^110Pd核的正宇称态和电磁跃迁

本采用相互作用玻色子模型研究了＾１１０Ｐｄ核的低能激发态的能普和电磁跃迁，应用简化的哈密顿量很好的描述它们的能谱和跃迁过渡。结果表明，＾１１０Ｐｄ基本上是属于Ｕ（５）→Ｏ（６）动力学对称的过渡核，同时也发现它具有ＳＵ（３）对称性的明显特征。     

等效三体势对偶偶Ba与Xe同位素核的负宇称带的能谱研究

在s-d IBM1的O(6)极限下,引入d玻色子之间相互作用的等效三体势,考虑f玻色子产生的八极态,导出了负宇称态能谱解析表达式,并对过渡区^{118, 120}Xe和^{124, 126, 128, 130}Ba 6个偶偶核的负宇称带进行了能谱计算,得到了与实验能谱符合很好的结果,然后用Staggering指数定量分析了负宇称态能谱中的Staggering现象。     

一种D-π-D-π-A结构化合物的合成表征及光学性质

报道一种新型的D-π-D-π-A结构的化合物:3-(4-溴苯乙烯基)-6-[(4-乙烯基吡啶)苯乙烯基]-N-乙基咔唑的合成.采用红外光谱、核磁共振谱、质谱和元素分析对目标化合物的结构进行了表征.测试了其紫外吸收光谱、单光子荧光光谱、单光子荧光寿命以及双光子荧光光谱.研究表明,目标化合物具有好的单光子荧光性质和强的双光子吸收效应.     

羟基吡啶酮衍生物结构特征的研究

报道了 ７个６－羟基－２－吡啶酮衍生物在溶液中的 １Ｈ－．１３Ｃ－ＮＭＲ波谱和固态的红外光谱数据．实验表明，在常温和酸性介质中井不能使它们以 ６－酮基－２－吡啶酮的结构存在．解释了红外光谱中１８８６—１６３０ ｃｍ－１范围内某些化合物的两条羰基谱带．根据波谱数据，提出了这类化合物在酸性、中性和碱性条件下可能存在的结构形式．     

基于SET/MOS混合结构的奇偶校验码产生电路的设计

基于单电子晶体管(SET)的库仑振荡效应和多栅输入特性,利用SET和金属氧化物半导体场效应晶体管(MOS管)的互补特性,设计了基于SET/MOS混合电路的奇偶校验码产生电路.利用HSPICE对所设计电路进行仿真验证,结果表明,该电路能够实现产生奇偶校验码的功能.该SET/MOS混合电路的实现只需要1个PMOS管、1个N...     

Goppa码一致校验位数目的下限

给定一个Ｇｏｐｐａ码，如何求出它的一致校验位数目问题，至今尚未解决。估计一致校验位数目，一般只用上限来估计．本文提出了不仅可用上限也可用下限来估计一致校验位数目的观点，并且给出了估计方法。用这种方法，某些特殊的Ｇｏｐｐａ码是能够求出它的一致校验位数目的。     

含双负介质一维光子晶体的量子阱结构研究

采用传输矩阵法研究一维光子晶体(AB)m(ACABACA)n(BA)m的透射谱,结果发现:无论C层为双正介质还是含双负介质,在归一化频率1.0ω/ω0处均构成对称分布的光子晶体量子阱结构,并在光量子阱透射谱的相应频率位置出现对称分布的共振透射峰,呈现明显的量子化效应.当C层为双正介质时,透射峰数目等于n+1且位置可调;当C层为双负介质时,出现数目与n的奇偶性相关的透射峰.     

Turbo码在DS／CDMA系统中的应用

基于多用户检测原理,针对传统的Turbo码通过信道信息来获得信息住的信息,修正了带校验位的并行级联Turbo码的BCJR算法,通过多用户提供的先验信息来获得信息位和校验位的信息,使其能和低复杂度的多用户检测器匹配,从而进行信息迭代,达到了消除多用户干扰的目的。     

Change in aggregation state of a porphyrin-perylene-diimide dyad induced by trifluoroacetic acid

The molecular aggregation state of a porphyrin-perylenediimide dyad can be changed by treating with trifluoroacetic acid. Transmittance electron microscopy （TEM） images revealed that lamella microstructures were formed when the dyad precipitated from neutral solvent, but spherical nano-particles were obtained when precipitating from acidic solution. X-ray diffraction patterns showed that the lamella microstructures and the nanoparticles were polycrystalline and amorphous solids, respectively. By using rational perylenediimide and porphyrin as reference compounds, careful analyses on the UV-visible spectra of the dyad and the references under different conditions were conducted and the results demonstrated that both the porphyrin and perylendiimide subunits of the dyad took J-aggregation in neutral solvent, but after being treated with trifluoroacetic acid and chloroform solution, the perylenediimide subunit changed to an H-aggregation while the porphyrin subunits changed to a random packing mode.     

沃尔什—哈达玛变换(WHT)系数偶数性的理论、应用与实现

本文对文[1]提出的一维WHT(A=Hx)系数的奇偶性给出了十分简扼的证明,并提出A系数的奇偶性与sum from j-1 to N Xj的奇偶性相同;二维WHT(A=H_1XH_2)的系数也具有奇偶性、且与sum from νj-1 to N_1·N_2 Xij的奇偶性相同的结论。进而,文章着重导出了量化数据的一维以及二维WHT的系数可全认做偶数的重要结论。文章指出,变换系数的偶数性,仅为WHT所独有,这进一步提高了WHT的数据压缩率,使得WHT成为更加有效可行的数据压缩手段。     

基于时间冗余的一致空间法在故障检测及隔离中的应用

研究基于时间冗余的一致空间法在线性时不变系统故障检测及隔离中的应用.指出系统在某一时刻某个故障在一致空间中位于固定方向.通过选取最优转换矩阵,将这一方向与其它因素在一致空间中所在方向相分离,提出一种故障隔离的方法.仿真实验表明,在传感器、执行器和元件均可能发生故障并且系统存在未知输入的情况下可实现故障检测及隔离.     

N,N-二甲基苯甲醛连氮及其Cu(I)配合物的合成与表征

设计合成了一种新的连氮类D-π-D型化合物N,N-二甲基苯甲醛连氮(L1),制备了其双核Cu(I)的配合物,分别用元素分析、红外光谱、核磁共振、电子自旋共振波谱、质谱及电喷雾质谱等进行了表征,并对它们的荧光性质进行了初步研究。     

Production and detection of cold antihydrogen atoms

A theoretical underpinning of the standard model of fundamental particles and interactions is CPT invariance, which requires that the laws of physics be invariant under the combined discrete operations of charge conjugation, parity and time reversal. Antimatter, the existence of which was predicted by Dirac, can be used to test the CPT theorem-experimental investigations involving comparisons of particles with antiparticles are numerous. Cold atoms and anti-atoms, such as hydrogen and antihydrogen, could form the basis of a new precise test, as CPT invariance implies that they must have the same spectrum. Observations of antihydrogen in small quantities and at high energies have been reported at the European Organization for Nuclear Research (CERN) and at Fermilab, but these experiments were not suited to precision comparison measurements. Here we demonstrate the production of antihydrogen atoms at very low energy by mixing trapped antiprotons and positrons in a cryogenic environment. The neutral anti-atoms have been detected directly when they escape the trap and annihilate, producing a characteristic signature in an imaging particle detector.     

SDS和PCN与胶束中NRa的相互作用

检测体系的紫外可见光谱、荧光光谱、表面张力、电导率等,研究了十二烷基硫酸钠(SDS)和盐酸普鲁卡因(PCN)与酸性形态中性红(NRa)的相互作用.中性红能降低SDS的临界胶束浓度.在SDS稀溶液中,表面活性剂分子能减弱NRa紫外吸收光谱及荧光发射光谱的强度.随着SDS溶液浓度的增大,NRa的光谱强度增大.NRa吸附于球状胶束表面,定位于棒状胶束膜相较深处.在SDS胶束体系中,随着PCN的加入,NRa的紫外可见光谱、荧光光谱强度减弱.     

Domination of heliosheath pressure by shock-accelerated pickup ions from observations of neutral atoms

The solar wind blows an immense magnetic bubble, the heliosphere, in the local interstellar medium (mostly neutral gas) flowing by the Sun. Recent measurements by Voyager 2 across the termination shock, where the solar wind is slowed to subsonic speeds before entering the heliosheath, found that the shocked solar wind plasma contains only approximately 20 per cent of the energy released by the termination shock, whereas energetic particles above approximately 28 keV contain only approximately 10 per cent; approximately 70 per cent of the energy is unaccounted for, leading to speculation that the unmeasured pickup ions or energetic particles below 28 keV contain the missing energy. Here we report the detection and mapping of heliosheath energetic ( approximately 4-20 keV) neutral atoms produced by charge exchange of suprathermal ions with interstellar neutral atoms. The energetic neutral atoms come from a source approximately 60 degrees wide in longitude straddling the direction of the local interstellar medium. Their energy spectra resemble those of solar wind pickup ions, but with a knee at approximately 11 keV instead of approximately 4 keV, indicating that their parent ions are pickup ions energized by the termination shock. These termination-shock-energized pickup ions contain the missing approximately 70 per cent of the energy dissipated in the termination shock, and they dominate the pressure in the heliosheath.     

Fibrinogen Structural Changes Caused by Glass Surface Adsorption Detected by Solid Surface Fluorescence Spectroscopy

ＦｉｂｒｉｎｏｇｅｎＳｔｒｕｃｔｕｒａｌＣｈａｎｇｅｓＣａｕｓｅｄｂｙＧｌａｓｓＳｕｒｆａｃｅＡｄｓｏｒｐｔｉｏｎＤｅｔｅｃｔｅｄｂｙＳｏｌｉｄＳｕｒｆａｃｅＦｌｕｏｒｅｓｃｅｎｃｅＳｐｅｃｔｒｏｓｃｏｐｙ＊ＧｏｎｇＹａｎｄａｏ（公衍道），ＤｉｎｇＸ...     

Formation, structure and properties of GeCn± and Ge2Cn± binary clusters

The binary cluster ions Ge₂C_n⁺/Ge₂C_n^- and GeC_n⁺ have been produced by laser ablation. The parity effect is present in the negative ions Ge₂C_n^-, though it is not very prominent. While the experiments tell that the parity effect is totally not shown in the positive ions Ge₂C_n⁺. An extensive theoretical investigation on GeCn/GeC_n⁺/GeC_n^-(n=1-10) and Ge₂Cn/Ge₂C_n⁺/Ge₂C_n^-(n=1-9) has been carried out by density functional theory at B3LPY level. The calculation shows that the low-lying states of GeC_n/GeC_n⁺/GeC_n^-(n=1-10) and Ge₂C_n/Ge₂C_n⁺/Ge₂C_n^-(n=1-9) are linear structure with germanium atoms locating at terminals respectively. The electronic distributions, ionization potential (IP_ad), elec-tron affinity (EA) and increasing bonding energy reveal that the parity effect of neutral species is much stronger than that of ions, which is attributed to the valence π-electrons. It is explained that the differences between experiments and cal-culations are due to the kinetic factor in the formation of Ge₂C_n^±.     

铽离子在氯磷酸锶镧中的发光和铈对它的敏化发光

本文报道了Tb~(3+)在氯磷酸锶镧中的发光性质、浓度猝灭和Ce~(3+)对Tb~(3+)的敏化发光。实验表明在该基质中Ce~(3+)对Tb~(3+)有良好的敏化作用。文中探讨了Ce~(3+)→Tb~(3+)的能量传递机理,证明为偶极子-偶极子相互作用的共振能量传递。     

用于LDPC编码调制系统的非规则映射技术

为使迭代解映射和译码的低密度奇偶校验(LDPC)编码调制系统获得逼近信道容量的优异性能,该文提出一种基于映射方式搜索的非规则映射技术,采用自适应二元交换算法(ABSA)搜索得到新映射方式,与Gray映射混合得到与信道编码接近最优匹配的非规则映射。对于DVB-T2标准规范的LDPC编码调制系统,在对其方案进行微小修改的前提下,该技术可对迭代解映射系统进行改进,挖掘出可观的迭代增益。以DVB-T2标准64800码长2/3码率的LDPC码和64QAM星座图为例,外信息传递(EXIT)图分析表明:该技术在加性白Gauss噪声(AWGN)信道下理论上可获得0.55dB的信噪比(SNR)增益;误码性能仿真表明:在误码率(BER)10-5时,该技术在AWGN和Rayleigh衰落信道下可分别获得0.30dB和0.26dB的增益。     

A Fault Detection and Isolation Scheme Based on Parity Space Method for Discrete Time-delay System

A Fault detection and isolation （FDI） scheme for discrete time-delay system is proposed in this paper, which can not only detect but also isolate the faults. A time delay operator ↓△ is introduced to resolve the problem brought by the time-delay system. The design and computation for the FDI system is carried by computer math tool Maple, which can easily deal with the symbolic computation. Residuals in the form of parity space can be deduced from the recursion of the system equations. Further more, a generalized residual set is created using the freedom of the parity space redundancy. Thus, both fault detection and fault isolation have been accomplished. The proposed method has been verified by a numerical example.