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1.
利用半夏-丙酮-MnSO4-KBrO3-H2SO4化学振荡体系对中草药半夏的化学振荡行为进行了研究,探讨了半夏的质量、粒度及振荡体系的酸度、温度、搅拌速度等因素对振荡反应的影响.同时,分析了半夏-丙酮-MnSO4-KBrO3-H2SO4化学振荡体系中丙酮和KBrO3的作用,推测了半夏参与化学振荡的可能机理.  相似文献   

2.
根据FKN振荡机理,报道了氨基乙酸-溴酸钾-硫酸锰-硫酸-丙酮体系的化学振荡反应,对振荡的影响因素进行了研究和讨论.确立了振荡反应进行的有效浓度范围,获得振荡的诱导期和周期与反应物浓度之间的经验式,振荡反应的表现活化能,建立振荡反应模型和反应机理,为振荡反应过程和机理研究提供一些实验依据.  相似文献   

3.
酒石酸—溴酸钾—硫酸锰—硫酸—丙酮体系的振荡反应   总被引:1,自引:0,他引:1  
根据FKN振荡机理,本文报道酒石酸-溴酸钾-硫酸锰-硫酸-丙酮体系的化学振荡反应,对振荡的影响因素进行了研究和讨论。  相似文献   

4.
本文选用丙二酸(MA)-KBrO3-MnS4-H2SO4作标准化学振荡器进行人血清对化学振荡的影响研究.对标准振荡器的选择、加样方式作了分析,并探讨了人血清影响化学振荡的机理.  相似文献   

5.
本文报道了苯酚——溴酸钾——硫酸体系的非催化化学振荡反应,研究了反应物浓度,反应温度、氯离子、自由基抑制剂(丙烯腈)等多种因素对化学振荡反应的影响,计算了反应活化能,分析了非催化反应的产物,研究了经典 Belousov—Zhabotinsky 振荡反应中常作为催化剂的金属离子(如 Mn~(2-),Ce~(2+)等)对非催化振荡反应的影响,最后对非催化反应的催化机理及控制机理作了初步探讨  相似文献   

6.
乳酸-葡萄糖双组份有机底物的B-Z振荡反应   总被引:1,自引:0,他引:1  
以乳酸和葡萄糖混合物的双组份有机物作为B-Z化学振荡反应底物,在KBrO3-MnSO4-H2SO4-丙酮环境中进行化学振荡反应.通过研究确定该双组份有机底物的振荡体系出现化学振荡现象的各反应物的有效浓度范围,并系统地研究和讨论影响化学振荡的诱导期、周期、振幅、图形和寿命等诸多因素.提供化学振荡现象的实验依据,推断化学反应的过程,建立化学振荡反应的模型,为B-Z化学振荡反应体系增添新的研究领域.  相似文献   

7.
研究报道了邻菲啰啉合铁(Ⅱ)催化下的化学振荡反应,对振荡的影响因素进行了研究和讨论.运用正交实验法确立了振荡反应进行的有效浓度范围.获得振荡的诱导期和周期与反应物浓度之间的变化趋势曲线,以及振荡反应在诱导期和振荡期的表观活化能.根据反应过程中的现象和实验数据,建立了振荡反应的模型和反应机理,进而为反应过程和机理研究提供一些实验依据.  相似文献   

8.
本文对Lotka—Volterra提出的自催化振荡模型机理进行动力学分析,看化学振荡的线性和非线性特征。  相似文献   

9.
非平衡态非线性化学——化学振荡   总被引:1,自引:0,他引:1  
概述了化学振荡的发展历程,从化学热力学和化学动力学两个方面对比化学振荡进行了研究和分析,得出振荡体系呈现非线性化学动力学特性,并从化学振荡产生的条件及其应用归纳、整理、剖析了化学振荡研究的意义,展望了化学振荡的未来。  相似文献   

10.
以酒石酸和葡萄糖混合物的双组份有机物作为B-Z化学振荡反应底物,在KBrO3-MnSO4-H2SO4-丙酮环境中进行化学振荡反应.通过研究确定该双组份有机底物的振荡体系出现化学振荡现象的各反应物的有效浓度范围,并系统地研究和讨论影响化学振荡的诱导期、周期、振幅、图形和寿命等诸多因素.提供化学振荡现象的实验依据,推断化学反应的过程,建立化学振荡反应的模型,为B-Z化学振荡反应体系增添新的内容.  相似文献   

11.
Language markedness is a common phenomenon in languages, and is reflected from hearing, vision and sense, i.e. the variation in the three aspects such as phonology, morphology and semantics. This paper focuses on the interpretation of markedness in language use following the three perspectives, i.e. pragmatic interpretation, psychological interpretation and cognitive interpretation, with an aim to define the function of markedness.  相似文献   

12.
何延凌 《科技信息》2008,(4):258-258
Language is a means of verbal communication. People use language to communicate with each other. In the society, no two speakers are exactly alike in the way of speaking. Some differences are due to age, gender, statue and personality. Above all, gender is one of the obvious reasons. The writer of this paper tries to describe the features of women's language from these perspectives: pronunciation, intonation, diction, subjects, grammar and discourse. From the discussion of the features of women's language, more attention should be paid to language use in social context. What's more, the linguistic phenomena in a speaking community can be understood more thoroughly.  相似文献   

13.
理论推导与室内实验相结合,建立了低渗透非均质砂岩油藏启动压力梯度确定方法。首先借助油藏流场与电场相似的原理,推导了非均质砂岩油藏启动压力梯度计算公式。其次基于稳定流实验方法,建立了非均质砂岩油藏启动压力梯度测试方法。结果表明:低渗透非均质砂岩油藏的启动压力梯度确定遵循两个等效原则。平面非均质油藏的启动压力梯度等于各级渗透率段的启动压力梯度关于长度的加权平均;纵向非均质油藏的启动压力梯度等于各渗透率层的启动压力梯度关于渗透率与渗流面积乘积的加权平均。研究成果可用于有效指导低渗透非均质砂岩油藏的合理井距确定,促进该类油藏的高效开发。  相似文献   

14.
As an American modern novelist who were famous in the literary world, Hemingway was not a person who always followed the trend but a sharp observer. At the same time, he was a tragedy maestro, he paid great attention on existence, fate and end-result. The dramatis personae's tragedy of his works was an extreme limit by all means tragedy on the meaning of fearless challenge that failed. The beauty of tragedy was not produced on the destruction of life, but now this kind of value was in the impact activity. They performed for the reader about the tragedy on challenging for the limit and the death.  相似文献   

15.
正The periodicity of the elements and the non-reactivity of the inner-shell electrons are two related principles of chemistry,rooted in the atomic shell structure.Within compounds,Group I elements,for example,invariably assume the+1 oxidation state,and their chemical properties differ completely from those of the p-block elements.These general rules govern our understanding of chemical structures and reactions.Using first principles calcula-  相似文献   

16.
We have developed an adiabatic connection to formulate the ground-state exchange-correlation energy in terms of pairing matrix linear fluctuations.This formulation of the exchange-correlation energy opens a new channel for density functional approximations based on the many-body perturbation theory.We illustrate the potential of such approaches with an approximation based on the particle-particle Random Phase Approximation(pp-RPA).This re-  相似文献   

17.
正The electronic and nuclear(structural/vibrational)response of 1D-3D nanoscale systems to electric fields gives rise to a host of optical,mechanical,spectral,etc.properties that are of high theoretical and applied interest.Due to the computational difficulty of treating such large systems it is convenient to model them as infinite and periodic(at least,in first approximation).The fundamental theoretical/computational problem in doing so is that  相似文献   

18.
For molecular systems,the quantum-mechanical treatment of their responses to static electromagnetic fields usually employs a scalar-potential treatment of the electric field and a vector-potential treatment of the magnetic field.Although the potential for each field separately is associated with the choice of an(unphysical)origin,the precise choice of the origin for the electrostatic field has little consequences for the results.This is different for the  相似文献   

19.
<正>"The Journal of Shanghai Normal University:Mathematics"is published by Shanghai Normal University as regular issues of The Journal of Shanghai Normal University each year from 2014 in English.The editors-in-chief of the issues are professors Yuhao Cong and Maoan Han.The Journal of Shanghai Normal University was started in 1958 with  相似文献   

20.
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