流动注射活性氧化铝微型柱在线分离富集——火焰原子吸收法铬价态分析的研究

铬的分析具有十分重要的意义 ,本文初步研讨了一种运用活性三氧化二铝微型柱在线分离富集铬 ( )和铬 ( )的方法 ,以流动注射为进样技术。火焰原子吸收法为检测手段。在 PH=2和 PH=6分别富集铬 ( )和铬 ( )。 0 .75 mol/L 氨水和 1.0 mol/L 硝酸为洗脱液。进样时间为 70秒。富集倍数分别为 11.3倍和 2 7.2倍。检出限 (30℃ )分别为 17ppb和 5 2 ppb。精密度为 3.2 %和 3.7%。分析速度为 2 3个样 /小时。此法具有快速简便、灵敏高效的特点     

流动注射分光光度法同时测定岩矿中的痕量钴和锰

本文研究了meso—四(4—磺基苯)卟啉流动注射分光光度法同时测定痕量C_0(Ⅱ),Mn(Ⅱ)的方法。应用多管路汇流一带分割一汇流单检测器时间差法,测定了岩矿中ppb级的钻和锰方法操作简便,分析速度可达20样·小时~(-1)。     

流动注射在线预富集原子吸收光谱法测痕量镍

本文研究了用丁二酮肟为配合剂,流动注射在线预富集原子吸收光谱检测痕量镍的方法。该方法选择性好,基体干扰小,分析速度快(分析频率达80h—1),灵敏度高(检测下限达3ppb)。方法用于测定标准生物样品和标准合金样品中的痕量镍,准确率达98.7％和99.1％。     

水中微量溶解氧连续自动分析仪的研制

在工业生产上,水或海水经过脱气后,其中溶解氧通常应降到10ppb以下,因此水中微量(ppb级)溶解氧的分析是很重要的一个课题。国内生产的DH-52及DH-02型连续自动分析仪只能适用于水质很高的情况。因此,我们1977年在海水淡化的研究工作中研制了能够适用于海水之类的微量溶解氧连续自动分析仪。 我们采用的方法是用载气从连续流动的水样中吹出其中的溶解氧,然后用原电池法连续分析其含氧量。所用原电池是Pb｜KOH｜Ag电池。所设计的气水接触器或称吹出器是螺旋管式并流接触器,如图1所示。螺旋管是玻璃管制,内径5毫米,总长2.9米。后来改用塑料…     

我国南方某鸭场北京鸭黄曲霉毒素中毒症的病因分析

本文对我国南方某鸭场北京鸭黄曲霉毒素中毒症(aflatoxicosis)的病因进行了研究,发现鸭饲料中霉菌(特别是黄曲霉)污染严重。每克饲料中霉菌菌落数达9.00×10~(-5)个,其中黄曲霉达3.15×10个。50％黄曲霉菌株产毒,菌株产毒量强,其中有两株产黄曲霉毒素B_1高达1,500000ppb。饲料中黄曲霉素素B_1含量相当高,达475ppb。黄曲霉毒素可能是诱发幼鸭死亡的主要原因。     

酒中微量锌的阳极溶出伏安法测定

酒中微量锌与饮酒人的健康有很大的关系。本文提出用阳极溶出伏安法直接测定酒中微量锌,探讨了酒中锌的阳极溶出行为及其测试的最佳条件,在pH=5-6的NH4Cl—HCl底溶中,使用铂基汞膜电极及大面积银汞膜参比电极,富集电位-1.3v,测量锌的溶出峰,Ep=-0.68v,波形良好,不需要分离和化学富集,方法简单,快速,线性范围为2-100ppb,酒中含锌25ppb的相对标准偏差为1.0%,灵敏度0.2ppb,回收率为99—107%之间。     

Investigation of the ozone formation potential for ethanol using a smog chamber

The ozone formation reactivity of ethanol has been studied using chamber experiments and model simulations. The computer simulations are based on the MCM v3.1 mechanism with chamber-dependent auxiliary reactions. Results show that the MCM mechanism can well simulate C 2 H 5 OH-NO x chamber experiments in our experimental conditions, especially on ozone formation. C 2 H 5 OH-NO x irradiations are less sensitive to relative humidity than alkane species under our experimental conditions. In order to well simulate the experiments under high relative humidity conditions, inclusion of N 2 O 5 +H 2 O=2HNO 3 in the MCM mechanism is necessary. Under C 2 H 5 OH-limited conditions, the C 2 H 5 OH/NO x ratio shows a positive effect on d(O 3 -NO)/dt and RO 2 +HO 2 . High C 2 H 5 OH/NO x ratios enhance the production of organoperoxide radical and HO 2 radical concentrations, which leads to a much quicker accumulation of ozone. By using ozone isopleths under typical scenarios conditions, the actual ozone formation ability of ethanol is predicted to be 2.3-3.5 part per billion (ppb) in normal cities, 3.5-146 ppb in cities where ethanol gas are widely used, and 0.2-3.2 ppb in remote areas. And maximum ozone formation potential from ethanol is predicted to be 4.0-5.8 ppb in normal cities, 5.8-305 ppb in cities using ethanol gas, and 0.2-3.8 ppb in remote areas.     

痕量镓的阴极溶出伏安法

当pH=5时镓与桑色素形成配合物吸附在悬汞电极上,产生一个敏锐的还原波。本文探索了最佳条件和共存离子的干扰,其峰电流与镓的浓度成比例,线性范围在1～120ppb,检测下限为0.3ppb。实验方法应用在攀枝花钢厂的钢、铁、矿石和炉渣中镓的测定,结果良好。     

非色散原子荧光光谱法的应用研究——Ⅱ、氢化法测定砷

用一台自制的非色散原子荧光光度计与氢化法相结合测定痕量砷。荧光测量是建立在用硼氢化钾还原砷,并将砷的气体氢化物导入电加热石英管中原子化的基础上。砷的检出极限是0.2ppb或1ng。试剂空白在5毫升样品溶液中相当于5ng的砷。分析工作曲线的线性范围从检出极限算起约为3个数量极。该法应用于饮用水、废水和人发中痕量砷的测定,得到了满意的结果。     

基于部分线性模型研究空气臭氧含量与气象因素的关系

针对空气中臭氧含量增加对人体健康和生态环境均产生较大影响,而低空大气中臭氧污染日益恶化这一问题,就空气中臭氧含量提出部分线性模型。研究其与相关气象影响因素之间的关系,包括每日最高温度、太阳辐射和风速,并结合核方法和自助法得到臭氧含量均值估计和重要分位数估计,为空气质量监测和预测提供部分理论依据;结果表明空气中臭氧含量与每日最高温度和风速线性相关,与太阳辐射非线性相关,且回归估计函数随太阳辐射整体呈"S"型增长,臭氧含量均值为70. 58 ppb,它的10%、25%、50%、75%和90%分位数分别为42. 98 ppb、58. 64 ppb、71. 84 ppb、85. 49 ppb和96. 30 ppb。     

Markedness and its Interpretation in Language Use

Language markedness is a common phenomenon in languages, and is reflected from hearing, vision and sense, i.e. the variation in the three aspects such as phonology, morphology and semantics. This paper focuses on the interpretation of markedness in language use following the three perspectives, i.e. pragmatic interpretation, psychological interpretation and cognitive interpretation, with an aim to define the function of markedness.     

Features of Women's language

Language is a means of verbal communication. People use language to communicate with each other. In the society, no two speakers are exactly alike in the way of speaking. Some differences are due to age, gender, statue and personality. Above all, gender is one of the obvious reasons. The writer of this paper tries to describe the features of women＇s language from these perspectives： pronunciation, intonation, diction, subjects, grammar and discourse. From the discussion of the features of women＇s language, more attention should be paid to language use in social context. What＇s more, the linguistic phenomena in a speaking community can be understood more thoroughly.     

低渗透非均质砂岩油藏启动压力梯度研究

理论推导与室内实验相结合,建立了低渗透非均质砂岩油藏启动压力梯度确定方法。首先借助油藏流场与电场相似的原理,推导了非均质砂岩油藏启动压力梯度计算公式。其次基于稳定流实验方法,建立了非均质砂岩油藏启动压力梯度测试方法。结果表明:低渗透非均质砂岩油藏的启动压力梯度确定遵循两个等效原则。平面非均质油藏的启动压力梯度等于各级渗透率段的启动压力梯度关于长度的加权平均;纵向非均质油藏的启动压力梯度等于各渗透率层的启动压力梯度关于渗透率与渗流面积乘积的加权平均。研究成果可用于有效指导低渗透非均质砂岩油藏的合理井距确定,促进该类油藏的高效开发。     

On Tragic Consciousness In The Works By Ernest Hemingway

As an American modern novelist who were famous in the literary world, Hemingway was not a person who always followed the trend but a sharp observer. At the same time, he was a tragedy maestro, he paid great attention on existence, fate and end-result. The dramatis personae's tragedy of his works was an extreme limit by all means tragedy on the meaning of fearless challenge that failed. The beauty of tragedy was not produced on the destruction of life, but now this kind of value was in the impact activity. They performed for the reader about the tragedy on challenging for the limit and the death.     

Achieving Unusual States of Matter Under High Pressure

正The periodicity of the elements and the non-reactivity of the inner-shell electrons are two related principles of chemistry,rooted in the atomic shell structure.Within compounds,Group I elements,for example,invariably assume the+1 oxidation state,and their chemical properties differ completely from those of the p-block elements.These general rules govern our understanding of chemical structures and reactions.Using first principles calcula-     

Exchange-Correlation and Electronic Excitation Energies from Pairing Matrix Fluctuations

We have developed an adiabatic connection to formulate the ground-state exchange-correlation energy in terms of pairing matrix linear fluctuations.This formulation of the exchange-correlation energy opens a new channel for density functional approximations based on the many-body perturbation theory.We illustrate the potential of such approaches with an approximation based on the particle-particle Random Phase Approximation(pp-RPA).This re-     

Density Functional Theory for the Response of Periodic Systems to Electric Fields Based on the Vector Potential Approach

正The electronic and nuclear(structural/vibrational)response of 1D-3D nanoscale systems to electric fields gives rise to a host of optical,mechanical,spectral,etc.properties that are of high theoretical and applied interest.Due to the computational difficulty of treating such large systems it is convenient to model them as infinite and periodic(at least,in first approximation).The fundamental theoretical/computational problem in doing so is that     

On the Thermodynamic Limit for Responses to Static Electromagnetic Fields

For molecular systems,the quantum-mechanical treatment of their responses to static electromagnetic fields usually employs a scalar-potential treatment of the electric field and a vector-potential treatment of the magnetic field.Although the potential for each field separately is associated with the choice of an(unphysical)origin,the precise choice of the origin for the electrostatic field has little consequences for the results.This is different for the     

Call for Papers

<正>"The Journal of Shanghai Normal University:Mathematics"is published by Shanghai Normal University as regular issues of The Journal of Shanghai Normal University each year from 2014 in English.The editors-in-chief of the issues are professors Yuhao Cong and Maoan Han.The Journal of Shanghai Normal University was started in 1958 with     

Journal of Donghua University ( English Edition) Contents of Volume 31

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