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1.
Both single-layer and double-layer organic light-emitting devices based on tris-(8-hydroxylquino- line)-aluminum (AIq3) as emitter are fabricated by thermal vacuum deposition. The electroluminescent characteristica of these devices at various temperatures are measured, and the temperature characteristics of device performance are studied. The effect of temperature on device current conduction regime is analyzed in detail. The results show that the current-voltage (I-V) characteristics of devices are in good agreement with the theoretical prediction of trapped charge limited current (TCLC). In addition, both the charge carrier mobility and charge carrier concentration in the organic layer increase with the rise of temperature, which results in the monotonous increase of AIq3 device current. The current conduction mechanisms of two devices at different temperatures are identical, but the exponent m in current-voltage equation changes randomly with temperature. The device luminance increases slightly and the efficiency decreases monotonously due to the aging of AIq3 luminescent properties caused by high temperature. A tiny blue shift can be observed in the electroluminescent (EL) spectra as the temperature increases, and the reduction of device monochromaticity is caused by the intrinsic characteristics of organic semiconductor energy levels.  相似文献   

2.
Investigations of crystal habit, micro-topographic imaging, micro-composition and micro-structural analysis of HPHT synthetic diamonds from the Fe-C(H) system indicate that most of them have an octahedral habit. The crystals grow mainly layer-to-layer from center to periphery. HPHT synthetic diamond is smaller in size than natural diamond because it only goes through nucleation and growth in the early stage. In the middle and late stages, due to the coalescence of diamond grains related to differences of surface energy, the growth of HPHT synthetic diamond is limited. The active energy (E) of transforming single nitrogen into a nitrogen-pair is lowered and the time of transforming single nitrogen into a nitrOgen-pair is shortened because of the existence of hydrogen. Therefore, aggregate nitrogen (A-centers) may exist in synthetic diamond from HPHT and explosive detonation processes. It needs further discussion on a worldwide view that the time of natural diamond formation extracted from nitrogen aggregation is some hundred million years. Consideration of the way in which surface energy influences the growth of diamond can help to understand some of the remaining issues (e.g. growth mechanism, etc.) in the HPHT synthetic process and effectively explain the formation of natural diamond in terms of HPHT thermodynamic theory. Especially, it is important to pay more attention to the influence of hydrogen on surface energy in that hydrogen may be a "bridge" for explaining the formation of HPHT synthetic and natural diamond.  相似文献   

3.
Study on the submerged fermentation (SMF) of termitomyces eurrhizus   总被引:1,自引:0,他引:1  
The influence of KH2PO4, peptone and brown sugar on Termitomyces fuliginosu’ s mycelium formation was studied with the application of the design of quadratic rotation general combination based on determining the growth curve. A quadratic regression model of biomass to the doses of the above three factors was established. The model fit well and therefore the optimum fermentation condition was obtained. Responses of biomass to the three single factors and to their interactions were discussed. Thus, the highest level of hiomass, 21.1 g/L, appeared under the optimized conditions when the initial KH2PO4, peptone and brown sugar were 1 g/L, 4 g/L and 72 g/L respectively.  相似文献   

4.
Poly(p-phenylene benzobisoxazole)(PBO) is a candidate of high performance materials for many applications. PBO materials' properties are considered to be closely related to their fabrication process, especially coagulation. In this paper, the coagulation effect on the chemical and microstructure of PBO was investigated with the help of a PBO model compound, 2, 2'-( 1,4-phenylene) bis (5-amino-6-benzoxazolole). During coagulation, the hetero-cyclic ring of the PBO structure was experienced cleavage and even being broken down completely under some extreme conditions. Wide-angle X-ray diffraction (WAXD) analysis showed that different coagulants could cause the microstructure difference in PBO materials. In a slow coagulation process, PBO molecular chains aligned more orderly in the side-by-side direction (200).  相似文献   

5.
An analysis is made to investigate the structure features of the extensive heavy rainfall left by typhoon Matsa, after its landfall in mainland China in August 2005, based on a range of observational results, including surface intensive observation data, TBB data from China's FY-2 satellite, and NCEP 1°×1° reanalysis data. The study tries to explore the interaction between atmospheric waves, 3-D atmospheric structures, and typhoon rainbands. Observational facts, diagnostic analysis, and atmospheric wave theory are used to look into the formation mechanism of distant typhoon rainbands. Results show that (1) Matsa rainbands have the features of noticeable wave train distribution and long distance propaga-tion; (2) the typhoon rainbands extend as far as 2000 km northwardly from the typhoon center, with a wavelength of 500―1000 km and a wave period of 12―24 h; (3) the wave structure of Matsa rainbands is closely associated with the corresponding wave variation of the ambient 3-D atmospheric structures, including disturbance vorticity, divergence field, vertical motion field, water vapor flux divergence field, etc. (4) both observational facts and theoretical analysis show that the northward extending typhoon rainbands are associated with the mixed effects of atmospheric inertia wave and internal gravity wave; (5) only under proper atmospheric stratification and vertical wavenumber of gravity wave, can a ty-phoon stimulate such a wave being able to reach such a distance, and result in extending wavy rain-bands.  相似文献   

6.
Polyamide could not only combine with DNA out- side but also inhibit expressing of gene[1]. At the same time, polyamide could coordinate many molecules. Ren et al.[2] found that [MgⅡ(dien)(OH)] can cleave pBR322DNA effectively in 2004. Liu et al.[3,4] f…  相似文献   

7.
In the past decades, more and more studies have been focused on the synthesis of monodisperse particles with different diameter by special polymerization technique. In 1980' s, Ugelstad, et al invented two-step swelling method to prepare monodisperse microsphere with large size more than 1μm. In the following decade, Okubo and his coworkers synthesized monodisperse crosslinked polymer particles above 3μm using one-step dynamic swelling method. New method has been developed to produce particles more than 50 gm in diameter with a standard deviation of less than 2 % . Up to now, most of the monodisperse particles were usually prepared by polymerization of St in the presence of surfactants. In this presentation, sub-micro sized P (MMA-EA-AA/MAA) particles with narrow size distribution were prepared by seeded emulsion polymerization in the absence of any surfactant materials.  相似文献   

8.
Seventeen disperse dyes including anthraquinone, azo, methine, nitro, and quinoline dyes were applied to dye the Polylactic Acid (PLA) yarns at different conditions, and the dyebath exhaustion was determined. The result shows that C.I. disperse red 167, C.I. disperse orange 30, and C.I. disperse blue 284 have dye-uptakes greater than 80%. Therefore, they can be used as the three principal dyes for PLA yams. The experiment discovered that the dyes, because of their Monoazo and ester group contents, have a higher dye-uptake for the PLA fiber. The research on the optimization of dyeing techniques suggests that PLA yarn can obtain a high level of dyeing effectiveness at the following conditions: pH 4- 5, dyeing temperture 110℃ for 30- 40 min. Color fastness to perspiration, and waterwashing fastness increased 1 - 1.5 by the addition of the abstergent FB during the reduction clearing.  相似文献   

9.
1IntroductionWhen used in the reaction system,airlift loopreactors(ALRs)have the characteristics of highmass transfer coefficient,good mixingperformance,low flow sheer stress and energysaving,and thus enjoy a broad prospect ofapplication.In additionto tra…  相似文献   

10.
The promoting effect of ultrasonic wave on the hydrodynamics and mass transfer characteristics of the airlift loop reactor was studied.The effect of the airlift reactor and ultrasonic wave on the reactor’s gas holdup,liquid circulation velocity,mixing time and overall volumetric mass transfer coefficient respectively with and without the presence of ultrasonic wave is empathetically examined and compared.The experiment has proven that the incorporation of ultrasonic wave has no effect on the gas holdup but has the tendency to gradually decrease the liquid circulation velocity and increase the overall volumetric mass transfer coefficient; the effect on the mixing time is relatively complex.At low gas velocity,low powered ultrasonic wave promotes the radial mixing of fluid;with the increase of ultrasonic power,ultrasonic vibration obstructs the radial mixing of fluid.Therefore,there exists an optimal ultrasonic power.Moreover,the effect of ultrasonic wave on the mixing time gradually decreases with the increase of the superficial gas velocity.Correlations were also proposed for the hydrodynamics and mass transfer characteristics of the reactor.  相似文献   

11.
褐藻及褐藻酸的研究现状和进展   总被引:1,自引:0,他引:1  
褐藻及从褐藻中分离出的一种重要化合物——褐藻酸具有广泛的应用价值。对褐藻的生物性状、地域分布及其产品褐藻酸的种类、地域分布、化学结构、理化性质、生产工艺及应用作一全面的阐述。  相似文献   

12.
从分子遗传学角度对采自陕西省黄龙县和河北小五台山两个地区的褐马鸡种群进行了研究,完成了上述两个地区褐马鸡线粒体控制区的全序列测序,并与GenBank中搜索的马鸡属的其它三个种的同源序列进行比对分析.综合考虑该区域的地质历史背景和本研究得到的上述两地区褐马鸡与蓝马鸡的遗传距离分析,研究认为由于0.15 MaBP黄河切穿三门峡后东流入海以及历史上的人类活动,导致原来连续的褐马鸡分布区域分隔,并逐渐分化成不同的地理种群.研究还指出褐马鸡种群内遗传多样性极低,并建议褐马鸡和蓝马鸡应为同种不同色型.  相似文献   

13.
针对川中丘陵区成昆铁路的典型道路边坡,以临近茶树区和自然边坡为对照,对道路边坡不同坡位的土壤藻类动态变化及茶树区和自然边坡土壤藻类的差异性进行了研究.结果表明:道路边坡不同坡位土壤藻类含量的变化表现为坡下>坡中>坡上>茶树区,自然边坡不同坡位土壤藻类含量的变化表现为坡下>坡中>坡上>茶树区.道路边坡坡下、坡中、坡上的土壤藻类含量分别是茶树区土壤藻类含量的2.18倍、2.16倍、1.48倍.道路边坡不同坡位土壤藻类含量均表现为,从1月到7月不断增大,并且在7月达到最大值,从7月到10月,土壤藻类含量开始降低.土壤有机质含量表现为自然边坡>茶树区>道路边坡.  相似文献   

14.
南海碳的生物地球化学研究进展   总被引:6,自引:0,他引:6  
简述南海碳的生物地球化学的研究进展,重点介绍国家杰出青年基金课题“南海碳的生物地球化学循环研究-胶体的显著作用”的研究内容,报道了近年来我们在该领域的最新阶段性研究成果。  相似文献   

15.
16.
The effect of treating algae-bearing water and induced odor by use of permanganate potassium composite (PPC) pre-oxidation was investigated, and was compared with the effect of treatments by pre-chlorination, permanganate petassium pre-oxidation and simple coagulation. The results showed that simple coagulation and pre-chlorination were less effective in removing algae and its odor, whereas PPC pre-oxidation was the most effective in algae removal and deodorization. Upon oxidation with PPC, the cells of Oscillatoria agardhic were inactivated and some intra-cellular and extra-cellular components were released into the water, which may help the coagulation by their bridging effect. The efficient removal of algae by PPC pre-oxidation is believed to be the joint contribution of several mechanisms.  相似文献   

17.
沸石与聚合氯化铝复合处理水源水中藻类的研究   总被引:1,自引:0,他引:1  
对富营养化水源水的强化混凝技术进行研究,系统地对沸石与聚合氯化铝复配强化混凝除藻的工艺参数进行了探讨。研究结果表明,当聚合氯化铝与沸石的加入量均为40mg/L时,除藻效果最好,浊度、叶绿素a和高锰酸盐指数去除率分别为94.7%、69.1%和59.9%,絮体体积压缩达50%。  相似文献   

18.
竹锈褐斑病由螨类为害引起,笔者于2008年3月至2009年12月对南京地区竹锈褐斑病发生状况进行了调查。结果表明:该病主要危害3个属共12种竹种,病害的发生与竹林地被物、竹种生长状况、竹种和竹林环境状况有密切关系。7月上中旬发病达到高峰,7月下旬至8月上旬螨类种群数量下降;8至9月气温仍然较高,同时降雨量减少,虫口数量有所回升。螨类1年发生多代,世代重叠严重。  相似文献   

19.
铁盐类混凝剂去除水中藻类生物的研究   总被引:2,自引:1,他引:2  
通过用自制聚硅硫酸铁、聚硅氯化铁、聚合氯化铁铝等高效混凝剂对武汉三个典型湖水进行了混凝除藻实验,发现聚合氯化铁铝除藻效果最好,其中叶绿素浓度为200--300μg/L的湖泊水去除率可达99.8%,加入助凝剂和氧化剂后,去除率明显提高。还对其进行了后续过滤实验。  相似文献   

20.
通过对广西百色盆地洲景矿4煤层褐煤(R_O=0.36%-0.40%),包括伴生泥岩中的树脂体详细的荧光岩石学和有机地球化学研究,和与其他地区大致同时代同煤阶树脂体的对比结果表明:4煤层属腐殖型的富油褐煤、好的烃源岩。丰富的树脂体是成烃的主要母质,渗出沥青体的存在是树脂体类有机物在未成熟阶段生烃和排烃的证据。  相似文献   

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