Exploring cyclic changes of the ocean carbon reservoir

A 5-Ma record from ODP Site 1143 has re-vealed the long-term cycles of 400—500 ka in the carbon isotope variations. The periodicity is correlatable all over the global ocean and hence indicative of low-frequency changes in the ocean carbon reservoir. As the same periodicity is also found in carbonate and eolian dust records in the tropical ocean, it may have been caused by such low-latitude proc-esses like monsoon. According to the Quaternary records from Site 1143 and elsewhere, major ice-sheet expansion and major transition in glacial cyclicity (such as the Mid-Brunhes Event and the Mid-Pleistocene Revolution ) were all pre-ceded by reorganization in the ocean carbon reservoir ex-pressed as an episode of carbon isotope maximum (d 13Cmax), implying the role of carbon cycling in modulating the glacial periodicity. The Quaternary glacial cycles, therefore, should no more be ascribed to the physical response to insolation changes at the Northern Hemisphere high latitudes alone; rather, they have been driven by the 揹ouble forcing? a combination of processes at both high and low latitudes, and of processes in both physical (ice-sheet) and biogeochemical (carbon cycling) realms. As the Earth is now passing through a new carbon isotope maximum, it is of vital impor-tance to understand the cyclic variations in the ocean carbon reservoir and its climate impact. The Pre-Quaternary varia-tions in carbon and oxygen isotopes are characterized by their co-variations at the 400-ka eccentricity band, but the response of d 13C and d 18O to orbital forcing in the Quater-nary became diverged with the growth of the Arctic ice-sheet. The present paper is the second summary report of ODP Leg 184 to the South China Sea.     

Pollen evidence from Baode of the northern Loess Plateau of China and strong East Asian summer monsoons during the Early Pliocene

The red clay eolian sequence on the Chinese Loess Plateau (CLP) is an important archive for paleoclimate change from the late Miocene to Pliocene,and can provide significant information for the controversial problems of East Asian monsoon evolution and its forcing mechanism.In this study,we present a pollen record from Baode,northern CLP.The record shows four stages of paleoecological evolution.From 5.6-4.4 Ma,a forest steppe ecosystem developed under an extremely warm period with high seasonal precipitation.Since 4.4 Ma,a drier episode occurred,which prompted parkland landscapes to develop.During 3.5-3.05 Ma,the environment changed to a rather open steppe ecosystem with a much cooler and drier climate.After 3.05 Ma,the vegetation evolved to forest steppe.Using the percentages of arboreal plants to mirror precipitation,and comparing with other published pollen data from the CLP,we find the existence of S-N directionality of the precipitation change and high percentage of arboreal plants in the entire CLP during the Early Pliocene,which suggest the CLP was characterized by a strong East Asian summer monsoon.The strong summer monsoon corresponds well to the low global ice volume,which may illuminate global climate mechanism for the summer monsoon evolution in the early Pliocene.     

A rock magnetic record of Asian cooling and aridification processes during 1.95-0.40 Ma in the southeastern Chinese Loess Plateau

The southeastern Chinese Loess Plateau is the terminal deposition area of dusts transported by the East Asian winter monsoon and the frontal area penetrated by the East Asian summer monsoon,and thus a climate sensitive region.This paper reports a rock magnetic study of a Quaternary loess-paleosol section in such a region.We tried to reconstruct the paleoclimate evolution history in the region during 1.95–0.40 Ma with magnetic parameters.The results show a general up-section decreasing trend of the ratio of HIRM/(SIRM–IRM100 mT),indicating a long-term decreasing trend of hematite coercivities in the deposits,which can be mainly related to the cooling and aridification trend of the environment in interglacial depositional area and glacial dust source region.The ratio,lf/ARM,widely used to reflect the variations of magnetic mineral grain size,manifests a long-term increasing trend of the magnetic mineral grain size and tends to indicate an overall weakening trend of the East Asian summer monsoon that controlled the pedogenic intensity.Although the regional multi-segmented paleoclimatic records revealed by several magnetic parameters in our study,the long-term Asian cooling and aridification trend inferred here is of global correlation significance.     

Sediment provenance and evolution of the East Asian winter monsoon since 700 ka recorded by major elements in the West Philippine Sea

To synthetically realize the character of major-element compositions as well as its significance for provenance and paleoenvironment recorded in core sediments of the West Philippine Sea over the last 700 ka,grain size and major elements of 221 bulk sediments,together with major-element compositions in the detrital phase of 16 typical samples,in core MD06-3047 collected from the Benham Rise were analyzed.Both discrimination plot and R-mode factor analysis indicate that vertical changes of major elements are mainly controlled by the sedimentation of nearby volcanic matter and the eolian dust input,whereas influences from marine biologic deposition and hydrothermal activity are minor.In particular,Al2O3 and K2O are representative of an eolian dust factor.The variation in the eolian dust factor score is characterized by the obviously glacial-interglacial periodicity and can be well compared with the paleotemperature record of the Antarctic ice core and the evolution of the East Asian winter monsoon(EAWM) recorded in the Chinese loess sequence,and then offers a new proxy for the evolution history of eolian dust input into the study area that is controlled by the EAWM intensity and aridity in the continental source regions of atmospheric dust.     

Variations of geochemical compositions and the paleoclimatic significance of a loess-soil sequence from Garzê County of western Sichuan Province, China

The West Sichuan Plateau is located in the southeast margin of the Tibetan Plateau, where the climate is mainly influenced by the Indian southwest summer monsoon and the Tibetan Plateau monsoon. In this study, detailed geochemical analysis has been carried out on Ganzisi loess-paleosol sequence in Ganzê County of western Sichuan Province. The results indicate that Ganzê loess and paleosol have experienced the incipient stage of chemical weathering in dust source regions, characterized by the decomposition of plagioclase which caused the depletion of mobile elements Na and Ca. The post-depositional chemical weathering is characterized by carbonate dissolution and oxidation of Fe2＋. The variations of some geochemical indexes （such as CIA values, Na/K and Fe2＋/ Fe3＋ ratios） in Ganzisi loess-paleosol sequence indicate a gradually decreased chemical weathering intensity in the dust source regions and deposition areas since 1.15 Ma BP consistent with the general increase of global ice volume, reflecting that the arid trend since 1.15 Ma BP in the southeast Tibetan Plateau is a regional response to the global climate change. The geochemical indexes in this section also reveal an obvious drying step occurred at about 250 ka BP in this region. We interpret this drying step as a result of decreased influence of the Indian southwest summer monsoon. This decrease in monsoon moisture is probably attributable to the uplift of the southeast margin of the Tibetan Plateau at about 250 ka BP.     

Rapid denudation of the Himalayan orogen in the Nyalam area,southern Tibet,since the Pliocene and implications for tectonics–climate coupling

The Himalayan orogen characterized by very high variability in tectonic and climatic processes,and is thus regarded as a natural laboratory for investigating the coupling of tectonics and climate,as well as the influence of this coupling on geomorphological processes.This study uses apatite fission track(AFT)dating of samples from a45-km-long section crossing the Great Himalaya Crystalline Complex(GHC)in the Nyalam area,southern Tibet,to constrain the timing and rate of late Cenozoic denudation.The AFT ages can be divided into two groups:(1)15–6 Ma,to the north of Nyalam town,for which the bestfit line of elevation-age has a gentle slope of 0.05,and for which a denudation rate of 0.27 mm/a is calculated;and(2)3–1 Ma,south of Nyalam town,for which the best-fit line has a steep slope of 0.64,and for which a denudation rate of 1.32 mm/a is calculated.The whole AFT ages has a positive correlation with sample elevation(i.e.,older ages are found at higher elevations),and the geographical location of the point of inflexion of the two fitted lines corresponds closely to the junction of Poqu River near Nyalam town.By integrating the AFT data with thermotectonic modeling,it can be inferred that the GHC has experienced two different periods of denudation:(1)slow denudation during middle to late Miocene(15–6 Ma)is recorded in the northern part of the GHC;and(2)rapid denudation from the Pliocene to the Pleistocene(3–1 Ma)is recorded in the southern part of the GHC.An abrupt change in denudation rate occurred between the two periods,with the Pliocene–Pleistocene denudation rate being five times higher than that during the Miocene.This abrupt change in denudation rate during Pliocene pervaded the Himalayan orogen,and was roughly synchronous with a marked change in global climate at 4–3 Ma,and intensification of the Asian monsoon.Importantly,the later period of rapid denudation in the study region closely coupled to the mean annual precipitation,while there is no clear evidence for large-scale faulting activity and associated uplift during this period.Therefore,climate(precipitation)is inferred to be the main cause of the rapid denudation of the Himalayan orogen since the Pliocene.     

Evidences of rapid erosion driven by climate in the Yarlung Zangbo （Tsangpo） Great Canyon, the eastern Himalayan syntaxis

Climate and tectonism are both particularly intense in the Yarlung Zangbo (Tsangpo) Great Canyon in the eastern Himalayan syntaxis,which is characterized by the most rapid landscape evolution of anywhere in the world.Thus,the eastern Himalayan syntaxis is one of the best locations to study the interactions between climate and tectonics.This paper investigates the cooling ages of the Doxong La-Baibung profile using apatite fission track (AFT) dating on 11 bedrock samples at elevations ranging from 4210 to 710 m.There are topographic,climatic,metamorphic,and thermochronological gradients in the profile,providing good conditions to study interactions between climate and tectonics.AFT ages ranged from 4.6±0.6 Ma to 1.7±0.3 Ma,and the mean fission track lengths ranged from 11.0 to 12.4 μm.It was found that the cooling rates revealed by AFT ages increased with decreasing elevation.However,the tendency of the cooling rates revealed by the 40 Ar-39 Ar ages was different from that indicated by the AFT ages.Moreover,for most districts of the eastern Himalayan syntaxis,the compiled AFT age distribution correlates well with the annual average precipitation,indicating the coupling of the cooling and erosion rates of the near-surface rock and precipitation.The geothermal history modeling results indicate an obvious increase in the cooling and erosion rate between 1.0 and 0.5 Ma.This age is consistent with other research findings for this time,when the vapor channel of the Yarlung Zangbo Great Canyon began to take effect.These evidences suggest that climate,especially precipitation,has acting as a key factor influencing the rapid cooling and erosion in the Yarlung Zangbo Great Canyon since 1-0.5 Ma.     

Dust storms and loess accumulation on the Tibetan Plateau：A case study of dust event on 4 March 2003 in Lhasa

Whether the Tibetan Plateau is a significant dust source area is of great importance, because this is related to the understanding of sources, accumulation and environmental effects of dusts on the Tibetan Plateau and inthe Far East-Pacific Ocean regions as well as to the evointion of coupling of the Tibetan Plateau and atmaspbere-oeean-continent exchange. Synoptic dynamics and remote sensing tracing of a dust storm on 3 to 5 March, 2003 in Lhasa onSouth Tibet demonstrate that the Tibetan Plateau possessesall factors and conditions of generating dust storms. Accompanied with this dust storm is a strong ascending stream onthe Plateau which has raised various sizes of durst particlesinto different levels. The lifted coarse particles were largelyfallen down and accumulated as loess on the eastern TibetanPlateau, and the fine particles were translated by the westerly jet and subsided in the northern Pacific Ocean. The spa-tial-temporal distribution of dust-storms between years 1961and 2000 ou the Plateau shows that duststorms mainly occurin winter and early spring with high frequency, and tile pathof dust storm moves gradually from south to north, which isclosely coupled with the northward moving of the westerlyjet from winter to spring over the Tibetan Plateau. Com-pared with other twelve dust source areas in China. the Ti-betan Plateau is one of the key dust souree areas for thelong-distance transport because its high occurring frequencyand elevation cause fine particles easily to be lifted into thezone of the westerly jet.     

Rock magnetic studies on the hominoid-bearing sediments at Zhupeng, Yuanmou Basin, southwestern China and its paleoclimatic significance

It has been proposed that paleoclimatic changes and tectonic events strongly affect hominoid evolution. The Zhupeng section at Yuanmou Basin, southwestern China, with the hominoid-bearing fluvial-lacustrine sediments, is an ideal natural laboratory to test this hypothesis. This study provided an integrated magnetic study, including low-frequency susceptibility, the anisotropy of magnetic susceptibility, temperature-dependent susceptibility, hysteresis loops, isothermal remanent magnetization, and anhysteretic remanent magnetization, on samples from the Baozidongqing section at Zhupeng. Results show that the dominant mag- netic carrier is hematite, with minor amount of magnetite. Both the composition and concentration of magnetic miner- als strongly correlate with the lithostratigraphy. At least eight short-term events defined by higher concentrations of magnetite were identified. These short events reflect that the subtropical dry-hot climate is similar to today＇s climate. Basing on the lithostratigraphic and rock magnetic results, we suggest that Yuanmou Basin was in a steady deposition environment from about 11 to 7 Ma, which is characterized by alternating of long-term torrid-humid climate and short-term dry-hot climate. Our study provides invaluable environment information for understanding the climate shift and the relationship between paleoenvironment and hominoid evolution in southwestern China during late Miocene.     

Growth ages of ferromanganese crusts from the western and central Pacific： Comparison between nannofossil analysis and ^10Be dating

Based on results of nannofossil analysis and 10Be dating in ferromanganese crusts M1-1 and A1-1 (no nannofossils were found in it),from the western and central Pacific respectively,it is found that the crust growth ages from nannofossil biostrati-graphy agree well with those based on 10Be isotope analysis. Both crusts have three growth layers,and the oldest layer was deposited in Miocene at about 12.80 Ma. The maximum,minimum,and average growth rates of crust A1-1 (from the central Pacific) are 8.11,1.92 and 3.47 mm/Ma,and those of crust M1-1 (from the western Pacific) are 2.93,0.47,and 0.94 mm/Ma.     

Quantitative reconstruction of the paleosalinity at Qinghai Lake in the past 900 years

Based on the function relationship between the shell length of Limnocythere inopinata and the salinity of its living water in Tibetan Plateau lakes, the paleosalinty of Qinghai Lake in the past 900 years was reconstructed through the measurement of the adult body length of Limnocythere inopinata. Meanwhile, the paleosalinity sequence of Qinghai Lake during the same period was rebuilt by the St/Ca ratio of the shell of Eucypris inflata combined with the St/Ca ratio of living ostracod valves from the species of genus Eucypris inflata and the host water. The paleosalinity results obtained by two different methods were compared and assessed in this paper. To check the result, it was also contrasted with other historical climatic sequences of this area including tree ring and ice core. It was shown that the paleosalinity sequence rebuilt by adult ostracod body length had high reliability, and the paleosalinity reconstruction method by trace elements of ostracod shells was not suitable for Qinghai Lake. From the reconstructed paleosalinty sequence of Qinghai Lake, it can be found that low salinity during 1160-1290 AD showed the humid climate condition on the Mediaeval Warm Period in this area, while the high salinity during 1410-1540 AD, 1610-1670 AD and 1770-1850 AD which was corresponding to the three cold pulses of the Little Ice Age with a dry climate condition. And the high salinity in the latest several decades was consistent with recent warm and dry trends of the climate in this area. The good consistency of the reconstructed palaeosalinity sequence and the precipitation sequence in this area rebuilt by tree ring proves the reconstruction of past lake salinity is reliable.     

Sm-Nd isotopic geochronology of the Yinachang Fe-Cu-REE deposit at Wuding, Yunnan Province and its genetic significance

Sm-Nd isotope systematics of ores and fluorites places precise time constraints on REE mineralization of the Yinachang Fe-Cu-REE deposit in Yunnan Province which occur in the Proterozoic Kunyan group. The ore-related fluorites contain high abundant REE, and show a strong enrichment of LREE and a positive Eu anomaly, which is in marked contrast to post-ore fluorites that are HREE enriched. The Sm-Nd isochron ages of the ores and fluorites are 1539±40 Ma and 1617±100 Ma, respectively, and calculated εNd（t） are -4.6 and -3.2. Accurate age determinations of the mineralization demonstrate that the REE mineralization took place during early Mesoproterozoic. Together with other geological evidence from the ore deposit, the primary REE-bearing ore-forming fluids are suggested to have been derived from the Enriched Mantle, and the Yinachang Fe-Cu-REE ore deposit is of volcanic exhalation- hydrothermal sedimentary origin. This study also imply that the sudden large-scale REE mineralization in the Mesoproterozoic epoch may have been induced by alkaline-rich anorogenic magmatism which occurred at marginal rifts of the continent in the Mesoproterozoic.     

Nd isotope as the tracer of seawater evolution of early Miocene in the eastern Pacific Ocean

Fifty-six samples of nannofossil ooze were collected from Core PC5794 in the northern equatorial Pacific at 5 cm intervals. With the methods of mass spectrometer (VG354) and ICP, the Nd isotopic compositions (εNd(t)), Mn contents and Mg/Sr ratios of carbonate phase have been analyzed. CaCO3 contents of bulk sediments were obtained by dissolution of 0.5 mol/L HCl. Based on these data, the high-resolution εNd(t) profile of seawater in early Miocene with core depth(or time) have been established. The values of εNd(t) range from -6.2 to -2.97 and 4 fluctuation cycles existed during 24.06-22.02 Ma. 4 low εNd(t) values (about -6.4) correspond to high CaCO3 contents, which implicates that there were 4 cold epochs or 4 times of Antarctic Bottom Water activity. They occurred at the time of 24.06 Ma, 23.85 Ma,22.88 Ma and 22.26 Ma, respectively. High εNd(t) values correspond to the high Mn contents and high values of Mg/Sr ratio, which indicates the existence of 4 intense hydrothermal activity periods during 24.06-22 Ma, the durations of them are 4.05-23.98 Ma, 23.69-23.15 Ma, 22.74-22.37 Ma and 22.06-22.02 Ma, respectively.     

Multistage evolution of continental collision orogen: A case study for western Dabie orogen

The foramtion and evolution of collisional orogen is a prominent feature along convergent plate margins, and is generally a complex process. This article presents an integrated study of zircon genesis, U-Pb age and Lu-Hf isotope composition as well as geological characteristics for the western Dabie orogen to constrain its multi-stage evolution history. The results suggest that the formation of oceanic crust in the Huwan area was constrained at ca. 400--430 Ma, which was slightly later than the collision of the northern Qinling with the North China Block. It formed in a marginal basin in the northern margin of the Yangtze Block. The peak metamorphism of eclogite in the Huwan area occurred at ca. 310 Ma, and the timing of the initial exhumation of oceanic eclogite was about 270 Ma. The high to ultrahigh pressure （HP-UHP） metamorphic rocks in the Xinxian and the Hong＇an metamorphic zones have the same ages and natures as those of the HP-UHP metamorphic rocks in the other Dabie-Sulu terrains, and also have experienced multi-stage exhumation, and thus can be taken as a coherent part of the Dabie-Sulu orogen. Therefore, the Qinling-Dabie-Sulu orogen is a typical multi-stage continental collision orogen, with an amalgamation process extending more than 200 Ma.     

Chronological record of the Early Mesozoic underplating in the northern margin of North China—U-Pb chronometry of zircons in the Late Mesozoic andesite from Western Liaoning

Cathodoluminescence spectroscopic analysis of zircons in the uppermost sanukites of the early Cretaceous Yixian Forma- tion in Western Liaoning reveals zoning structures of the zircons in the volcanic rocks. LA-ICP-MS chronometry shows that the central part of the zircons is remnant zircon with a U-Pb dating of 254 Ma,which is consistent with the age of the Early Mesozoic underplating granulites,and that the periphery is zircon crystallizing out of the host magma with a U-Pb dating of 116 Ma,which is highly consistent with the Ar-Ar dating of the host volcanic rocks.Compositions of the clinopyroxenes xenocrystals in the sanukites are similar to those of the clinopyroxenes in the underplating granulites,indicating that the granulites accreted to the lower crust in the Early Mesozoic have been reformed and disrupted by the upwelling diapers of the asthenosphere and taken part in formation of the sanukites in the Late Mesozoic.     

Runoff sensitivity to climate changes in the Longitudinal Range-Gorge Region （LRGR）： An example of the Longchuan Basin in the Upper Yangtze

The sensitivity of runoff to the climate change in the Longitudinal Range-Gorge Region （LRGR） in southwest China was investigated with a case study in the Longchuan Basin of the upper Yangtze River, where the climate change is more complex due to the influences from both global warming and local topography. Non-updating artificial neural networks were calibrated and validated at the baseline condition and were used to predict the response of runoff under 25 hypothetical climate scenarios, which were generated by adjusting the baseline temperature by -1, 0, 1, 2 and 3℃ and by scaling rainfall by 0%, ± 10% and ± 20%, The results indicated that runoff is more sensitive to the increase in rainfall. The annual and seasonal runoff changes were determined by the interaction between temperature and rainfall. At seasonal scale, the direction of change in runoff is more determined by temperature in winter and spring; whereas it is more determined by rainfall in summer and autumn. The LRGR in southwest China may experience a higher frequency of floods in the wet season and more serious droughts in the dry season, if a wetter summer and warmer winter is the trend of future climate change, as predicted by many GCMs.     

Seasonal variations of dust record in the Muztagata ice cores

Based on the oxygen isotope ratio and microparticle record in ice cores recovered at Mt. Muztagata, Eastern Pamirs, the seasonal variations of atmospheric dust have been reconstructed for the past four decades. High dust concentrations and coarser particle grains have the similar trend with oxygen isotope value. Our statistical results indicate that 50%--60% high dust concentration samples occur during the season with high oxygen isotope values （summer）, while low dust storm frequency during spring and winter. Back-trajectory analysis shows that the air mass hitting Muztagata predominately came from West Asia （such as Iran-Afghanistan Plateau） and Central Asia, which are the main dust source area for Muztagata. Dust storms in those source areas most frequently occur during summer （from May to August）, while frequent dust storm events in northern China mainly occur during spring （March to May）. Regions in the path of Asian dust transport, such as in Japan, the North Pacific, and Greenland, also show high dust concentrations during spring （from March to May）. Our results indicate that dust storms have different seasonality in different regions within Asia.     

Decrease trend of dust event frequency over the past 200 years recorded in the Malan ice core from the northern Tibetan Plateau

By analyses of the dust layers in the Malan ice core from the northern Tibetan Plateau, it was found that dirty ratio in this core might be a good proxy for dust event frequency. The variations in the dirty ratio displayed a decrease trend over the past 200 years, which implies that dust events became less frequent during the study period. The decrease trend in the variations in dust event frequency might be caused mostly by the natural processes, including increasing precipitation and weakening westerly which might be related with global warming. Furthermore, significant negative correlation was found between the dirty ratio and δ^18O in the Malan ice core. This is highly important for studying the effect of atmospheric dust on climate change.     

“Climate effect” of the northeast cold vortex and its influences on Meiyu

The Northeast Cold Vortex (NECV) is an important weather system in the middle and high latitudes in East Asia. Its time scale is synoptic, yet the frequent activities of NECV have significant "climate effect" which influences not only the monthly temperature in the lower troposphere in Northeast China but also the Meiyu rainfall in East Asia. On the basis of ERA-40 reanalysis data provided by ECMWF, the "climate effect" of NECV and its relationship with Meiyu in East Asia are studied. It is shown that there is significant correlation between NECV during the Meiyu period and rainfall amount: strong NECV corresponds to more Meiyu rainfall and weak NECV corresponds to less rainfall. In strong NECV years, the dry and cold air from the north is led to the south by NECV, converges with the lower-level warm and wet southwesterly on the north verge of Meiyu region, thus forms an unstable stratification of "upper dryness and lower wetness" . Triggered by ascending motion, the Meiyu rainfall amount is more than usual. It is on the contrary in weak NECV years. The anomalous SST in north Pacific in the previ-ous year may be a factor that results in the anomalous NECV at Meiyu period. The land-sea thermal contrast in summer facilitates NECV, while that in winter inhibits NECV. All of the above provide a meaningful result for the short-term climate prediction of NECV and Meiyu.     

Petrogenesis of the Neoproterozoic bimodal volcanic rocks along the western margin of the Yangtze Block： New constraints from Hf isotopes and Fe/Mn ratios

High-precision major element and Hf isotope data are reported for the Neoproterozoic Suxiong volcanic rocks along the western margin of the Yangtze Block. These volcanic rocks have variable εHf（T） values and Fe/Mn ratios. The relatively primitive basalts have high Fe/Mn ratios and high Hf-Nd isotopic compositions, indicating that they were generated by partial melting of garnet clinopyroxene in mantle plume at high pressure. Thus, the Suxiong basalts are genetically related to the proposed Neoproterozoic superplume. On the contrary, a few differentiated basalts have low Fe/Mn ratios and low Hf-Nd isotopic compositions. They are likely to experience assimilation-fractional crystallization process. The Suxiong rhyolites have consistent Hf and Nd model ages of 1.3-1.4 Ga. They are likely generated by shallow dehydration melting of pre-existing young arc igneous rocks associated with the basaltic underplating/intrusion in a continental rift.