尖晶石及含钛尖晶石的添加对MgO质材料性能的影响

以电熔氧化镁、电熔镁铝尖晶石和电熔含钛尖晶石为原料,分别在镁质材料中添加15％电熔镁铝尖晶石和电熔含钛尖晶石,研究了两种不同类型的尖晶石的加入对镁质材料性能的影响。结果表明：在MgO质材料中分别加入15％的镁铝尖晶石和含钛尖晶石后,试样的烧结性能和抗渣渗透性提高,而试样的冷态抗折强度和抗渣侵蚀性能变差。且在镁质材料中加入含钛尖晶石后材料的各项性能高于加入镬铝尖晶石后的各项性能。     

低碳镁碳砖的研究现状与发展

综述近年来国内外低碳镁碳质耐火材料的研究与发展状况,提出镁碳质耐火材料低碳化以后所需要解决的关键问题以及目前解决这些问题所采取的主要对策,并指出了今后在低碳质耐火材料的开发研究过程中应重视的几个关键的科学与技术问题.     

镁碳砖的研究现状与发展趋势

综述了近年来国内外镁碳质耐火材料的发展和研究现状,尤其对镁碳砖防氧化剂和镁碳砖低碳化等方面的研究与发展状况进行了分析和汇总.在此基础上提出了镁碳砖未来的研究方向,即通过成分优化和结构设计,提升和发挥传统材料的性能;研究开发高性能防氧化剂;镁碳砖低碳化方法的改进及性能评估.     

钢锭头部保护渣增碳机理初探

调查了鞍钢8.3t钢锭头部使用保护渣浇注时的碳偏析情况:在实验室研究了熔融保护渣碳的饱和含量及其影响因素;熔渣-钢液间、碳粉-熔渣-钢液间平衡增碳研究,从而对使用保护渣浇注时钢锭头部的增碳机理提出了初步的看法:由于钢锭头部熔渣的含碳量很低(0.10％—0.20％),所以在浇注中保持足够的熔渣层不致于引起头部增碳。     

不同熔渣下铝镁质材料渣蚀机理研究

选取冶炼取向硅钢和铝镇静钢的精炼终渣及钢包用铝镁质材料,采用静态坩埚法于1 600 ℃×3 h下进行熔渣侵蚀试验,对渣蚀后试样作显微结构分析,并测定熔渣的化学成分、熔化温度及黏度.结果显示,随着熔渣中wAl2O3的升高和碱度的增大,熔渣的熔点升高,黏度增大.黏度较大的熔渣与耐火材料接触后扩散较慢,对耐火材料的熔损和渗透减弱.当熔渣与耐火材料反应形成较多的高熔点CA2,CA6和MA尖晶石相且连续交错分布时,耐火材料表面粗糙度增大,浸润加剧.钢包循环使用,熔渣与耐火材料进行新一轮的渗透与溶解,最终侵蚀得到抑制,呈现粘渣状态.     

硫酸固化–浸出含钛高炉渣回收钛、铝、镁并分离硅

本研究采用了一种节能路线处理含钛高炉渣，即低温硫酸固化，低浓度硫酸溶液浸出的方法同时提取钛、铝、镁。系统地研究了硫酸固化–浸出含钛高炉渣的工艺参数，在最佳条件下钛、铝、镁的回收率分别达到85.96%、81.17%、93.82%。采用快速浸出模型，限制硅的溶解和聚合，硅的溶出率仅3.18%。研究了硫酸固化-浸出的机理。在硫酸固化过程中反应快速发生并急剧放热，在氢离子的进攻下，渣的结构被破坏，硅酸盐解聚形成可滤性二氧化硅，钛、铝、镁、钙离子被置换形成硫酸盐包裹在无定型二氧化硅颗粒表面。浸出液中钛、铝、镁得到回收，浸出残渣中富集硫酸钙和二氧化硅。该方法有效避免浸出过程硅溶胶的形成，固液分离得到加速。     

熔融还原型熔渣对Al2O3—C—ZrO2系耐火材料的侵蚀

在实验室内模拟熔融还原铁浴式熔渣，采用静态与旋转法研究了高铝质耐火材料及其配加石墨碳与ＺｒＯ２耐火材料的抗渣蚀能力变化，用ｘ射线衍射及波谱分析方法分析了侵蚀的特点，主要因素及其与耐火材料在侵蚀过程中微观结构变化的相互关系。结果表明，配加适量的石墨碳与ＺｒＯ２均可改善耐火材料的结构及抗渣蚀的能力，渣的氧化性是影响侵蚀速度的重要因素之一。     

MgO-CaO系耐火材料的研究与应用

镁钙系耐火材料具有一系列优良的性能，有关镁钙系耐火材料的研究与应用一直受到人们的关注。镁钙系耐火材料的弱点是其中游离氧化钙易水化的问题，围绕着这一问题，人们做了大量的工作并取得了一些有益的结论。对镁钙系耐火材料的现状进行了分析，介绍镁钙系耐火材料的性能、生产、研究和应用，并对下一步的研究工作提出了建议。     

碳氮化含钛高炉渣对铁沟捣打料抗氧化性及抗渣性的影响

测定碳氮化处理后含钛高炉渣的熔化特性,并研究在高炉铁沟捣打料中加入碳氮化含钛高炉渣后对材料抗氧化性及抗渣性的影响。结果表明,含钛高炉渣经碳氮化处理后,渣中主要的矿物相为氮化钛或碳氮化钛和钙镁黄长石或钙铝黄长石,渣中相的组成和含量受还原温度影响较大,随着渣的还原温度升高,还原渣的熔点呈上升趋势;将还原渣引入到高炉铁沟捣打料中,部分或完全替代碳化硅原料,可明显提高捣打料的抗氧化性,最佳的渣加入量为7%,过多将会导致捣打料抗氧化性减弱;因Ti(C,N)具有优良的抗渣性能,碳氮化含钛高炉渣的引入不影响高炉铁沟捣打料的抗渣性。     

基于PFC~(2D)的镁碳质耐火材料断裂行为模拟研究

将镁碳质耐火材料视为骨料和细粉基质组成的两相复合材料,采用基于离散元的颗粒流模拟软件PFC2D,将材料离散成刚性颗粒组成的模型,把颗粒细观参数的变化与宏观力学特性联系起来,构建镁碳质耐火材料在1000℃下的试验模型,模拟试样三点弯曲的载荷-位移曲线,对材料裂纹的扩展进行分析,并通过改变摩擦系数、平行粘结刚度比、孔隙率以及平行粘结弹性模量,对比分析细观参数对载荷力峰值大小的影响情况。结果表明,采用PFC2D可准确模拟镁碳质耐火材料在三点弯曲时的断裂行为;材料的摩擦系数和平行粘结弹性模量与试样所受最大载荷力呈正比关系,而孔隙率和平行粘结刚度比与试样所受最大载荷力呈反比关系。     

Markedness and its Interpretation in Language Use

Language markedness is a common phenomenon in languages, and is reflected from hearing, vision and sense, i.e. the variation in the three aspects such as phonology, morphology and semantics. This paper focuses on the interpretation of markedness in language use following the three perspectives, i.e. pragmatic interpretation, psychological interpretation and cognitive interpretation, with an aim to define the function of markedness.     

Features of Women's language

Language is a means of verbal communication. People use language to communicate with each other. In the society, no two speakers are exactly alike in the way of speaking. Some differences are due to age, gender, statue and personality. Above all, gender is one of the obvious reasons. The writer of this paper tries to describe the features of women＇s language from these perspectives： pronunciation, intonation, diction, subjects, grammar and discourse. From the discussion of the features of women＇s language, more attention should be paid to language use in social context. What＇s more, the linguistic phenomena in a speaking community can be understood more thoroughly.     

低渗透非均质砂岩油藏启动压力梯度研究

理论推导与室内实验相结合,建立了低渗透非均质砂岩油藏启动压力梯度确定方法。首先借助油藏流场与电场相似的原理,推导了非均质砂岩油藏启动压力梯度计算公式。其次基于稳定流实验方法,建立了非均质砂岩油藏启动压力梯度测试方法。结果表明:低渗透非均质砂岩油藏的启动压力梯度确定遵循两个等效原则。平面非均质油藏的启动压力梯度等于各级渗透率段的启动压力梯度关于长度的加权平均;纵向非均质油藏的启动压力梯度等于各渗透率层的启动压力梯度关于渗透率与渗流面积乘积的加权平均。研究成果可用于有效指导低渗透非均质砂岩油藏的合理井距确定,促进该类油藏的高效开发。     

On Tragic Consciousness In The Works By Ernest Hemingway

As an American modern novelist who were famous in the literary world, Hemingway was not a person who always followed the trend but a sharp observer. At the same time, he was a tragedy maestro, he paid great attention on existence, fate and end-result. The dramatis personae's tragedy of his works was an extreme limit by all means tragedy on the meaning of fearless challenge that failed. The beauty of tragedy was not produced on the destruction of life, but now this kind of value was in the impact activity. They performed for the reader about the tragedy on challenging for the limit and the death.     

Achieving Unusual States of Matter Under High Pressure

正The periodicity of the elements and the non-reactivity of the inner-shell electrons are two related principles of chemistry,rooted in the atomic shell structure.Within compounds,Group I elements,for example,invariably assume the+1 oxidation state,and their chemical properties differ completely from those of the p-block elements.These general rules govern our understanding of chemical structures and reactions.Using first principles calcula-     

Exchange-Correlation and Electronic Excitation Energies from Pairing Matrix Fluctuations

We have developed an adiabatic connection to formulate the ground-state exchange-correlation energy in terms of pairing matrix linear fluctuations.This formulation of the exchange-correlation energy opens a new channel for density functional approximations based on the many-body perturbation theory.We illustrate the potential of such approaches with an approximation based on the particle-particle Random Phase Approximation(pp-RPA).This re-     

Density Functional Theory for the Response of Periodic Systems to Electric Fields Based on the Vector Potential Approach

正The electronic and nuclear(structural/vibrational)response of 1D-3D nanoscale systems to electric fields gives rise to a host of optical,mechanical,spectral,etc.properties that are of high theoretical and applied interest.Due to the computational difficulty of treating such large systems it is convenient to model them as infinite and periodic(at least,in first approximation).The fundamental theoretical/computational problem in doing so is that     

On the Thermodynamic Limit for Responses to Static Electromagnetic Fields

For molecular systems,the quantum-mechanical treatment of their responses to static electromagnetic fields usually employs a scalar-potential treatment of the electric field and a vector-potential treatment of the magnetic field.Although the potential for each field separately is associated with the choice of an(unphysical)origin,the precise choice of the origin for the electrostatic field has little consequences for the results.This is different for the     

An affordable accurate evaluation of the binding conformations predicted by molecular docking studies in bio-system

Franck-Condon factors bridge the gap between theoretical modeling and experimental observations for molecular electronic spectroscopy and electron transfer.Under the displaced harmonic oscillator approximation,multidimensional Franck-Condon factors are decomposed into a product of many one-dimensional(1D)Franck-Condon(FC)factors,and each 1D-FC factor is associated with one Huang-Rhys factor that determines the leading contribution of     

Call for Papers

<正>"The Journal of Shanghai Normal University:Mathematics"is published by Shanghai Normal University as regular issues of The Journal of Shanghai Normal University each year from 2014 in English.The editors-in-chief of the issues are professors Yuhao Cong and Maoan Han.The Journal of Shanghai Normal University was started in 1958 with