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1.
1-氨基萘-6-磺酸和它的二水合物的晶体结构   总被引:1,自引:0,他引:1  
利用x-射线衍射分析测定了标题化合物的晶体结构。1-氨基萘-6-磺酸属正交晶系,空间群Pbca,a=1.0543(5),b=1.1126,c=1.6203(1)nm,V=1.900nm3,最终偏离因子R=0.048,Rw=0.046;二水合1-氨基萘-6-磺酸属单斜晶系,空间群P21/n,a=1.1290(2),b=0.7486(8)c=1.8677(8)nm,β=106.1(2)°,V=1.1111nm3,最终偏离因子R=0.048,Rw=0.0530。  相似文献   

2.
二苯乙烯荧光蓝-S荧光猝灭测定微量锌(Ⅱ)   总被引:1,自引:0,他引:1  
研究了二苯乙烯荧光蓝-S荧光猝灭测定微量锌(Ⅱ)的实验条件.在pH6.0的H3PO4-H3BO3-HAc-NaOH缓冲溶液中,试剂的最大激发波长λex=367nm,最大荧光发射波长λem=457nm;Zn(Ⅱ)与试剂生成的1∶2的配合物使试剂的荧光强度减弱;利用荧光猝灭法测定微量锌(Ⅱ),线性范围为0~0.8μg/10ml;方法用于测定食品中、人发中的微量锌(Ⅱ),结果满意.  相似文献   

3.
二苯乙烯荧光蓝—S荧光猝灭测定微量锌(II)   总被引:3,自引:0,他引:3  
研究了二苯乙烯荧光蓝-S荧光猝灭测量微量锌(Ⅱ)的实验条件,在pH6.0的H3PO4-H3BO3-HAc-NaOH缓冲溶液中,试剂的最大激发波长λex=367nm,最大荧光发射波长λem=457nm;Zn(Ⅱ)与试剂生成的1:2的配合物使试剂的荧光强度减弱;利用荧光猝灭法测定微量锌(Ⅱ),线性范围为0 ̄0.8μg/10ml;方法用于测量食品中、人发中的微量锌(Ⅱ),结果满意。  相似文献   

4.
拟定了测定微量锌(Ⅱ)的新方法,研究了锌(Ⅱ).水杨基荧光酮-阳离子表面活性剂体系的显色反应,实验证明,在pH(9.0~9.7)的H_3BO_3-H_3PO_4-HAc-NaOH缓冲体系中,锌(Ⅱ)与水杨基荧光酮生成1:2的配合物,在阳离子表面活性剂-溴化十六烷基三甲胺(CTMAB)存在下生成1:2:3的蓝紫色三元配合物,λ_(max)为570nm,表观摩尔吸光系数ε为7.7×10 ̄4L·mol-1·cm-1,可在水相中直接测定锌(Ⅱ);并且详细研究了最佳实验条件,锌(Ⅱ)含量在(1.0~8.0)μg/25mL,范围符合比耳定律,锌(Ⅱ)的检测限为0.04μg/mL,用于快速测定食品中的微量锌(Ⅱ),结果满意。  相似文献   

5.
UO2(PMBP)2HMPA配合物的合成与结构研究   总被引:1,自引:0,他引:1  
合成了UO_2(PMBP)_2HMPA(PMBP=1-苯基-3-甲基-4-苯甲酰基-吡唑啉酮-5,HMPA=六甲基磷酰胺),测定了该配合物的元素组成、红外光语、质子核磁共振谱及晶体结构。该晶体属于单斜晶系,空间群为P2_1,a=1.1468(5)nm,b=1.4777(2)nm,c=1.4056(6)nm,β=100.91(4)°,V=2.3389nm ̄3,D_c=1.43g/cm ̄3,Z=2,F(000)=979.85。在配合物中,U原子采用七配位,其配位多面体为扭曲的五角双锥。  相似文献   

6.
用3-硝基-1,2,4-三唑-5-酮(NTO)的锂盐水溶液与Eu2O3的稀硝酸溶液反应,合成了NTO的铕配合物,其单晶结构用X射线分析法进行了测定,确定了它的结构式为〔Eu(NTO)3(H2O)5〕5H2O。其晶体属单斜晶系,空间群为P21/n,最终偏离因子R为0.023。晶胞参数如下:a1.8720(2)nm,b0.6548(3),c1.9323(3)nm,β95.33(1)°,V2.3583(5)nm3,Z4,Dc2.026gcm-3,μ27.678cm-1,F(000)1432。铕离子的配位数为8,其配位多面体为畸变的十二面体  相似文献   

7.
报道了用N-苯基-3-羟基-2-乙基-4-吡啶酮(HL)为配体合成了Fe(Ⅲ)型配合物,并测定了它的晶体结构,晶体属单斜晶系,空间群P21/c;a=1.6767(5)nm,b=1.219(3)nm,c=1.730(1)nm;β=93.31°;V=3.530(8)nm^3,Z=4,Dc=1.382g/cm^3。结构分析表明Fe处于三个N-苯基-3-羟基-2-乙基-4-吡啶酮的6个氧原子的畸变的八面体配位环境中。  相似文献   

8.
分别测定了PAC电极(Pb-Ag-Ca新型阳极的简称)在MnSO4-H2SO4溶液中的阴极极化曲线及阳极极 线,从图中求得:icor=15.85μA/cm^2,ψωr=-0.095V,Vcor=2.95Kg/m^2ann.7.90%(电极重量每年消耗的百分数)i。(2)=54.70μA/cm^2及i。(3)=1.10μA/cm^2;讨论了PAC阳极的腐蚀机理即反应(2)受反应(3)的动力学参数所  相似文献   

9.
本文报道了由乙基麦芽酚(ethylmaltol,3-羟基-2-乙基-4(H)-吡喃酮)和对甲苯胺合成标题化合物,并进行了元素分析,UV,IR,MS,1HNMR表征和X射线单晶结构分析.该晶体属单斜晶系,空间群P21/n.a=0.7035(1),b=1.8615(7),c=1.8296(2)nm,β=99.81°,Z=8,V=2.4526(10)nm3,Dc=1.242mg/m3.该晶体中存在着分子间氢键.  相似文献   

10.
用X—射线测定了meso-四(4-甲氧基苯基)卟啉的溶剂合物(TPMP·CHCl3)的晶体结构。实验表明,该晶体属单斜晶系,空间群P21/C,a=1.4377(2)nm,b=0.9674(7)nm,c=1.5688(4)nm,β=101.00(2)°,V=2.142nm3,Z=2,dc=1.324g/cm3,μ=2.613cm-1,F(000)=444。讨论了分子结构中的非平面共轭效应及卟啉环与锰(Ⅲ)离子配位后锰(Ⅲ)对其结构参数的影响。  相似文献   

11.
Language markedness is a common phenomenon in languages, and is reflected from hearing, vision and sense, i.e. the variation in the three aspects such as phonology, morphology and semantics. This paper focuses on the interpretation of markedness in language use following the three perspectives, i.e. pragmatic interpretation, psychological interpretation and cognitive interpretation, with an aim to define the function of markedness.  相似文献   

12.
何延凌 《科技信息》2008,(4):258-258
Language is a means of verbal communication. People use language to communicate with each other. In the society, no two speakers are exactly alike in the way of speaking. Some differences are due to age, gender, statue and personality. Above all, gender is one of the obvious reasons. The writer of this paper tries to describe the features of women's language from these perspectives: pronunciation, intonation, diction, subjects, grammar and discourse. From the discussion of the features of women's language, more attention should be paid to language use in social context. What's more, the linguistic phenomena in a speaking community can be understood more thoroughly.  相似文献   

13.
理论推导与室内实验相结合,建立了低渗透非均质砂岩油藏启动压力梯度确定方法。首先借助油藏流场与电场相似的原理,推导了非均质砂岩油藏启动压力梯度计算公式。其次基于稳定流实验方法,建立了非均质砂岩油藏启动压力梯度测试方法。结果表明:低渗透非均质砂岩油藏的启动压力梯度确定遵循两个等效原则。平面非均质油藏的启动压力梯度等于各级渗透率段的启动压力梯度关于长度的加权平均;纵向非均质油藏的启动压力梯度等于各渗透率层的启动压力梯度关于渗透率与渗流面积乘积的加权平均。研究成果可用于有效指导低渗透非均质砂岩油藏的合理井距确定,促进该类油藏的高效开发。  相似文献   

14.
As an American modern novelist who were famous in the literary world, Hemingway was not a person who always followed the trend but a sharp observer. At the same time, he was a tragedy maestro, he paid great attention on existence, fate and end-result. The dramatis personae's tragedy of his works was an extreme limit by all means tragedy on the meaning of fearless challenge that failed. The beauty of tragedy was not produced on the destruction of life, but now this kind of value was in the impact activity. They performed for the reader about the tragedy on challenging for the limit and the death.  相似文献   

15.
正The periodicity of the elements and the non-reactivity of the inner-shell electrons are two related principles of chemistry,rooted in the atomic shell structure.Within compounds,Group I elements,for example,invariably assume the+1 oxidation state,and their chemical properties differ completely from those of the p-block elements.These general rules govern our understanding of chemical structures and reactions.Using first principles calcula-  相似文献   

16.
We have developed an adiabatic connection to formulate the ground-state exchange-correlation energy in terms of pairing matrix linear fluctuations.This formulation of the exchange-correlation energy opens a new channel for density functional approximations based on the many-body perturbation theory.We illustrate the potential of such approaches with an approximation based on the particle-particle Random Phase Approximation(pp-RPA).This re-  相似文献   

17.
正The electronic and nuclear(structural/vibrational)response of 1D-3D nanoscale systems to electric fields gives rise to a host of optical,mechanical,spectral,etc.properties that are of high theoretical and applied interest.Due to the computational difficulty of treating such large systems it is convenient to model them as infinite and periodic(at least,in first approximation).The fundamental theoretical/computational problem in doing so is that  相似文献   

18.
For molecular systems,the quantum-mechanical treatment of their responses to static electromagnetic fields usually employs a scalar-potential treatment of the electric field and a vector-potential treatment of the magnetic field.Although the potential for each field separately is associated with the choice of an(unphysical)origin,the precise choice of the origin for the electrostatic field has little consequences for the results.This is different for the  相似文献   

19.
<正>"The Journal of Shanghai Normal University:Mathematics"is published by Shanghai Normal University as regular issues of The Journal of Shanghai Normal University each year from 2014 in English.The editors-in-chief of the issues are professors Yuhao Cong and Maoan Han.The Journal of Shanghai Normal University was started in 1958 with  相似文献   

20.
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