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1.
用烧碱溶解分离珠珍岩尾砂,可得碱金属铝硅酸盐碱性溶液,此溶液是合成分子筛的廉价原料。本实验研究了干法碱溶珍珠岩尾砂的效果及最适宜的工艺条件。采用干法最大限度地溶解珍珠岩尾砂的工艺条件是烧碱与原砂的配比为1:1,灼烧温度550℃,灼烧时间2小时。在常温常压下,按此参数操作,珍珠岩尾砂的一次转化率为80%以上。  相似文献   

2.
将珍珠岩与NaOH混合进行高温碱溶,结果表明:珍珠岩与NaOH的质量比为1.00:0.75,在550℃灼烧1h,可使珍珠岩的化学有效成价SiO2溶出率达83%以上,溶出液可做工业用水玻璃,经分析质量达到国家标准。  相似文献   

3.
贵州高硫铝土矿溶出性能研究   总被引:6,自引:1,他引:6  
研究贵州高硫型高品位铝土矿溶出性能,考查石灰添加量、溶出温度、苛性碱浓度和溶出时间对氧化铝溶出率的影响以及铝土矿的硫向溶液中的转化率(即硫的溶出率)的影响。实验结果表明,溶出高硫铝土矿较适宜的条件是:温度260℃,碱浓度195g/l,石灰添加量CaO12%,时间50min.此时,氧化铝溶出率高于88%,硫的溶出率低于13%.  相似文献   

4.
系统研究了纯化冶金级Al(OH)3的工艺参数,通过对影响碱溶及纯化的因素进行试验,探索出碱溶除去Al(OH)3中晶间碱,获得Na20合量<0.003%的低钠Al(OH)3的新方法,得出最佳工艺条件.  相似文献   

5.
研究了铝土矿两段烧结工艺的Ⅱ段烧结及溶出的最佳操作条件,确定Ⅰ段赤泥在钙比为235,烧结温度为1120~1200℃时,氧化钠溶出率达92%左右,氧化铝溶出率达81%左右;当溶出液氧化铝质量浓度为40~80g/L时,Ⅱ段熟料溶出的二次反应很弱,溶出条件宽松.因此,两段烧结新工艺处理铝硅比为6的矿石,氧化钠总溶出率达986%,氧化铝总溶出率达968%,碱的化学损失是每吨氧化铝损失碳酸钠18kg.  相似文献   

6.
Sr在碱硬锰矿固溶体中的化学固溶量研究   总被引:1,自引:0,他引:1  
以SrCO3、BaCOs、Al2O3和TiO2为原料,通过配方设计,采用高温固相反应,合成了单相固溶Sr的碱硬锰矿固溶体.借助于X射线衍射、扫描电子显微镜和电子探针波谱等分析手段,研究了配方设计、Sr在碱硬锰矿固溶体中的化学固溶量等问题.实验结果表明,采用高温固相反应工艺,容易合成掺Sr碱硬锰矿固溶体及单相掺Sr碱硬锰矿固溶体,但是Sr在碱硬锰矿固溶体中的最高化学固溶量与配方设计有关,当配方的化学式为SrxBa1Al2 2rTi6-24O16时,其最大化学固溶量为0.13mol,而当配方的化学式为Srx yBa1-yAl2 2xTi6-24O16时,其最大化学固溶量为0.22moLSr在碱硬锰矿固溶体中的最高固溶量还与合成方法有关,采用均相化学反应法合成的单相掺Sr碱硬锰矿固溶体中Sr的最高化学固溶量要高于固相反应法合成的固溶体中Sr的最高化学固溶量.  相似文献   

7.
木质素氧化制取表面活性剂的适宜条件   总被引:2,自引:1,他引:1  
通过正交实验研究了过氧化氢用量、氧气压力、最高温度、保温时间等条件对麦草氧化碱木质表面活性、氧化木质素中酸溶及酸不溶木质素含量的影响。结果表明,对氧化木质素表面活性及氧化后木质素中酸溶木质素的含量产生影响的4个因素的主次顺序为:过氧化氢用量,最高温度、保温时间,氧气压力。当过氧化氢用量为20%、最高温度90℃、保温时间0.5h、氧气压力0.6MPa时,氧化木质素的表面活性最好。当过氧化氢用量为20%、最高温度90℃、保温时间1h、氧气压力为0.4MPa时,氧化木质素中酸溶木质素所占的比例最高。  相似文献   

8.
从针裂蹄中用碱提取得到一种碱溶糖,并用高碘酸氧化等方法确定了结构.  相似文献   

9.
研究了机械活化反应器中,温度、溶出原液α_K、溶出时间及液固比等因素对平果铝土矿溶出率的影响.在225℃,溶出原液α_K3.2,L/S2.5,溶出2h的条件下,Al_2O_3的溶出率达96.60%,比相同条件下的高压釜溶出率高18%;动力学研究表明,在138~176℃,范围内,试验结果能很好地模拟动力学模型1-(1-X) ̄(1/3)=k_at,测得其表观活化能为72.64kJ/mol,溶出过程属化学反应控制.研究结果表明,机械活化可明显改善一水硬铝石的溶出性能,强化其溶出过程,提高其溶出率。  相似文献   

10.
测试了压蒸条件下两种天然长石在水及饱和Ca(OH)2溶液中碱溶出情况.结果表明长石在水中碱溶出量比较少,溶出的碱主要是钠碱.长石在饱和Ca(OH)2溶液中碱溶出量比较多,溶出的碱包括钠碱和钾碱.集料碱溶出对混凝土碱含量影响比较小.  相似文献   

11.
Language markedness is a common phenomenon in languages, and is reflected from hearing, vision and sense, i.e. the variation in the three aspects such as phonology, morphology and semantics. This paper focuses on the interpretation of markedness in language use following the three perspectives, i.e. pragmatic interpretation, psychological interpretation and cognitive interpretation, with an aim to define the function of markedness.  相似文献   

12.
理论推导与室内实验相结合,建立了低渗透非均质砂岩油藏启动压力梯度确定方法。首先借助油藏流场与电场相似的原理,推导了非均质砂岩油藏启动压力梯度计算公式。其次基于稳定流实验方法,建立了非均质砂岩油藏启动压力梯度测试方法。结果表明:低渗透非均质砂岩油藏的启动压力梯度确定遵循两个等效原则。平面非均质油藏的启动压力梯度等于各级渗透率段的启动压力梯度关于长度的加权平均;纵向非均质油藏的启动压力梯度等于各渗透率层的启动压力梯度关于渗透率与渗流面积乘积的加权平均。研究成果可用于有效指导低渗透非均质砂岩油藏的合理井距确定,促进该类油藏的高效开发。  相似文献   

13.
As an American modern novelist who were famous in the literary world, Hemingway was not a person who always followed the trend but a sharp observer. At the same time, he was a tragedy maestro, he paid great attention on existence, fate and end-result. The dramatis personae's tragedy of his works was an extreme limit by all means tragedy on the meaning of fearless challenge that failed. The beauty of tragedy was not produced on the destruction of life, but now this kind of value was in the impact activity. They performed for the reader about the tragedy on challenging for the limit and the death.  相似文献   

14.
正The periodicity of the elements and the non-reactivity of the inner-shell electrons are two related principles of chemistry,rooted in the atomic shell structure.Within compounds,Group I elements,for example,invariably assume the+1 oxidation state,and their chemical properties differ completely from those of the p-block elements.These general rules govern our understanding of chemical structures and reactions.Using first principles calcula-  相似文献   

15.
We have developed an adiabatic connection to formulate the ground-state exchange-correlation energy in terms of pairing matrix linear fluctuations.This formulation of the exchange-correlation energy opens a new channel for density functional approximations based on the many-body perturbation theory.We illustrate the potential of such approaches with an approximation based on the particle-particle Random Phase Approximation(pp-RPA).This re-  相似文献   

16.
正The electronic and nuclear(structural/vibrational)response of 1D-3D nanoscale systems to electric fields gives rise to a host of optical,mechanical,spectral,etc.properties that are of high theoretical and applied interest.Due to the computational difficulty of treating such large systems it is convenient to model them as infinite and periodic(at least,in first approximation).The fundamental theoretical/computational problem in doing so is that  相似文献   

17.
For molecular systems,the quantum-mechanical treatment of their responses to static electromagnetic fields usually employs a scalar-potential treatment of the electric field and a vector-potential treatment of the magnetic field.Although the potential for each field separately is associated with the choice of an(unphysical)origin,the precise choice of the origin for the electrostatic field has little consequences for the results.This is different for the  相似文献   

18.
Franck-Condon factors bridge the gap between theoretical modeling and experimental observations for molecular electronic spectroscopy and electron transfer.Under the displaced harmonic oscillator approximation,multidimensional Franck-Condon factors are decomposed into a product of many one-dimensional(1D)Franck-Condon(FC)factors,and each 1D-FC factor is associated with one Huang-Rhys factor that determines the leading contribution of  相似文献   

19.
<正>"The Journal of Shanghai Normal University:Mathematics"is published by Shanghai Normal University as regular issues of The Journal of Shanghai Normal University each year from 2014 in English.The editors-in-chief of the issues are professors Yuhao Cong and Maoan Han.The Journal of Shanghai Normal University was started in 1958 with  相似文献   

20.
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