具有良好可再生性的新型二氧化硅磁性氧化石墨烯纳米复合材料

Graphene oxide (GO) wrapped Fe₃O₄ nanoparticles (NPs) were prepared by coating the Fe₃O₄ NPs with a SiO₂ layer, and then modifying by amino groups, which interact with the GO nanosheets to form covalent bonding. The SiO₂ coating layer plays a key role in integrating the magnetic nanoparticles with the GO nanosheets. The effect of the amount of SiO₂ on the morphology, structure, adsorption, and regenerability of the composites was studied in detail. An appropriate SiO₂ layer can effectively induce the GO nanosheets to completely wrap the Fe₃O₄ NPs, forming a core-shell Fe₃O₄@SiO₂@GO composite where Fe₃O₄@SiO₂ NPs are firmly encapsulated by GO nanosheets. The optimized Fe₃O₄@SiO₂@GO sample exhibits a high saturated adsorption capacity of 253 mg·g?1 Pb(II) cations from wastewater, and the adsorption process is well fitted by Langmuir adsorption model. Notably, the composite displays excellent regeneration, maintaining a ~90% adsorption capacity for five cycles, while other samples decrease their adsorption capacity rapidly. This work provides a theoretical guidance to improve the regeneration of the GO-based adsorbents.     

烧结铁矿中FeO含量对其在富氢高炉中还原行为的影响

Japan started the national project “COURSE 50” for CO₂ reduction in the 2000s. This project aimed to establish novel technologies to reduce CO₂ emissions with partially utilization of hydrogen in blast furnace-based ironmaking by 30% by around 2030 and use it for practical applications by 2050. The idea is that instead of coke, hydrogen is used as the reducing agent, leading to lower fossil fuel consumption in the process. It has been reported that the reduction behavior of hematite, magnetite, calcium ferrite, and slag in the sinter is different, and it is also considerably influenced by the sinter morphology. This study aimed to investigate the reduction behavior of sinters in hydrogen enriched blast furnace with different mineral morphologies in CO–CO₂–H₂ mixed gas. As an experimental sample, two sinter samples with significantly different hematite and magnetite ratios were prepared to compare their reduction behaviors. The reduction of wustite to iron was carried out at 1000, 900, and 800°C in a CO–CO₂–H₂ atmosphere for the mineral morphology-controlled sinter, and the following findings were obtained. The reduction rate of smaller amount of FeO led to faster increase of the reduction rate curve at the initial stage of reduction. Macro-observations of reduced samples showed that the reaction proceeded from the outer periphery of the sample toward the inside, and a reaction interface was observed where reduced iron and wustite coexisted. Micro-observations revealed three layers, namely, wustite single phase in the center zone of the sample, iron single phase in the outer periphery zone of the sample, and iron oxide-derived wustite FeO and iron, or calcium ferrite-derived wustite 'FeO' and iron in the reaction interface zone. A two-interface unreacted core model was successfully applied for the kinetic analysis of the reduction reaction, and obtained temperature dependent expressions of the chemical reaction coefficients from each mineral phases.     

微生物浸矿技术在我国的研究现状及发展前景

As the world’s second largest economy experiencing rapid economic growth, China has a huge demand for metals and energy. In recent years, China ranks first, among all the countries in the world, in the production and consumption of several metals such as copper, gold, and rare earth elements. Bioleaching, which is an approach for mining low grade and refractory ores, has been applied in industrial production, and bioleaching has made great contributions to the development of the Chinese mining industry. The exploration and application of bioleaching in China are reviewed in this study. Production and consumption trends of several metals in China over the past decade are reviewed. Technological processes at key bioleaching operations in China, such as at the Zijinshan Copper Mine and Mianhuakeng Uranium Mine, are presented. Also, the current challenges faced by bioleaching operations in China are introduced. Moreover, prospects such as efficiency improvement and environmental protection are proposed based on the current situation in the Chinese bioleaching industry.     

不同结构和形态的天然镁硅酸盐:与K反应制备生物柴油的K2MgSiO4催化剂

In this work, different magnesium silicate mineral samples based on antigorite, lizardite, chrysotile (which have the same general formula Mg₃Si₂O₅(OH)₄), and talc (Mg₃Si₄O₁₀(OH)₂) were reacted with KOH to prepare catalysts for biodiesel production. Simple impregnation with 20wt% K and treatment at 700–900°C led to a solid-state reaction to mainly form the K₂MgSiO₄ phase in all samples. These results indicate that the K ion can diffuse into the different Mg silicate structures and textures, likely through intercalation in the interlayer space of the different mineral samples followed by dehydroxylation and K₂MgSiO₄ formation. All the materials showed catalytic activity for the transesterification of soybean oil (1:6 of oil : methanol molar ratio, 5wt% of catalyst, 60°C). However, the best results were obtained for the antigorite and chrysotile precursors, which are discussed in terms of mineral structure and the more efficient formation of the active phase K₂MgSiO₄.     

Mg和La对Ca–Ti 处理钢中夹杂物演变和组织的影响

The evolution of inclusions and the formation of acicular ferrite (AF) in Ca–Ti treated steel was systematically investigated after Mg and La addition. The inclusions in the molten steel were Ca–Al–O, Ca–Al–Mg–O, and La–Mg–Ca–Al–O after Ca, Mg, and La addition, respectively. The type of oxide inclusion in the final quenched samples was the same as that in the molten steel. However, unlike those in molten steel, the inclusions were Ca–Al–Ti–O + MnS, Ca–Mg–Al–Ti–O + MnS, and La–Ca–Mg–Al–Ti–O + MnS in Mg-free, Mg-containing, and La-containing samples, respectively. The inclusions distributed dispersedly in the La-containing sample. In addition, the average size of the inclusions in the La-containing sample was the smallest, while the number density of inclusions was the highest. The size of effective inclusions (nucleus of AF formation) was mainly in the range of 1–3 μm. In addition, the content of ferrite side plates (FSP) decreased, while the percentage of AF increased by 16.2% due to the increase in the number of effective inclusions in the La-containing sample in this study.     

微波预处理对复杂铜矿磨矿及浮选动力学的影响

The effect of CaCO₃, Na₂CO₃, and CaF₂ on the reduction roasting and magnetic separation of high-phosphorus iron ore containing phosphorus in the form of Fe₃PO₇ and apatite was investigated. The results revealed that Na₂CO₃ had the most significant effect on iron recovery and dephosphorization, followed by CaCO₃, the effect of CaF₂ was negligible. The mechanisms of CaCO₃, Na₂CO₃, and CaF₂ were investigated using X-ray diffraction (XRD), scanning electron microscopy and energy dispersive spectrometry (SEM–EDS). Without additives, Fe₃PO₇ was reduced to elemental phosphorus and formed an iron–phosphorus alloy with metallic iron. The addition of CaCO₃ reacted with Fe₃PO₇ to generate an enormous amount of Ca₃(PO₄)₂ and promoted the reduction of iron oxides. However, the growth of iron particles was inhibited. With the addition of Na₂CO₃, the phosphorus in Fe₃PO₇ migrated to nepheline and Na₂CO₃ improved the reduction of iron oxides and growth of iron particles. Therefore, the recovery of iron and the separation of iron and phosphorus were the best. In contrast, CaF₂ reacted with Fe₃PO₇ to form fine Ca₃(PO₄)₂ particles scattered around the iron particles, making the separation of iron and phosphorus difficult.     

不同硅饱和系数水榴石的碳酸化分解动力学

Carbonated decomposition of hydrogarnet is one of the vital reactions of the calcification–carbonation method, which is designed to dispose of low-grade bauxite and Bayer red mud and is a novel eco-friendly method. In this study, the effect of the silica saturation coefficient (x) on the carbonation of hydrogarnet was investigated from the kinetic perspective. The results indicated that the carbonation of hydrogarnets with different x values (x = 0.27, 0.36, 0.70, and 0.73) underwent two stages with significantly different rates, and the kinetic mechanisms of the two stages can be described by the kinetic functions R3 and D3. The apparent activation energies at Stages 1 and 2 were 41.96–81.64 and 14.80–34.84 kJ/mol, respectively. Moreover, the corresponding limiting steps of the two stages were interfacial chemical reaction and diffusion.     

一种超重力燃烧合成制备高性能高熵合金的新方法

A new method of high-gravity combustion synthesis (HGCS) followed by post-treatment (PT) is reported for preparing high-performance high-entropy alloys (HEAs), Cr_0.9FeNi_2.5V_0.2Al_0.5 alloy, whereby cheap thermite powder is used as the raw material. In this process, the HEA melt and the ceramic melt are rapidly formed by a strong exothermic combustion synthesis reaction and completely separated under a high-gravity field. Then, the master alloy is obtained after cooling. Subsequently, the master alloy is sequentially subjected to conventional vacuum arc melting (VAM), homogenization treatment, cold rolling, and annealing treatment to realize a tensile strength, yield strength, and elongation of 1250 MPa, 1075 MPa, and 2.9%, respectively. The present method is increasingly attractive due to its low cost of raw materials and the intermediate product obtained without high-temperature heating. Based on the calculation of phase separation kinetics in the high-temperature melt, it is expected that the final alloys with high performance can be prepared directly across master alloys with higher high-gravity coefficients.     

窄板坯结晶器内连铸工艺参数对钢液流场的影响

Computational simulations and high-temperature measurements of velocities near the surface of a mold were carried out by using the rod deflection method to study the effects of various operating parameters on the flow field in slab continuous casting (CC) molds with narrow widths for the production of automobile exposed panels. Reasonable agreement between the calculated results and measured subsurface velocities of liquid steel was obtained under different operating parameters of the CC process. The simulation results reveal that the flow field in the horizontal plane located 50 mm from the meniscus can be used as the characteristic flow field to optimize the flow field of molten steel in the mold. Increases in casting speed can increase the subsurface velocity of molten steel and shift the position of the vortex core downward in the downward circulation zone. The flow field of liquid steel in a 1040 mm-wide slab CC mold can be improved by an Ar gas flow rate of 7 L·min?1 and casting speed of 1.7 m·min?1. Under the present experimental conditions, the double-roll flow pattern is generally stable at a submerged entry nozzle immersion depth of 170 mm.     

浅析下湾金矿床成矿地质条件与矿床成因

以区域地质背景、地球物理特征、地球化学特征及矿体地质特征为基础,讨论了下湾金矿的成矿地质条件,认为矿床为变质-热液金矿床.     

重质油藏的经营管理

主要介绍在重质油藏的经营管理中提高采收率的技术方法和应用,探讨包括总体优化设计在内的油藏管理目标,并阐明多学科协作对油藏管理的有利影响。重点论述:(1)油藏管理学对于改善重质油藏项目的作用;(2)水—汽交替注入工艺(WASP)技术的应用;(3)热量调控中热量的模化。文章还通过实例研究讨论了在实际重质油藏中借助有效的油藏管理技术提高热效值的情况,并介绍了光纤传感器用于井下测温度和压力、4D地震以及蒸汽辅助重力驱(SAGD)等新技术。     

存款保险制度的缺陷与国外实践

指出了存款保险制度的缺陷,阐述了为解决存款保险制度的缺陷国际货币基金组织的指导原则,列举了解决存款保险制度缺陷的实践。     

云南省楚雄八角锌矿床地质特征及矿床成因

云南省楚雄八角锌矿床位于祥云—新平多金属成矿带中南段。通过对楚雄八角锌矿床地质特征的阐述,指出矿体明显受地层岩性和构造的联合控制,矿床成因为构造及地层控制的地下水中~低温热液矿床,并总结了控矿因素和找矿标志。     

乐家湾锑矿床矿化蚀变作用及矿床成因

乐家湾锑太和是粤北锑矿带上的典型矿床。围岩蚀变具有很好的分带性，从矿体向围岩依次为锑矿化带、硅化蚀变带和黄铁矿化蚀变带，蚀变前后每１００ｃｍ＾３中的组分置换可达２０３．３８ｇ。通过成矿作用过程、稳定同位素和包裹体的研究分析，作者认为乐家湾锑矿床属层控－低温热液叠加成因。     

浅议存款保险制度

阐述了存款保险制度的内涵及其发展,分析了在我国建立显性存款保险制度的意义,给出了我国存款保险制度的框架。     

浅析初裕沟铁矿床成矿地质条件与矿床成因

以区域地质背景、地球物理特征、矿区地质特征及矿体地质特征为基础,讨论了初裕沟铁矿床的成矿地质条件,认为该矿床为沉积变质铁矿床。     

存款保险制度的效应分析及框架构想

存款保险制度的建立是我国利率市场化改革的前提.它是应对金融恐慌的制度安排,也是解决金融机构市场退出的重要途径.存款保险制度不仅保护存款人利益,而且也是防范和化解金融风险的重要工具.以存款保险制度为研究对象,在分析存款保险制度的正面效应和负面效应的基础上,提出了建立适合我国国情的存款保险制度框架的具体构想.     

建立我国存款保险制度初探

采用比较、实证分析、经济分析等方法,从存款保险制度的基本概念出发,通过对存款保险制度的基础及功能的阐述,结合当前我国金融待业风险状况,论证了我国建立存款保险制度的必要性.对于如何建立符合中国实际的存款保险制度提出了建议.     

复杂多层薄矿体矿床模型的建立

本文开发了建立复杂多层薄矿体矿床模型的计算机程序,并用该程序建立了构造极复杂多变的我国最大型露天锰矿山的矿床模型,取得了满意的效果。