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1.
超重力尿素湿法烟气脱硝技术的研究   总被引:1,自引:0,他引:1  
通过考察氮氧化物湿法吸收机理,对NOx液相吸收的传质理论进行了相关分析。采用定-转子反应器(RSR)作为新型吸收设备,对尿素溶液吸收氮氧化物废气的工艺条件进行了试验研究,考察了液体流量、进气流量、定-转子反应器转速、尿素含量及吸收温度等因素对NOx脱除率的影响,确定了脱除NOx的最佳条件。试验结果表明,对定-转子反应器内部结构为SS-RH这种组合,最佳操作参数为液体流量0.2m3/h、进气流量0.2m3/h、定-转子反应器转速1400r/min、尿素溶液质量分数20%、吸收温度60℃。在此条件下,NOx的脱除率可达到63%。  相似文献   

2.
采用一种新的泡沫分离技术处理NO_x废气.在泡沫分离塔中,以含有A-912混合型表面活性剂的尿素溶液对NO_x进行吸收条件试验.经一级处理,吸收率达93%.  相似文献   

3.
研究CO2气体中的氮氧化物净化工艺,得到最佳条件:吸收液温度40~60℃,空塔气速5.4cm/s,填料高与塔径比9:1,瓷环填料空隙率为68%,尿素填充量为0.8倍填料高,吸收液中尿素溶液浓度不低于4.86mol/L。此方法是一种过程简单、综合利用的绿色化学工艺。  相似文献   

4.
分析了氮氧化物水吸收过程主要化学反应的特点,并据此提出了影响该吸收过程的基本规律;建立了基于反应速率的平衡级理论模型并用于反应吸收过程,实例验证了该模型计算结果的正确性,并分析了主要工艺条件温度、压力、氧气含量对NOx吸收过程的影响规律,为氮氧化物水吸收过程的设计和操作提供理论指导.  相似文献   

5.
硝酸尾气中氮氧化物净化技术研究   总被引:2,自引:0,他引:2  
介绍了用酸性尿素溶液作吸收剂,吸收硝酸尾气中氮氧化物的净化方法。用正交试验法选择最佳工艺条件,并对其结果进行极差分析和方差分析。该法具有去除率高、没有第二次污染、成本低的特点。  相似文献   

6.
针对传统氮氧化物废气处理工艺的不足,成功设计制作了与高温炭还原法相配套的处理装置,并对现场进行改造施工,将研究成果应用于生产实践,实现了碲硝酸氧化过程产生的氮氧化物废气的高效处理,达标排放。  相似文献   

7.
将尿素和GA-A型分子筛混合装入石英管中放入微波反应器里,进行从模拟富氧废气中脱除NOX的效果性能实验研究。微波GA-A型分子筛上尿素选择性还原能有效地脱除废气中的NOX,NOX的去除率可达92%,烟气微波脱硝去除量可达70.6 MG/H。尿素和GA-A型分子筛共同使用时净化效率和微波去除量明显高于单独使用尿素或GA-A型分子筛,单独使用GA-A型分子筛没有微波脱硝效果。微波脱硝效果随着入口NOX浓度的增大而增大。氮氧化物的净化效率随着气体流量的增加而逐渐减小,而微波脱硝去除量随着气体流量的增加而逐渐增大。适宜的功率为259~280 W,适宜的气体流量为0.5 M3/H左右,微波反应器内的温度为104~113℃,明显低于SCR和SNCR。微波脱硝的机理是GA-A型分子筛催化尿素和氮氧化物发生微波诱导催化反应达到脱硝的目的。  相似文献   

8.
纳米ZnO粉体的制备及其影响因素   总被引:11,自引:0,他引:11  
采用均匀沉淀法,以六水合硝酸锌为原料,尿素为沉淀剂,在不同反应条件下,合成不同晶粒尺寸的纳米氧化锌,用XRD、TEM和BET等方法表征所合成产品的形貌和平衡晶粒度等,讨论不同反应条件对产物性能的影响,并确定最佳反应条件。实验表明,在Zn^2 浓度为0.2mol/L、与尿素的量比为1:4时投料,于124℃搅拌下反尖3.5h,经离心洗涤和超声波处理,粗产物于80℃烘干后,在200℃煅烧3h,所得产物平均粒径为32.8nm,且粒径分布窄、分散性好,产率在85%以上。  相似文献   

9.
利用三氯异氰尿酸氧化作用,在较温和的反应条件下,氧化叔胺及含氮类杂环化合物,合成一系列的氮氧化物,产率52%-92%.  相似文献   

10.
半干法制备高结合磷淀粉磷酸酯的研究   总被引:8,自引:0,他引:8  
以木薯淀粉为原材料、三聚磷酸钠为酯化剂、尿素为催化剂,半干法制备了高结合磷淀粉磷酸酯。探讨了反应温度、反应时间、尿素用量、pH值和磷酸盐用量对结合磷含量和反应效率的影响,确定了最佳的反应条件,当淀粉用量为100g(绝干),蒸馏水用量为100mL时,反应温度150℃,反应时间1h,尿素用量2g,pH5.0,三聚磷酸钠用量5g,产品的结合磷含量1.19%,反应效率55.32%。  相似文献   

11.
Language markedness is a common phenomenon in languages, and is reflected from hearing, vision and sense, i.e. the variation in the three aspects such as phonology, morphology and semantics. This paper focuses on the interpretation of markedness in language use following the three perspectives, i.e. pragmatic interpretation, psychological interpretation and cognitive interpretation, with an aim to define the function of markedness.  相似文献   

12.
何延凌 《科技信息》2008,(4):258-258
Language is a means of verbal communication. People use language to communicate with each other. In the society, no two speakers are exactly alike in the way of speaking. Some differences are due to age, gender, statue and personality. Above all, gender is one of the obvious reasons. The writer of this paper tries to describe the features of women's language from these perspectives: pronunciation, intonation, diction, subjects, grammar and discourse. From the discussion of the features of women's language, more attention should be paid to language use in social context. What's more, the linguistic phenomena in a speaking community can be understood more thoroughly.  相似文献   

13.
理论推导与室内实验相结合,建立了低渗透非均质砂岩油藏启动压力梯度确定方法。首先借助油藏流场与电场相似的原理,推导了非均质砂岩油藏启动压力梯度计算公式。其次基于稳定流实验方法,建立了非均质砂岩油藏启动压力梯度测试方法。结果表明:低渗透非均质砂岩油藏的启动压力梯度确定遵循两个等效原则。平面非均质油藏的启动压力梯度等于各级渗透率段的启动压力梯度关于长度的加权平均;纵向非均质油藏的启动压力梯度等于各渗透率层的启动压力梯度关于渗透率与渗流面积乘积的加权平均。研究成果可用于有效指导低渗透非均质砂岩油藏的合理井距确定,促进该类油藏的高效开发。  相似文献   

14.
As an American modern novelist who were famous in the literary world, Hemingway was not a person who always followed the trend but a sharp observer. At the same time, he was a tragedy maestro, he paid great attention on existence, fate and end-result. The dramatis personae's tragedy of his works was an extreme limit by all means tragedy on the meaning of fearless challenge that failed. The beauty of tragedy was not produced on the destruction of life, but now this kind of value was in the impact activity. They performed for the reader about the tragedy on challenging for the limit and the death.  相似文献   

15.
正The periodicity of the elements and the non-reactivity of the inner-shell electrons are two related principles of chemistry,rooted in the atomic shell structure.Within compounds,Group I elements,for example,invariably assume the+1 oxidation state,and their chemical properties differ completely from those of the p-block elements.These general rules govern our understanding of chemical structures and reactions.Using first principles calcula-  相似文献   

16.
We have developed an adiabatic connection to formulate the ground-state exchange-correlation energy in terms of pairing matrix linear fluctuations.This formulation of the exchange-correlation energy opens a new channel for density functional approximations based on the many-body perturbation theory.We illustrate the potential of such approaches with an approximation based on the particle-particle Random Phase Approximation(pp-RPA).This re-  相似文献   

17.
正The electronic and nuclear(structural/vibrational)response of 1D-3D nanoscale systems to electric fields gives rise to a host of optical,mechanical,spectral,etc.properties that are of high theoretical and applied interest.Due to the computational difficulty of treating such large systems it is convenient to model them as infinite and periodic(at least,in first approximation).The fundamental theoretical/computational problem in doing so is that  相似文献   

18.
<正>"The Journal of Shanghai Normal University:Mathematics"is published by Shanghai Normal University as regular issues of The Journal of Shanghai Normal University each year from 2014 in English.The editors-in-chief of the issues are professors Yuhao Cong and Maoan Han.The Journal of Shanghai Normal University was started in 1958 with  相似文献   

19.
20.
<正>"Journal of Jilin University(Science Edition)"is a comprehensive academic journal in the fields of science sponsored by Jilin University and administrated by the Ministry of Education of the Peoples Republic of China.The journal started publication in 1955.The original name at starting publication was"Journal of Natural Science of Northeast People University",which was changed into"Acta Scientiarum Naturalium Universitatis Jilinensis"in 1958 owing to the name change of the university.The present journal name has  相似文献   

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