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1.
设f(x)是R^n上的可测函数,u(x,t)=f*pt(x)为f的Poisson积分,定义算子F(f)(x,t)=t(θu(x,t)/θt)。在本注记中我们首先给出一则反例以说明F不是L^∞(R^n)到帐蓬空间T^∞的有界算子,然后证明了F却是BMO(R^n)到T^∞的有界算子。它补充、完善了Coifman-Meyer-Stein的结果。  相似文献   

2.
部分取代苯定量结构-生物降解相关性(QSBR)研究   总被引:1,自引:0,他引:1  
采用Chems3D中量子化学MOPAC-AM1法计算了7种间苯胺类和8地苯酚的分子量高占有轨道能EHOMO、分子最低空轨道能ELUMO。用QSAR程序软件包查得分子体积Vm。结合分子连接性指数(^3X,^3X^v)对生物降解二级速率常数对数lgKb进行定量结构-生物降解相关性(QSBR)分析,通过回归分析,得到如下两个回归方程:lgKb=-0.832-0.118Vm+1.748^3X^v,n=15,R^2=0.832,SE=0.577,F=29.7,p=0.000。(1)lgKb=0.124Vm+1.749^3X^v,n=15,R^2=0.998,SE=0.5591,F=4148.99,p=0.000.(2)  相似文献   

3.
通过量子化学的SCC-DV-Xα计算方法,分别研究了C3A分子结构中2种AlO4四面体和3种CaOx(x=6,6,9)多面体的价键特性与活性。原子净电荷、键强、电子态密度、ELUMO以及ΔE(LUMO-HOMO)等的计算结果表明:与水反应时,多面体活性大小顺序为Ca(4)O9>Ca(1)O6(或Ca(3)O6)>Al(1)O4>Al(2)O4。C3A具有高水化活性主要与弱的Ca-O键和空洞缺陷有关。  相似文献   

4.
以过硫酸钾(KPS)-亚硫酸氢钠(NaBS)为引发体系,甲基丙烯酸甲酯(MMA)及甲基丙烯酸(MAA)为接枝单体,制得了具有亲水性与疏水性接枝支链交联明胶.用红外光谱确证了产物结构.实验结果表明,当[KPS]=[NaBS]=6×10-3M,[MMA]=6×10-1M,Gelx-g-PMAA=4g,SL=4100,60℃反应5小时,接枝率G%及接枝效率E%均出现最大值.研究了此类两亲性接枝交联明胶的溶胀行为.  相似文献   

5.
三维定量构效关系最新研究进展   总被引:10,自引:0,他引:10  
在简要回顾了经典的Hansch方法的基础上,重点讨论了4种典型的3D-QSAR方法,即分子形状分析(MSA)、距离几何学方法(DG)、比较分子力场分析(COMFA)和假想活性位点阵(HASL)的基本原理,并介绍了人工神经网络在3D-QSAR的原理和应用  相似文献   

6.
合成了过氧磷钨杂多酸盐α2-K7-mHm(P2W17(TαO2)O61).xH2O(M=K,TMA,TEA,TBA)并且极谱-循环伏安,IR,UV吸收光谱,XPS,XRD,^31PNMR,^183WNMR谱进行表征。  相似文献   

7.
研究了以二氯乙酸为溶剂,三乙胺为引发剂,γ-谷氨酸甲酯-N羧基-α-氨基羧酐(MLG-NCA)与γ-谷氨酸苄酯-N羧基-α-氨基羧酐(BLG-NCA)的共聚反应.用1H-NMR谱测定了共聚物中两种单体元的组成.利用Kelen-Tudos作图法和最小二乘法计算出两种单体竞聚率.结果表明MLG-NCA的竞聚率为,r1=0.960,BLG-NCA竞聚率为r2=0.704.  相似文献   

8.
ESTABLISHINGANORGANICCHEMISTRYMICROSCALELABORATORYPROGRAM¥ArthurR.Murdoch(MountUnionCollege,Alliance,Ohio,USA)(Visitingprofes...  相似文献   

9.
APPROXIMATESOLUTIONSOFSOMEBOUNDARYVALUEPROBLEMSFORPARABOLICEQUATIONSANDTHEIRERRORESTIMATESHuMinde(胡敏德);WenGuochun(闻国椿)(Logist...  相似文献   

10.
对GPS定位中的SA误差作了系统辨识。表明:SA误差可用时变AR(p)模型表述,AR(p)的时变参数可由RLS算法结合F判据建立的AR(p)模型辨识机获得。用该方法获得的模型对SA误差进行预报,在剔除野值后精度在10m之内。还提出了一种将以AR(p)模型表述的SA误差加入GPS KALMAN滤波器的方法,可得到一种具有SA预报能力的GPS KALMAN滤波器。  相似文献   

11.
Language markedness is a common phenomenon in languages, and is reflected from hearing, vision and sense, i.e. the variation in the three aspects such as phonology, morphology and semantics. This paper focuses on the interpretation of markedness in language use following the three perspectives, i.e. pragmatic interpretation, psychological interpretation and cognitive interpretation, with an aim to define the function of markedness.  相似文献   

12.
何延凌 《科技信息》2008,(4):258-258
Language is a means of verbal communication. People use language to communicate with each other. In the society, no two speakers are exactly alike in the way of speaking. Some differences are due to age, gender, statue and personality. Above all, gender is one of the obvious reasons. The writer of this paper tries to describe the features of women's language from these perspectives: pronunciation, intonation, diction, subjects, grammar and discourse. From the discussion of the features of women's language, more attention should be paid to language use in social context. What's more, the linguistic phenomena in a speaking community can be understood more thoroughly.  相似文献   

13.
理论推导与室内实验相结合,建立了低渗透非均质砂岩油藏启动压力梯度确定方法。首先借助油藏流场与电场相似的原理,推导了非均质砂岩油藏启动压力梯度计算公式。其次基于稳定流实验方法,建立了非均质砂岩油藏启动压力梯度测试方法。结果表明:低渗透非均质砂岩油藏的启动压力梯度确定遵循两个等效原则。平面非均质油藏的启动压力梯度等于各级渗透率段的启动压力梯度关于长度的加权平均;纵向非均质油藏的启动压力梯度等于各渗透率层的启动压力梯度关于渗透率与渗流面积乘积的加权平均。研究成果可用于有效指导低渗透非均质砂岩油藏的合理井距确定,促进该类油藏的高效开发。  相似文献   

14.
As an American modern novelist who were famous in the literary world, Hemingway was not a person who always followed the trend but a sharp observer. At the same time, he was a tragedy maestro, he paid great attention on existence, fate and end-result. The dramatis personae's tragedy of his works was an extreme limit by all means tragedy on the meaning of fearless challenge that failed. The beauty of tragedy was not produced on the destruction of life, but now this kind of value was in the impact activity. They performed for the reader about the tragedy on challenging for the limit and the death.  相似文献   

15.
正The periodicity of the elements and the non-reactivity of the inner-shell electrons are two related principles of chemistry,rooted in the atomic shell structure.Within compounds,Group I elements,for example,invariably assume the+1 oxidation state,and their chemical properties differ completely from those of the p-block elements.These general rules govern our understanding of chemical structures and reactions.Using first principles calcula-  相似文献   

16.
We have developed an adiabatic connection to formulate the ground-state exchange-correlation energy in terms of pairing matrix linear fluctuations.This formulation of the exchange-correlation energy opens a new channel for density functional approximations based on the many-body perturbation theory.We illustrate the potential of such approaches with an approximation based on the particle-particle Random Phase Approximation(pp-RPA).This re-  相似文献   

17.
正The electronic and nuclear(structural/vibrational)response of 1D-3D nanoscale systems to electric fields gives rise to a host of optical,mechanical,spectral,etc.properties that are of high theoretical and applied interest.Due to the computational difficulty of treating such large systems it is convenient to model them as infinite and periodic(at least,in first approximation).The fundamental theoretical/computational problem in doing so is that  相似文献   

18.
For molecular systems,the quantum-mechanical treatment of their responses to static electromagnetic fields usually employs a scalar-potential treatment of the electric field and a vector-potential treatment of the magnetic field.Although the potential for each field separately is associated with the choice of an(unphysical)origin,the precise choice of the origin for the electrostatic field has little consequences for the results.This is different for the  相似文献   

19.
<正>"The Journal of Shanghai Normal University:Mathematics"is published by Shanghai Normal University as regular issues of The Journal of Shanghai Normal University each year from 2014 in English.The editors-in-chief of the issues are professors Yuhao Cong and Maoan Han.The Journal of Shanghai Normal University was started in 1958 with  相似文献   

20.
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