances in several branches of chemistry. Living in Sweden during a transitional period between the older and newer chemistry and being a scientific as well as a political conservative, Blomstrand sought to reconcile Berzelius's dualistic theory with the unitary and type theories. He was opposed to Kekulé's dogma of constant valency, and he strove to establish a sound and complete theory of variable valency. This article briefly outlines Blomstrand's life and considers his best known book, Die Chemie der Jetztzeit (1869), as well as his work on mineralogy, inorganic chemistry (the earth acid elements, heteropoly acids, platinum complexes), and his theoretical views on valency, diazo compounds, and metal-ammines. His so-called ‘chain theory’, as developed and modified by his fellow Scandinavian chemist and close friend, Sophus Mads Jørgensen, was for more than three decades the most popular and successful of the numerous attempts to explain the constitution, properties, and reactions of coordination compounds.     

Huygens at work: Annotations in his rediscovered personal copy of Hooke's Micrographia

It is well known that Hooke's wave theory of light, set forth in his Micrographia of 1665, is viewed as a step towards Huygens's famous theory of light. This view depends mostly on some short remarks given by Huygens in his Traité de la Lumi`ere (1690) and the earlier Projet du Contenu de la Dioptrique (1673). Huygens's personal copy of Micrographia was believed to be lost until found at Braunschweig (Brunswick) University Library by the author three years ago. It is annotated at Observ. IX (pp. 47–67) only, where Hooke deals with his wave theory of light and colours. This article provides a short review of Hooke's theory, and an interpretation of Huygens's annotations, which show clearly the first steps towards the opinions he was to express in his Traité de la lumi`ere, particularly methodological ones. Furthermore, a short comparison is here drawn with Huygens's annotations in his copy of Ango's L'optique divisée en trois livres, which show similar patterns of reasoning.     

Leonhard Euler's ‘anti-Newtonian’ theory of light

Leonhard Euler was the leading eighteenth-century critic of Isaac Newton's projectile theory of light. Euler's main criticisms of Newton's views are surveyed, and also his alternative account according to which light is a wave motion propagated through the aether. Important changes are identified as having occurred between 1744 and 1746 in Euler's thinking about the way in which a wave such as he supposed light to be is propagated through a medium. Paradoxically, in view of Euler's overtly anti-Newtonian stand, these amount to Euler abandoning his early, Malebranchian notions about the physical basis of wave propagation, in favour of the ideas set out by Newton in Book II of his Principia.     

Instruments of Music,Instruments of Science: Hermann von Helmholtz's Musical Practices,his Classicism,and his Beethoven Sonata

The young Hermann Helmholtz, in an 1838 letter home, declared that he always appreciated music much more when he played it for himself. Though a frequent concert-goer, and celebrated for his highly influential 1863 work on the physiological basis of music theory, Die Lehre von den Tonempfindungen, it is likely that Helmholtz's enduring engagement with music began with his initial, personal experience of playing music for himself. I develop this idea, shifting the discussion of Helmholtz's work on sound sensation back to its origins, and examine the role of his material interaction with musical instruments and music itself. In his sound sensation studies, Helmholtz understood sound as an external, physical object. But Helmholtz also conceived of sound in musical terms. Further, Helmholtz's particular musical tastes as well as his deeply personal interaction with musical instruments allowed him to reconcile his conception of sound as physical object with his conception of sound as music. Helmholtz's physiological theory of sound sensation was both the product of and constitutive of how he heard and created sound. I argue that Helmholtz himself was the embodied reconciliation of his physiological theory of sound sensation and his belief that musical aesthetics were historically and culturally contingent.     

Life's Greatest Secret: The Race to Crack the Genetic Code

In response to the Lisbon earthquake of 1 November 1755, and the subsequent seismic activity in Europe, Kant wrote several articles on earthquakes and volcanic phenomena. Full translations of the most important parts of these articles are presented, and summaries for the remainder. Kant developed a carefully worked out theory to account for seismic activity, based on his reading of the scientific literature, the reports received in Königsberg of the Lisbon earthquake and associated events, and his general theory of the origin of the Earth's crust, as presented in his Allgemeine Naturgeschichte of 1755. Following Lémery, Kant supposed that volcanic action was due to the subterranean combination of sulphur and iron, and he rejected the suggestion that earthquakes might be due to the gravitational pull of heavenly bodies. Kant's theory was naturalistic, but his account was not wholly divorced from physicotheological considerations.     

The Reception of Miller's Ether-Drift Experiments in the USA: The History of a Controversy in Relativity Revolution

This paper analyses documents from several US archives in order to examine the controversy that raged within the US scientific community over Dayton C. Miller's ether-drift experiments. In 1925, Miller announced that his repetitions of the famous Michelson-Morley experiment had shown a slight but positive result: an ether-drift of about 10 kilometres per second. Miller's discovery triggered a long debate in the US scientific community about the validity of Einstein's relativity theories. Between 1926 and 1930 some researchers repeated the Michelson-Morley experiment, but no one found the same effect as Miller had. The inability to confirm Miller's result, paired with the fact that no other ether theory existed that could compete with special relativity theory, made his result an enigmatic one. It thus remained of little interest to the scientific community until 1954, when Robert S. Shankland and three colleagues reanalysed the data and proposed that Miller's periodic fringe shift could be attributed to temperature effects. Whereas most of the scientific community readily accepted this explanation as the conclusion of the matter, some contemporary anti-relativists have contested Shankland's methodology up to now. The historical accounts of Miller's experiments provide contradictory reports of the reaction of the US scientific community and do not analyse the mechanisms of the controversy. I will address this shortcoming with an examination of private correspondence of several actors involved in these experiments between 1921 and 1955. A complex interconnection of epistemic elements, sociological factors, and personal interests played a fundamental role in the closure of this experimental controversy in the early 1930s, as well as in the reception of Shankland's reanalysis in the 1950s.     

The Remarkable Fecundity of Leibniz's Work on Infinite Series

The publication in 1906 of Alexander Smith's Introduction to general inorganic chemistry inaugurated a decisive change in chemical pedagogy in the US, the effects of which are still evident. The nature and extent of Smith's innovations are described through a comparison of his text to its source material and contemporaries. His authoritative command of and whole-hearted commitment to the intellectual framework of Ionist physical chemistry set his text apart from its American competitors, while his efforts to make the tools of physical chemistry immediately useful to his readers distinguished it from its most immediate source material, Wilhelm Ostwald's Grundlinien der anorganischen Chemie. Smith's curricular innovations in chemistry were a practical expression of his radically restrictive view of the social role of collegiate education, which he conceived as solely of use for its ability to prepare students for professional life. During the fifteen years prior to the publication of his groundbreaking textbook, Smith underwent two critical, formative experiences. First, he retreated intellectually from the structural organic chemistry in which he was trained, ultimately adopting a professional identity as a physical inorganic chemist. His involvement in the controversy regarding the structure of 1,3-diketones reveals much about his reasons for eventually abandoning organic chemistry. Second, he served the National Education Association as chairman of the Sub-committee on College Entrance Requirements in Chemistry, in the process making a close study of the ends and methods of secondary and collegiate education. These experiences made him unique among proponents of physical chemistry in the US, and help account for the unique nature of his contributions to the development of the chemical professions.     

Scientific pluralism and the Chemical Revolution

In a number of papers and in his recent book, Is Water H₂O? Evidence, Realism, Pluralism (2012), Hasok Chang has argued that the correct interpretation of the Chemical Revolution provides a strong case for the view that progress in science is served by maintaining several incommensurable “systems of practice” in the same discipline, and concerning the same region of nature. This paper is a critical discussion of Chang's reading of the Chemical Revolution. It seeks to establish, first, that Chang's assessment of Lavoisier's and Priestley's work and character follows the phlogistonists' “actors' sociology”; second, that Chang simplifies late-eighteenth-century chemical debates by reducing them to an alleged conflict between two systems of practice; third, that Chang's evidence for a slow transition from phlogistonist theory to oxygen theory is not strong; and fourth, that he is wrong to assume that chemists at the time did not have overwhelming good reasons to favour Lavoisier's over the phlogistonists' views.     

Aldous Huxley and the Sheldonian hypothesis

For a period of almost twenty years Aldous Huxley made use in his novels and biographies of the theories of physique and character developed by the psychometrist William Sheldon. This is most clearly seen in the novel Time must have a stop, whose characters follow Sheldon's theories in the most intricate and precise fashion. Huxley's use of Sheldon's work in this novel will be examined, and his motives for embarking on this relatively rare use of science in literature discussed.     

The Lunar Theories of Tycho Brahe and Christian Longomontanus in the Progymnasmata and Astronomia Danica

Tycho Brahe's lunar theory, mostly the work of his assistant Christian Longomontanus, published in the Progymnasmata (1602), was the most advanced and accurate lunar theory yet developed. Its principal innovations are: the introduction of equant motion for the first inequality in order to separate the determination of direction and distance; a more accurate limit for the second inequality although requiring a more complex calculation; additional inequalities of the variation and, in place of the annual inequality in Tycho's earlier theory, a reduction in the equation of time; in the latitude theory a variation of the inclination of the orbital plane and an inequality of the motion of the nodes; a reduction in the range of variation of distance, parallax, and apparent diameter. Some of these were already present in Tycho's earlier lunar theory (1599), but all were changed in notable ways. Twenty years later Longomontanus published a modified version of the lunar theory in Astronomia Danica (1622), for the purpose of facilitating the calculation through new correction tables, and also explained his reasons for parts of the theory in the Progymnasmata. This paper is a technical study of both lunar theories.