噻唑杂环偶氮分散染料的溶剂效应

测试了两个噻唑杂环偶氮分散染料在十五种溶剂中的电子光谱,发现化合物的可见吸收光谱吸收带的(?)_(max)~(UV)不仅与溶剂的折射率n有关,而且与溶剂的介电常数ε有关,即与溶剂的n~2-1/2n~2+1、(ε-n~2)(2ε+n~2)/ε(n+2)~2和ε-1/ε+2-n~2-1/n~2+2存在着良好的线性关系。     

关于两类K_4同胚图色等价性的研究

利用色多项式研究了围长为7的K4同胚图K4(1,3,3,δ,ε,η)与K4(3,2,2,δ',ε',η')之间的色等价性问题,指出围长为7的K4同胚图K4(1,3,3,δ,ε,η)与K4(3,2,2,δ',ε',η')不存在色等价关系。这一结论有助于解决围长为7的K同胚图的色唯一性问题。     

含盐三元系的热力学行为(I)—丙酮—水—氯化锂和丙酮—水—氯化钾的临界现象

二十年前,李,芦曾报导了加盐于完全混溶的双液系而能使之分层时,存在着任何双液比的情况下,分层温度与盐量均呈直线关系 T=m×3÷T_0的规律。(T及T_0分别是有盐和无盐时的分层温度)、早年Prigogine曾用严格正规溶液模型在临界组成时推出了这一直线关系为本文利用正规溶液模型,假定盐量不大时,可以不受临界组成这个条件的限制而导出这种直线关系。同时,文章还报导了这种直线关系与着名的Furter和setschenov两个盐效应直线方程的必然连系。丙酮一水二元系当分别加入Licl及kcl时,测定了所形成体系的分层温度,得出了与盐量间存在的直线关系。最后,根据溶液在离子周围形成优势分布的观点,文章还解释了二元系加盐分层的机理。     

具有桥链七甲川菁染料的合成及其电子吸收光谱

合成了三个具有桥链的七甲川菁染料。研究染料结构对最大吸收波长的影响,并测定了染料在18种溶剂中的吸收光谱,发现染料的V_(max)~(ab)分别与溶剂的n~2-1/2n~2+1、(ε-n~2)(2ε+n~2)/ε(n+2)~2和((ε-1)/(ε+2))-((n~2-1)/(n~2+2))存在着良好的钱性关系。     

稀薄溶液中MEH-PPV共轭高分子的静态光散射研究

在不同温度下利用静态光散射技术研究了MEH-PPV共轭高分子在混合溶剂中的结构形态。结果显示,温度为25℃时甲苯/壬烷稀薄混合溶剂中MEH-PPV共轭高分子Zimm图有偏离直线现象出现,这表示溶液中存在少量的聚集结构。而温度为50℃时MEH-PPV共轭高分子Zimm图则呈直线状,这表示该温度下的甲苯/壬烷稀薄混合溶液为良溶剂。此外,还计算出MEH-PPV共轭高分子的单元分子量和单元长分别为260 g/mol和0.67 nm,进而由Kratky-Perod方程得到50℃下MEH-PPV分子链在混合溶剂中的持续长度lps分别为5.24 nm与3.68 nm,相应的Kuhn链结长lK分别为10.48 nm与7.36 nm,Kuhn链结数分别为1 329与1 871。     

有机相酶催化合成单甘酯对映体的研究

以固定化脂肪酶Novozym435为催化剂,有机溶剂为反应介质,油酸、甘油反应合成手性单甘酯,考察了溶剂对单甘酯的对映体选择性酯化反应的影响。分析了对映体过量值ee与溶剂的物性参数（疏水性LogP、介电常数ε、分子体积、溶解度参数δ）的相关性,结果表明,ee值与溶剂的分子体积、LogP都呈负相关性,在小分子溶剂或高极性溶剂体系,可获得较高ee值。     

极限分析定义中ε-N与ε-δ确定法

本文对ε的任意性、限定性,N 与δ的存在不唯一性,几何内涵及寻找法等等,多方位本质性地剖析研究,探索内在规律性,导致出确定法。     

关于整函数的幅角分布

本文证明了下述定理: 设f(z)为超越整函数,则必存在一条从原点出发的半直线B:arg z=θ_0(0≤θ_0<2π),具有下述性质:若n(≥3)为任一正整数,α(≠0)、b为任意二有穷复数,则对任意正数δ,有:n(r,θ_0,ε,f′-af~n=b)=∞。     

超临界CO2的溶剂特性对脂肪酶催化反应的影响

分别用溶解度参数和介电常数表征超临界流体的溶剂特性，并计算了不同压力下二氧化碳的溶解度参数和介电常数。测定了不同压力下脂肪酶催化月桂酸和正丁醇酯化反应的最大反应速率和米氏常数，研究了溶解度参数δ和介电常数ε对最大反应速率Ｖｍ的影响，并比较好地进行了关联：ｌｎ［Ｖｍａｘ／（ｍｍｏｌｈ－１ｇ－１）］＝４．４６５－０．１５３（δ／ＭＰａ０．５），ｌｎ［Ｖｍａｘ／（ｍｍｏｌｈ－１ｇ－１）］＝４．１８７－８．３１８（ε－１）／（ε＋１）．从而通过溶剂特性将压力这一操作条件直接与反应动力学相联系。     

关于两类K4同胚图色等价性的研究

利用色多项式研究了围长为7的K4同胚图K4(1，3，3，δ，ε，η)与K4(3，2，2，δ′，ε′，η′)之间的色等价性问题，指出围长为7的K4同胚图K4(1，3，3，δ，ε，η)与K4(3，2，2，δ′，ε′，η′)不存在色等价关系。这一结论有助于解决围长为7的K4同胚图的色唯一性问题。     

Markedness and its Interpretation in Language Use

Language markedness is a common phenomenon in languages, and is reflected from hearing, vision and sense, i.e. the variation in the three aspects such as phonology, morphology and semantics. This paper focuses on the interpretation of markedness in language use following the three perspectives, i.e. pragmatic interpretation, psychological interpretation and cognitive interpretation, with an aim to define the function of markedness.     

Features of Women's language

Language is a means of verbal communication. People use language to communicate with each other. In the society, no two speakers are exactly alike in the way of speaking. Some differences are due to age, gender, statue and personality. Above all, gender is one of the obvious reasons. The writer of this paper tries to describe the features of women＇s language from these perspectives： pronunciation, intonation, diction, subjects, grammar and discourse. From the discussion of the features of women＇s language, more attention should be paid to language use in social context. What＇s more, the linguistic phenomena in a speaking community can be understood more thoroughly.     

An Analysis of Catherine＇s Character——Wuthering Heights

Wuthering Heights, Emily Bronte＇s only novel, was published in December of 1847 under the pseudonym Ellis Bell. The book did not gain immediate success, but it is now thought one of the finest novels in the English language. Catherine is the key character of this masterpiece, because everybody and everything center on her though she had a short life. We can understand this masterpiece better if we know Catherine well.     

Lower Paleozoic oil relationships within Williston Basin, Canada

The Williston Basin is a significant petroleum province, containing oil production zones that include the Middle Cambrian to Lower Ordovician, Upper Ordovician, Middle Devonian, Upper Devonian and Mississippian and within the Jurassic and Cretaceous. The oils of the Williston Basin exhibit a wide range of geochemical characteristics defined as "oil families", although the geochemical signature of the Cambrian Deadwood Formation and Lower Ordovician Winnipeg reservoired oils does not match any "oil family". Despite their close stratigraphic proximity, it is evident that the oils of the Lower Palaeozoic within the Williston Basin are distinct. This suggests the presence of a new "oil family" within the Williston Basin. Diagnostic geochemical signatures occur in the gasoline range chromatograms, within saturate fraction gas chromatograms and biomarker fingerprints. However, some of the established criteria and cross-plots that are currently used to segregate oils into distinct genetic families within the basin do not always meet with success, particularly when applied to the Lower Palaeozoic oils of the Deadwood and Winnipeg Formation.     

低渗透非均质砂岩油藏启动压力梯度研究

理论推导与室内实验相结合,建立了低渗透非均质砂岩油藏启动压力梯度确定方法。首先借助油藏流场与电场相似的原理,推导了非均质砂岩油藏启动压力梯度计算公式。其次基于稳定流实验方法,建立了非均质砂岩油藏启动压力梯度测试方法。结果表明:低渗透非均质砂岩油藏的启动压力梯度确定遵循两个等效原则。平面非均质油藏的启动压力梯度等于各级渗透率段的启动压力梯度关于长度的加权平均;纵向非均质油藏的启动压力梯度等于各渗透率层的启动压力梯度关于渗透率与渗流面积乘积的加权平均。研究成果可用于有效指导低渗透非均质砂岩油藏的合理井距确定,促进该类油藏的高效开发。     

On Tragic Consciousness In The Works By Ernest Hemingway

As an American modern novelist who were famous in the literary world, Hemingway was not a person who always followed the trend but a sharp observer. At the same time, he was a tragedy maestro, he paid great attention on existence, fate and end-result. The dramatis personae's tragedy of his works was an extreme limit by all means tragedy on the meaning of fearless challenge that failed. The beauty of tragedy was not produced on the destruction of life, but now this kind of value was in the impact activity. They performed for the reader about the tragedy on challenging for the limit and the death.     

Achieving Unusual States of Matter Under High Pressure

正The periodicity of the elements and the non-reactivity of the inner-shell electrons are two related principles of chemistry,rooted in the atomic shell structure.Within compounds,Group I elements,for example,invariably assume the+1 oxidation state,and their chemical properties differ completely from those of the p-block elements.These general rules govern our understanding of chemical structures and reactions.Using first principles calcula-     

Exchange-Correlation and Electronic Excitation Energies from Pairing Matrix Fluctuations

We have developed an adiabatic connection to formulate the ground-state exchange-correlation energy in terms of pairing matrix linear fluctuations.This formulation of the exchange-correlation energy opens a new channel for density functional approximations based on the many-body perturbation theory.We illustrate the potential of such approaches with an approximation based on the particle-particle Random Phase Approximation(pp-RPA).This re-     

Density Functional Theory for the Response of Periodic Systems to Electric Fields Based on the Vector Potential Approach

正The electronic and nuclear(structural/vibrational)response of 1D-3D nanoscale systems to electric fields gives rise to a host of optical,mechanical,spectral,etc.properties that are of high theoretical and applied interest.Due to the computational difficulty of treating such large systems it is convenient to model them as infinite and periodic(at least,in first approximation).The fundamental theoretical/computational problem in doing so is that     

On the Thermodynamic Limit for Responses to Static Electromagnetic Fields

For molecular systems,the quantum-mechanical treatment of their responses to static electromagnetic fields usually employs a scalar-potential treatment of the electric field and a vector-potential treatment of the magnetic field.Although the potential for each field separately is associated with the choice of an(unphysical)origin,the precise choice of the origin for the electrostatic field has little consequences for the results.This is different for the