表面增强拉曼光谱研究尼古丁与金属纳米粒子的相互作用

以金、银纳米及Au@Ag、Au-Ag合金复合纳米粒子为基底,研究尼古丁分子的表面增强拉曼光谱,讨论分子在4种纳米粒子表面的作用方式及可能的吸附取向.结果表明,分子在金纳米和Au-Ag合金纳米粒子表面的吸附取向相同——垂直吸附,不同的是与金纳米粒子形成了稳定的N-Au键;由于银纳米粒子和Au@Ag核壳纳米粒子表面均富含大...     

等离子体引发聚乙烯表面肝素化及其生物相容性

目的 研究等离子体引发低密度聚乙烯（ＬＤＰＥ）表面肝素化以及肝素化ＬＤＰＥ表面抗凝血性和组织相容性。方法 利用等离子体引发技术在ＬＤＰＥ膜表面接枝聚乙二醇（ＰＥＧ）和肝素,用体外凝血时间及细胞生长试验考察改性ＬＤＰＥ表面的生物相容性。     

甘肃两当杨家坪地区土壤金异常晕与金矿化特征

从区域地质背景和矿区地质特征入手,分析了甘肃两当杨家坪地区的土壤金异常晕,结果表明,该区土壤晕分布与构造展布方向相一致,金异常晕对地层的选择性不明显．对化探土壤测量中金、银、铅、锌、砷、汞6种元素指标进行了R型聚类分析和相关性分析,Au和As相关性最高;Ag和Hg关系密切,属同一指标;Au,As,Ag,Hg具有一定相关性,属直接指示元素;Pb,Zn为参考指标．阐明了研究区的金矿化特征,进而从地层、岩性、构造、成矿热液等方面分析了该区的金与多金属成矿地质条件;初步探讨了金矿成因,指出了杨家坪金矿为石英脉型金矿,地层岩性、构造、热液共同控制着金的富集与成矿．     

Minimizing the effect of near-distance dielectric sensitivity on retrieving average aspect ratio of gold nanorod by optical extinction spectroscopy: in the case of CTAB adsorption

The aspect ratio （AR） is one of the most intriguing parameters of gold nanorods （GNRs）, which plays an important role in determining localized surface plasmon （LSPR） properties. Instead of conventional imaging techniques, the optical extinction spectroscopy （OES） method has been developed for allowing fast sta-tistically measuring the average AR under static approxi- mation. In this work, combining with the previous achievements in spectroscopic technique, we further ana-lyze the effects of gold dielectric function and near dis-tance dielectric sensitivity. The former may reflect possible dielectric loss of real Au samples from ideal single crys- talline. The latter reflects the cetyltrimethylammonium bromide （CTAB） adsorption on the surface of GNR indu- ces different LSPR shifts below and above critical micelle concentration （CMC）. However, their effect on the deter-mination of AR has not been evaluated in OES method. The average AR measurements as a function of absorbance of CTAB-GNRs and LSPR maximum below the CMC were studied. Our results indicate that after considering these factors, the mean ARs obtained from spectroscopic techniques are closer to those obtained from imaging techniques.     

平板式MTPV系统中燃烧若干影响因素的试验

平板式微热光电(MTPV)能源系统采取全新的亚毫米平板式燃烧室取代以往的圆柱式,对应的面容比的增加将提高燃烧室壁面的能量输出,从而提高系统的能量密度.针对石英玻璃材质的平板式燃烧室,改变氢气流量、氢氧混合比以及平行板间夹缝距离等,进行燃烧试验,测试了外壁面和出口的温度,进而分析几种因素的影响规律.结果表明,在一定条件下,亚毫米平板式微燃烧室能克服壁面能量损失激增而带来的着火困难和火焰淬熄等问题,能够实现稳定燃烧.合理选择工况参数,可以提高燃烧室温度和优化温度分布,提升系统工作性能.     

Au／Ni多层膜的原子学结构研究

利用嵌入原子势方法，完成了Ａｕ／Ｎｉ多层膜的分子动力学模拟计算。研究了Ａｕ／Ｎｉ多层膜中原子层数对多层膜界面的影响。探讨了原子层厚度和多层膜膜面取向对原子层间距、Ａｕ／Ｎｉ界面影响的变化规律。     

多硫化钠浸金研究

本文中研究了用多硫化钠作浸出剂浸出锑锍中的金。根据实验和理论分析,认为多硫化物浸金具有如下反应: 6Au 2S~(2-) S_4~(2-)=6AuS~- 8Au 3S~(2-) S_5~(2-)=8AuS~- 6Au 2HS~- 2OH~- S_4~(2-)=6AuS~- 2H_2O 8Au 3HS~- 3OH~- S_5~(2-)=8AuS~- 3H_2O考察了粒度、温度、硫化钠用量、加硫量、氢氧化钠浓度、液固比、时间等因素对金浸出率的影响。在研究所得的最佳条件下,金的浸出率稳定在93％以上。     

电极电位对L-蛋氨酸分子吸附构型影响的表面增强拉曼光谱

利用电化学现场表面增强拉曼光谱技术研究了在粗糙化金电极和银电极表面吸附的L-蛋氨酸自组装单分子膜结构随电位改变的特征.实验结果表明:在外加电位0--0.6V范围内,L-蛋氨酸主要是通过硫原子和去质子化羧基2个吸附位点与银电极表面产生相互作用的;而在金电极表面表现为分子中的氨基、去质子化羧基和硫原子3个吸附位点随电位负移而改变的特征;另外,对于金电极表面吸附的L-蛋氨酸单分子膜而言,还伴随着吸附物分子由于分子内旋转等而引致的分子构型的转变.     

Spreading of human neutrophils on an ICAM-1-immobilized substrate under shear flow

Neutrophil (PMN) spreading on endothelium, mediated by the interactions between surface-bound β2 integrin and intercellular adhesion molecule-1 (ICAM-1) in the inflammatory cascade, is crucial for PMN post-adhesion and trans-migration in blood flow. The underlying mechanisms by which shear flow regulates PMN spreading dynamics are not well understood. Here, a parallel-plate flow chamber assay was applied to quantify the time course of PMN adhesion and spreading on an ICAM-1-immobilized substrate. Two types of shear flow, steady flows at shear stresses of 0.2, 0.5, and 1 dyne/cm2 and stepwise flows at 0, 1, and 10 dyne/cm2, were used to elucidate the impact of shear flow on cell adhesion and spreading. The number of adhered PMNs, the fraction of spreading PMNs and the projected area of spread PMNs were determined and were found to correlate with the distribution of surface-bound β2 integrin subunit (CD11a, CD11b, or CD18). The results indicate that PMN spreading on an ICAM-1 substrate is bi-directionally regulated under shear flow. CD11a, CD11b and CD18 subunits of β2 integrin contribute distinctly to PMN spreading on ICAM-1 substrates. This work provides new insights into understanding PMN spreading on the endothelium, mediated by β2 integrin and ICAM-1 under shear flow.     

高松山金矿地质特征及找矿标志

黑龙江省逊克县高松山矿区金矿石类型为石英脉-蚀变岩型。金矿体与赋矿围岩存在着明显的物性差异,与Au、Ag、As、Sb、Cu有密切的相关关系,并以零磁场、高电阻为特征,从而本区具备了物化探找矿前提。该区为黑龙江东北部的一个重要的找矿远景区。     

甲壳糖对Au^3＋氧化还原吸附性能研究

研究了不同脱乙酰度甲壳糖对Ａｕ＾３＋的吸附性能，广角Ｘ－射线衍射实验有甲壳糖能把Ａｕ＾３＋还原成Ａｕ，静态吸附实验结果表明，甲壳糖对Ａｕ＾３＋的吸附量随脱惭酰度的增大而升高脱乙酰时间为４ｈ的甲壳糖对Ａｕ＾３＋的吸附量随溶液ＰＨ值的同而增加；在ＰＨ值等于５．０时吸附量达１１７３ｍｇ／ｇ；另外，随溶液离子强度或高甲壳糖对Ａｕ＾３＋的吸附量减少，吸附动力学实验结果表明，甲壳糖对Ａｕ＾３＋吸附量在１２０ｍ     

成骨细胞在纳米材料表面上粘附特性

在利用静电自组装技术制备的具备不同纳米形貌的S iO2纳米粒子薄膜及空白试片上,进行了SD大鼠成骨细胞的粘附特性考评实验,并对比了成骨细胞分别在纳米粒子基片和空白试片上的粘附数、细胞活性及形态的差异.实验结果表明:利用静电自组装技术获得的纳米结构表面对细胞的粘附特性确实存在良性影响;在所采用的3个纳米尺度下,细胞粘附数随纳米尺度的增加而增加,M TT检测结果表明细胞活性也随之增加.     

Spreading of nanofluids on solids

Suspensions of nanometre-sized particles (nanofluids) are used in a variety of technological contexts. For example, their spreading and adhesion behaviour on solid surfaces can yield materials with desirable structural and optical properties. Similarly, the spreading behaviour of nanofluids containing surfactant micelles has implications for soil remediation, oily soil removal, lubrication and enhanced oil recovery. But the well-established concepts of spreading and adhesion of simple liquids do not apply to nanofluids. Theoretical investigations have suggested that a solid-like ordering of suspended spheres will occur in the confined three-phase contact region at the edge of the spreading fluid, becoming more disordered and fluid-like towards the bulk phase. Calculations have also suggested that the pressure arising from such colloidal ordering in the confined region will enhance the spreading behaviour of nanofluids. Here we use video microscopy to demonstrate both the two-dimensional crystal-like ordering of charged nanometre-sized polystyrene spheres in water, and the enhanced spreading dynamics of a micellar fluid, at the three-phase contact region. Our findings suggest a new mechanism for oily soil removal--detergency.     

组合式金合金圆平面磁控靶的设计

首先对传统的圆平面磁控靶的形状进行改进,设计一个靶材利用率高的纯金靶．利用金合金的色区图,计算沉积不同Ｋ值和颜色的镀金膜时,组合式Ｋ金靶上金、银、铜的面积比,从而在纯金靶上固定相应面积的扇形银片和铜片,研制出不同Ｋ值和色度的组合式金合金靶．     

十四烷基二甲基苄基氯化铵萃取金的研究

用放射性核素¹⁹⁸Au示踪法研究了季铵盐十四烷基二甲基苄基氯化铵(TDMBA)从碱性氰化液中萃取金,考察了水相金浓度、助溶剂含量、萃取时间、季铵盐与KAu(CN)₂摩尔比值n_r等因素对萃取率的影响,并研究了有机相的连续萃取、有机相金含量与水含量的关系。结果表明,助溶剂体积比10%以上时,十四烷基二甲基苄基氯化铵对金具有萃取能力强,平衡时间短的特点。季铵盐阳离子与Au(CN)₂^-结合比为1∶1,符合离子缔合机理。     

空间太阳电池自动涂胶过程的扩散原理

空间太阳电池封装操作包括:注射器涂胶过程、盖片胶平面扩散以及玻璃盖片封装操作三个阶段.分析了盖片胶从注射器中流出落在电池片上后,逐渐扩散融合的过程.基于非牛顿流体理论,建立了盖片胶的平面扩散模型,使用有限元软件Adina,基于流体体积法进行运动界面追踪,对模型进行了模拟仿真,并与实验结果进行了对比验证.获得了盖片前胶层的形状,确定了胶层的边缘位置.为封装过程的分析建模提供了胶层厚度和边界等几何参数.对类似的平面扩散问题,也提供了一种新的解决方法.     

Myofibrillogenesis regulator-1 promotes cell adhesion and migration in human hepatoma cells

Myofibrillogenesis regulator-1 (MR-1) is a gene overexpressed usually in many human cancers. However, the effects of MR-1 on cell proliferation, adhesion, migration and genome-wide gene regulation are still unclear. In this study, a human hepatoma cell line that highly overexpresses MR-1, BEL-7402/MR-1 cells was established. While the high expression of MR-1 did not promote cell proliferation, it significantly increased cell spreading, adhesion and migration compared with control cells. A total of 147 genes were regulated by MR-1 expression, 46 genes were down-regulated and 101 genes were up-regulated by MR-1 overexpression. Many of these genes were related to cell adhesion, cytoskeletal regulation, MAPK signaling, and cell cycle related pathways. Western blot analysis further confirmed the regulation of pathways associated with migration by MR-1. These results suggest that MR-1 is involved in the regulation of cancer cell adhesion, migration and related gene expression.     

悬链面与正螺面之间的内在关系

研究了两类著名的且极其重要的极小曲面——悬链面与正螺面之间的内在联系．得到了具有不同参数的悬链面和正螺面是成等角对应,即当悬链面中顶点到原点的距离为a,正螺面中的螺距变成b时（其中b是速度与角速度的比值）,则悬链面与正螺面是成等角对应的关系．     

Re-Os dating of gold-bearing arsenopyrite of the Maoling gold deposit,Liaoning Province,Northeast China and its geological significance

The Maoling gold deposit, one of the large gold deposits in eastern Liaoning Province, NE China, is an arsenopyrite-disseminated gold deposit with a resource of approximately 25 t Au and an average Au grade of 3.2 g/t. Six arsenopyrites closely related to Au mineralization of the Maoling gold deposit are dated by Re-Os technique and define a Re-Os isochron with an age of 2316±140 Ma, which suggests that the deposit was formed in the Paleoproterozoic era rather than in the Indosinian period as some early researchers suggested. High initial ^187Os/^188Os ratio of 1.32±0.48 indicates a crustal derivation of the ore-forming material of the deposit, which may be derived from rocks of the Gaixian formation of the Liaohe Group. Furthermore,the result also implies that the age of the Gaixian Formation in the Maoling district is older than 2316±140 Ma.     

影响木材火焰传播速度特征量的实验研究

木材着火时火焰的传播规律将为木材在火灾场景中的行为提供重要参考,分析了木材燃烧的机理和影响木材燃烧时火焰传播速度的特征量,借助于实验的方法,研究了空间方位角和几何尺寸等特征量对火焰传播速度的影响.结果表明,方位角越小,不同尺寸木条火焰传播速度差别越大;火焰传播速度随方位角的增大而增大;木条宽度越大,火焰传播速度越慢.