广绿玉玉石的矿物学研究

 广绿玉产于广东省广宁县,是一种富有特色的珍贵玉石材料。对绿、白、黄、黑等4类典型广绿玉原料,采用X射线粉末衍射、扫描电镜、红外光谱、差热分析、电子探针等多种方法,对玉石的全岩物相、主矿物显微形貌、矿物化学及晶体结构等进行了分析。结果表明,广绿玉主要由2M1型绢云母组成,部分品种含有绿泥石和石英等。乙二醇饱和处理X射线粉末衍射和红外光谱分析显示绢云母结构中不含蒙脱石间层;差热分析显示玉石在中温区吸热谷的脱羟极值温度大于600 ℃,与水云母明显不同;扫描电镜显示绢云母类单矿物的微形貌多呈鳞片状,矿物排列组合沿长轴顺层穿插和定向交织,表现为叠层状或鳞片交织状微结构;电子探针成分分析表明绢云母矿物化学成分中Si、K、Al、Cr等含量较高,部分属含铬绢云母亚类,Cr可能是绿色和白色广绿玉的主要致色元素。     

基于高光谱技术的钻孔岩心蚀变信息研究:以新疆白杨河铀矿床为例

新疆白杨河矿床是近年来发现的亚洲最大的次火山岩型铀铍矿床。应用美国ASD可见光—短波红外地面光谱仪对新疆白杨河铀矿床的三个钻孔进行全孔岩心光谱测量与分析,确定了矿体中热液蚀变矿物主要有高铝绢云母、中铝绢云母、低铝绢云母、绿泥石、蒙脱石、碳酸盐、赤铁矿和褐铁矿等。铀矿化富集部位的蚀变矿物组合为高铝绢云母+中铝绢云母+绿泥石(+少量高岭石与碳酸盐)+赤铁矿,铀矿化主要与赤铁矿化、高铝绢云母和中铝绢云母有关,尤其可能是三者共同存在的地段更是铀成矿的有利地段,这可以为白杨河矿床深部铀矿勘探提供参考与借鉴。同时,区域铀矿找矿中,要注意强烈发育低铝绢云母蚀变与高铝绢云母蚀变的过渡带,要注意有基性岩脉发育的地段,这些地段是铀矿找矿的有利地段。     

吉林哈福瓷石矿矿物岩石特征的研究

本文采用系统的实验资料,较详细研究了吉林哈福瓷石矿的矿物岩石特征,其中包括差热及热失重特征,X射线衍射特征,红外吸收光谱特征,电子探针及电镜特征等。研究结果表明:矿石主要由水云母(含少量绢云母)、石英及少量蒙脱石组成,其中水云母占30-50％,石英占50-70％;化学成分与南方瓷石相比,具有SiO_2偏高,AiO_3、K_2O偏低的特点;它是在相对封闭的系统中,在中性到弱碱性的中低温热液条件下,由集细斑岩蚀变而成,并测得矿石包体平均均一温度为138℃,包体气液的PH值约等于7。因此,哈福瓷石是一种独具特色的岩石——水云母绢英岩;矿石可作为腊质代用原料和日用、工业陶瓷的原料及釉面砖原料。     

APTES湿法修饰对绢云母粉末粗糙表面张力的影响

对绢云母(Sericite)粉末进行硅烷偶联剂湿法处理,采用Washburn 法测量了经不同浓度的硅烷偶联剂修饰后的绢云母粉末的表面张力.修饰后的绢云母粉末的表面张力具有周期性的变化,且波峰与波谷随着3-氨基丙基三乙氧基硅烷(APTES)用量的增加而增大.利用比表面仪(BET)和激光粒度仪,获得绢云母粉末表面的粗糙度为17.5,且根据Wenzel 和 Cassie复合方程,获得液体与粗糙表面接触的投影面积分数f2为0.103,在绢云母粉末表面的单分子层APTES密度为1.82×1018 个/m2.     

走自主创新之路提升企业竞争力

滁州格锐矿业有限责任公司是一家民营科技型企业,也是安徽省高新技术企业,主营各类非金属矿功能新材料的研发和生产.公司主导产品为GR复合钛白颜料和湿法超细绢云母材料,其中GR复合钛白颜料在国内外首次实现复合钛白的产业化生产,目前尚为国内独家生产;湿法超细绢云母材料独家采用湿法超细提纯工艺,产品现已占据国内涂料用高档绢云母市场的70%以上.     

高径厚比超细改性绢云母鳞片的研制

采用超音速气流粉碎方法对绢云母进行超细粉碎,通过控制进口压力、工作压力和进料速度可生产出不同粒度、径厚比的绢云母超细粉(鳞片),采用硅烷偶联剂对超细绢云母进行表面化学改性,通过对径厚比、改性绢云母填充量等变量的研究,探讨改性绢云母增强尼龙6力学性能的变化规律．实验结果表明,高径厚比改性绢云母增强尼龙6的力学性能有显著的提高。     

湖南某地页岩成分及物理性能分析

针对湖南省某地有储量巨大的铁质页岩原矿,为有效利用该矿产资源,用X线衍射仪、电感耦合等离子体发射光谱仪(ICP-AES)、红外光谱仪、防护热板导热系数测量装置、辐射仪对页岩成分和物理性能进行检测分析,研究2种焙烧工艺参数下的页岩烧胀性.研究结果表明:该页岩含有绿泥石、高岭石、蒙脱石和绢云母等多种层状硅酸盐矿物及Al,Fe,Mg,K和Na多种金属元素,在中远红外波段具有较高的反射率,烧胀性良好,其涂层的导热系数为0.045 W/(m·K),内、外照射系数分别为0.27和0.69;该页岩在建筑陶粒材料、保温隔热涂料等方面具有广阔的应用前景.     

有机活性绢云母填充量对尼龙6 力学性能的影响

采用硅烷偶联剂对绢云母表面进行化学处理,并将其作为尼龙6的填充剂,通过改变活性绢云母填充量,研究增强尼龙6的力学性能．探讨硅烷偶联剂对绢云母的影响机理,分析活性绢云母填充量对尼龙6力学性能的影响规律．实验结果表明,活性绢云母填充绢云母填充尼龙6后的力学性能有显著的改善,活性绢云母填充尼龙6的数量存在着一个最佳值．     

绢云母增强无机硅酸锌涂料耐蚀抗磨性及耐水性

 研究探讨了绢云母在无机硅酸锌涂料中添加改性的应用,采用极化曲线、干磨损实验、浸泡及水冲刷实验等测试手段,对比考察了添加绢云母前后涂层的腐蚀特性、摩擦磨损及耐水性能。结果表明,绢云母具有的良好耐腐蚀性能,以及绢云母与腐蚀产物一起对涂层孔隙的协同填塞作用,降低了涂层的腐蚀速率;绢云母的层片状结构降低了涂层的摩擦系数,减轻了涂层的塑性变形,阻止了涂层内部裂纹的产生和扩展,增强涂层耐磨性能;绢云母的添加可以促使涂层内部形成一种致密的层网状结构,增加了涂层的致密性、抗渗透性和涂层强度,从而提高了涂层的耐水性。     

利用聚合氯化铝降低隐石墨浮选过程中绢云母脉石的夹带

利用聚合氯化铝(PACl)凝聚绢云母降低其泡沫夹带。研究结果表明:绢云母的粒径不仅影响精矿的水回收率,而且严重地影响绢云母的夹带回收率。在自然p H条件下,PACl水解产生的快速反应聚合物Alb、不反应的胶体物质Alc分别通过电中和机制及絮凝机制有效地选择性凝聚绢云母。PACl质量浓度为200 mg/L时,隐石墨浮选精矿的水回收率及灰分分别从空白实验的34%和24.5%降低到23%和16.8%。PACl能选择性地凝聚绢云母,有效降低绢云母的泡沫夹带,改善隐石墨浮选选择性。     

Markedness and its Interpretation in Language Use

Language markedness is a common phenomenon in languages, and is reflected from hearing, vision and sense, i.e. the variation in the three aspects such as phonology, morphology and semantics. This paper focuses on the interpretation of markedness in language use following the three perspectives, i.e. pragmatic interpretation, psychological interpretation and cognitive interpretation, with an aim to define the function of markedness.     

Features of Women's language

Language is a means of verbal communication. People use language to communicate with each other. In the society, no two speakers are exactly alike in the way of speaking. Some differences are due to age, gender, statue and personality. Above all, gender is one of the obvious reasons. The writer of this paper tries to describe the features of women＇s language from these perspectives： pronunciation, intonation, diction, subjects, grammar and discourse. From the discussion of the features of women＇s language, more attention should be paid to language use in social context. What＇s more, the linguistic phenomena in a speaking community can be understood more thoroughly.     

低渗透非均质砂岩油藏启动压力梯度研究

理论推导与室内实验相结合,建立了低渗透非均质砂岩油藏启动压力梯度确定方法。首先借助油藏流场与电场相似的原理,推导了非均质砂岩油藏启动压力梯度计算公式。其次基于稳定流实验方法,建立了非均质砂岩油藏启动压力梯度测试方法。结果表明:低渗透非均质砂岩油藏的启动压力梯度确定遵循两个等效原则。平面非均质油藏的启动压力梯度等于各级渗透率段的启动压力梯度关于长度的加权平均;纵向非均质油藏的启动压力梯度等于各渗透率层的启动压力梯度关于渗透率与渗流面积乘积的加权平均。研究成果可用于有效指导低渗透非均质砂岩油藏的合理井距确定,促进该类油藏的高效开发。     

On Tragic Consciousness In The Works By Ernest Hemingway

As an American modern novelist who were famous in the literary world, Hemingway was not a person who always followed the trend but a sharp observer. At the same time, he was a tragedy maestro, he paid great attention on existence, fate and end-result. The dramatis personae's tragedy of his works was an extreme limit by all means tragedy on the meaning of fearless challenge that failed. The beauty of tragedy was not produced on the destruction of life, but now this kind of value was in the impact activity. They performed for the reader about the tragedy on challenging for the limit and the death.     

Achieving Unusual States of Matter Under High Pressure

正The periodicity of the elements and the non-reactivity of the inner-shell electrons are two related principles of chemistry,rooted in the atomic shell structure.Within compounds,Group I elements,for example,invariably assume the+1 oxidation state,and their chemical properties differ completely from those of the p-block elements.These general rules govern our understanding of chemical structures and reactions.Using first principles calcula-     

Exchange-Correlation and Electronic Excitation Energies from Pairing Matrix Fluctuations

We have developed an adiabatic connection to formulate the ground-state exchange-correlation energy in terms of pairing matrix linear fluctuations.This formulation of the exchange-correlation energy opens a new channel for density functional approximations based on the many-body perturbation theory.We illustrate the potential of such approaches with an approximation based on the particle-particle Random Phase Approximation(pp-RPA).This re-     

Density Functional Theory for the Response of Periodic Systems to Electric Fields Based on the Vector Potential Approach

正The electronic and nuclear(structural/vibrational)response of 1D-3D nanoscale systems to electric fields gives rise to a host of optical,mechanical,spectral,etc.properties that are of high theoretical and applied interest.Due to the computational difficulty of treating such large systems it is convenient to model them as infinite and periodic(at least,in first approximation).The fundamental theoretical/computational problem in doing so is that     

On the Thermodynamic Limit for Responses to Static Electromagnetic Fields

For molecular systems,the quantum-mechanical treatment of their responses to static electromagnetic fields usually employs a scalar-potential treatment of the electric field and a vector-potential treatment of the magnetic field.Although the potential for each field separately is associated with the choice of an(unphysical)origin,the precise choice of the origin for the electrostatic field has little consequences for the results.This is different for the     

An affordable accurate evaluation of the binding conformations predicted by molecular docking studies in bio-system

Franck-Condon factors bridge the gap between theoretical modeling and experimental observations for molecular electronic spectroscopy and electron transfer.Under the displaced harmonic oscillator approximation,multidimensional Franck-Condon factors are decomposed into a product of many one-dimensional(1D)Franck-Condon(FC)factors,and each 1D-FC factor is associated with one Huang-Rhys factor that determines the leading contribution of     

Call for Papers

<正>"The Journal of Shanghai Normal University:Mathematics"is published by Shanghai Normal University as regular issues of The Journal of Shanghai Normal University each year from 2014 in English.The editors-in-chief of the issues are professors Yuhao Cong and Maoan Han.The Journal of Shanghai Normal University was started in 1958 with