统计热力学模型对液体混合物导热系数的研究

应用溶液统计热力学方法和溶液理论，建立了多元液体混合物的统计热力学 模型。将该模型与溶液传热反应速率理论相结合，导出了一个新的多元液体混合物的导 热系数方程。该方程应用于９７个二元体系的关联和１５个多元（三元、四元、五元〕 体系的推算，方程的计算值与实验值吻合。这表明应用溶液统计热力学模型可以对溶液 的导热系数进行研究。     

碳酸二甲酯饱和液体粘度的实验研究

为将碳酸二甲酯作为替代清洁燃料的研究提供基本物性数据，使用改型的乌别洛特毛细管粘度计对283.273～383.104K温度区间的碳酸二甲酯饱和液体粘度进行了实验研究，并利用实验得到的饱和液体粘度实验数据，拟合了碳酸二甲酯饱和液体的粘度方程。实验结果表明，粘度测量结果的不确定度小于3．0％，实验数据与粘度方程的最大偏差为2．10％，平均偏差为0．58%。     

二甲醚饱和液相导热系数的实验研究

研制了高精度瞬态双热线法导热系数测量装置及数据采集系统,整个测量系统的不确定度小于±1%.用液相甲苯标定213~363 K温度区间的饱和液相导热系数,并与标准值进行了比较,测量的平均偏差为0.37%,最大偏差为0.73%.用此装置对245~385 K温度区间的二甲醚饱和液相导热系数进行了实验研究,利用测量得到的饱和液相导热系数数据,拟合了二甲醚饱和液相的导热系数方程,该方程的计算值与实验数据的平均偏差为0.32%,最大偏差为0.85%,为二甲醚作为替代制冷剂和替代燃料等研究提供了急需的热物性数据.     

焦化炉管焦导热系数的测定

从现场焦化炉中截取一段结焦炉管 ,采用热通量法测定了炉管结焦层的导热系数。实验表明 ,当温度为5 0～ 10 0℃时 ,管焦导热系数随温度的升高而迅速降低 ;当温度为 10 0～ 5 5 0℃时 ,随着温度的升高 ,管焦导热系数降低的速度逐渐减缓 ,并最终稳定在 3 .8W/ (m·℃ ) ,实验误差不超过 10 %。对实验数据进行多项式线性回归 ,得到了管焦导热系数随温度变化的回归方程 ,该方程的相对误差低于 4 %。     

HFC混合物二元交互作用系数的关联与推算

结合Peng-Robinson（PR）方程与已有的实验数据对氢氟烃混合物（HFCs）二元混合工质进行了气液平衡计算，关联得到相关体系的二元交互作用系数。在此基础上建立了二元混合物交互作用系数的推算模型，该模型能近似给出多种HFC任意二元混合的交互作用系数，由此交互作用系数计算的气液平衡压力误差一般在2％内，能满足工程需要。     

PR导热系数普遍化模型及其精度预测分析

在原PR导热系数模型基础上,改进建立了一个PR导热系数普遍化模型,在温度80～1 400 K和压力0.1～350 MPa内对油气藏流体中常见的22个纯组分的气、液相导热系数总共3 263个数据点进行了拟合,总平均相对误差为7.34%.对13个二元和三元混合物总共260个数据点预测的总平均相对误差为7.94%;对3个石油馏分总共22个数据点导热系数预测的总平均相对误差为9.68%.对极性纯物质的总共810个数据点预测的总平均相对误差为6.86%;对极性二元混合物的共439个数据点预测的总平均相对误差为6.03%.该模型的计算精度明显优于石油工程中常用的导热系数模型.     

液体混合物导热系数理想模型的建立及其应用

根据液体结构的特点,通过建立液体混合物导热系数的理想模型,发展了计算混合液体导热系数的新方法。对288种含水和非水液体混合物2060个数据点的拟合结果表明,计算值与实验值的一致性令人满意,平均误差0．98％,计算精度优于献方法。据此发展了一种根据纯物质导热系数预测混合液体导热系数的方法,预测结果的平均误差为1．69％,小于献方法的误差。     

液体混合物的导热系数与汽液平衡之间的关系

将统计热力学模型与作者建立的传热反应速率理论相结合，通过液体混合物中分子间的相互作用能、分子的大小和形状，将液体混合物的导热系数与汽液平衡相互联系起来，使这两类液体混合物的性质统一到分子间相互作用能、分子的大小和形状这一液体混合物的共性上，对这两类性质进行统一的描述，研究这两类性质之间的关系。对１１对二元体系根据液体混合物的导热系数对汽液平衡进行了推算。结果表明，所建立的液体混合物的模型能够描述它们的导热系数与汽液平衡之间的相互关系。     

烟草导热系数与含水率的变化关系

推导出了烟草导热系数与湿基含水率的关系式，并用实验测定值检测了推算式的精度。对于烟叶堆积床，推算值与实验测定值的绝对平均偏差为1．75％，算术平均偏差为0．15％；对于烟丝堆积床，推算值与实验测度值的绝对平均偏差为2．36％，算术平均偏差为0．25％。其精度均满足工程需求。该关系式也可推广应用于其他含湿多孔介质导热系数的计算。     

焦化炉管焦导热系数的测定

从现场焦化炉中截取一段结焦炉管,采用热通量法测定了炉管结焦层的导热系数.实验表明,当温度为50～100℃时,管焦导热系数随温度的升高而迅速降低;当温度为100～550℃时,随着温度的升高,管焦导热系数降低的速度逐渐减缓,并最终稳定在3.8W/(m@℃),实验误差不超过10%.对实验数据进行多项式线性回归,得到了管焦导热系数随温度变化的回归方程,该方程的相对误差低于4%.     

Markedness and its Interpretation in Language Use

Language markedness is a common phenomenon in languages, and is reflected from hearing, vision and sense, i.e. the variation in the three aspects such as phonology, morphology and semantics. This paper focuses on the interpretation of markedness in language use following the three perspectives, i.e. pragmatic interpretation, psychological interpretation and cognitive interpretation, with an aim to define the function of markedness.     

Features of Women's language

Language is a means of verbal communication. People use language to communicate with each other. In the society, no two speakers are exactly alike in the way of speaking. Some differences are due to age, gender, statue and personality. Above all, gender is one of the obvious reasons. The writer of this paper tries to describe the features of women＇s language from these perspectives： pronunciation, intonation, diction, subjects, grammar and discourse. From the discussion of the features of women＇s language, more attention should be paid to language use in social context. What＇s more, the linguistic phenomena in a speaking community can be understood more thoroughly.     

低渗透非均质砂岩油藏启动压力梯度研究

理论推导与室内实验相结合,建立了低渗透非均质砂岩油藏启动压力梯度确定方法。首先借助油藏流场与电场相似的原理,推导了非均质砂岩油藏启动压力梯度计算公式。其次基于稳定流实验方法,建立了非均质砂岩油藏启动压力梯度测试方法。结果表明:低渗透非均质砂岩油藏的启动压力梯度确定遵循两个等效原则。平面非均质油藏的启动压力梯度等于各级渗透率段的启动压力梯度关于长度的加权平均;纵向非均质油藏的启动压力梯度等于各渗透率层的启动压力梯度关于渗透率与渗流面积乘积的加权平均。研究成果可用于有效指导低渗透非均质砂岩油藏的合理井距确定,促进该类油藏的高效开发。     

On Tragic Consciousness In The Works By Ernest Hemingway

As an American modern novelist who were famous in the literary world, Hemingway was not a person who always followed the trend but a sharp observer. At the same time, he was a tragedy maestro, he paid great attention on existence, fate and end-result. The dramatis personae's tragedy of his works was an extreme limit by all means tragedy on the meaning of fearless challenge that failed. The beauty of tragedy was not produced on the destruction of life, but now this kind of value was in the impact activity. They performed for the reader about the tragedy on challenging for the limit and the death.     

Achieving Unusual States of Matter Under High Pressure

正The periodicity of the elements and the non-reactivity of the inner-shell electrons are two related principles of chemistry,rooted in the atomic shell structure.Within compounds,Group I elements,for example,invariably assume the+1 oxidation state,and their chemical properties differ completely from those of the p-block elements.These general rules govern our understanding of chemical structures and reactions.Using first principles calcula-     

Exchange-Correlation and Electronic Excitation Energies from Pairing Matrix Fluctuations

We have developed an adiabatic connection to formulate the ground-state exchange-correlation energy in terms of pairing matrix linear fluctuations.This formulation of the exchange-correlation energy opens a new channel for density functional approximations based on the many-body perturbation theory.We illustrate the potential of such approaches with an approximation based on the particle-particle Random Phase Approximation(pp-RPA).This re-     

Density Functional Theory for the Response of Periodic Systems to Electric Fields Based on the Vector Potential Approach

正The electronic and nuclear(structural/vibrational)response of 1D-3D nanoscale systems to electric fields gives rise to a host of optical,mechanical,spectral,etc.properties that are of high theoretical and applied interest.Due to the computational difficulty of treating such large systems it is convenient to model them as infinite and periodic(at least,in first approximation).The fundamental theoretical/computational problem in doing so is that     

On the Thermodynamic Limit for Responses to Static Electromagnetic Fields

For molecular systems,the quantum-mechanical treatment of their responses to static electromagnetic fields usually employs a scalar-potential treatment of the electric field and a vector-potential treatment of the magnetic field.Although the potential for each field separately is associated with the choice of an(unphysical)origin,the precise choice of the origin for the electrostatic field has little consequences for the results.This is different for the     

An affordable accurate evaluation of the binding conformations predicted by molecular docking studies in bio-system

Franck-Condon factors bridge the gap between theoretical modeling and experimental observations for molecular electronic spectroscopy and electron transfer.Under the displaced harmonic oscillator approximation,multidimensional Franck-Condon factors are decomposed into a product of many one-dimensional(1D)Franck-Condon(FC)factors,and each 1D-FC factor is associated with one Huang-Rhys factor that determines the leading contribution of     

Call for Papers

<正>"The Journal of Shanghai Normal University:Mathematics"is published by Shanghai Normal University as regular issues of The Journal of Shanghai Normal University each year from 2014 in English.The editors-in-chief of the issues are professors Yuhao Cong and Maoan Han.The Journal of Shanghai Normal University was started in 1958 with