| 强耦合非晶态Sb2S3球与碳纳米管中的钠离子和锂离子存储 |
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| 引用本文： | Qiong Jiang,Wen-qi Zhang,Jia-chang Zhao,Pin-hua Rao,Jian-feng Mao. 强耦合非晶态Sb2S3球与碳纳米管中的钠离子和锂离子存储[J]. 矿物冶金与材料学报, 2021, 28(7): 1194-1203. DOI: 10.1007/s12613-021-2259-5 |
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| 作者姓名： | Qiong Jiang Wen-qi Zhang Jia-chang Zhao Pin-hua Rao Jian-feng Mao |
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| 作者单位： | 1)School of Chemistry and Chemical Engineering, Shanghai University of Engineering Science, Shanghai 201620, China |
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| 摘 要： | A facile one-step strategy involving the reaction of antimony chloride with thioacetamide at room temperature is successfully developed for the synthesis of strongly coupled amorphous Sb2S3 spheres and carbon nanotubes (CNTs). Benefiting from the unique amorphous structure and its strongly coupled effect with the conductive network of CNTs, this hybrid electrode (Sb2S3@CNTs) exhibits remarkable sodium and lithium storage properties with high capacity, good cyclability, and prominent rate capability. For sodium storage, a high capacity of 814 mAh·g?1 at 50 mA·g?1 is delivered by the electrode, and a capacity of 732 mAh·g?1 can still be obtained after 110 cycles. Even up to 2000 mA·g?1, a specific capacity of 584 mAh·g?1 can be achieved. For lithium storage, the electrode exhibits high capacities of 1136 and 704 mAh·g?1 at 100 and 2000 mA·g?1, respectively. Moreover, the cell holds a capacity of 1104 mAh·g?1 under 100 mA·g?1 over 110 cycles. Simple preparation and remarkable electrochemical properties make the Sb2S3@CNTs electrode a promising anode for both sodium-ion (SIBs) and lithium-ion batteries (LIBs).
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| 关 键 词： | ; ; ; ; |
Superior sodium and lithium storage in strongly coupled amorphous Sb2S3 spheres and carbon nanotubes |
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| Qiong Jiang,Wen-qi Zhang,Jia-chang Zhao,Pin-hua Rao,Jian-feng Mao. Superior sodium and lithium storage in strongly coupled amorphous Sb2S3 spheres and carbon nanotubes[J]. International Journal of Minerals,Metallurgy and Materials, 2021, 28(7): 1194-1203. DOI: 10.1007/s12613-021-2259-5 |
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| Authors: | Qiong Jiang Wen-qi Zhang Jia-chang Zhao Pin-hua Rao Jian-feng Mao |
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| Abstract: | A facile one-step strategy involving the reaction of antimony chloride with thioacetamide at room temperature is successfully de-veloped for the synthesis of strongly coupled amorphous Sb2S3 spheres and carbon nanotubes (CNTs). Benefiting from the unique amorphous structure and its strongly coupled effect with the conductive network of CNTs, this hybrid electrode (Sb2S3@CNTs) exhibits remarkable sodi-um and lithium storage properties with high capacity, good cyclability, and prominent rate capability. For sodium storage, a high capacity of 814 mAh·g-1 at 50 mA·g-1 is delivered by the electrode, and a capacity of 732 mAh·g-1 can still be obtained after 110 cycles. Even up to 2000 mA·g-1, a specific capacity of 584 mAh·g-1 can be achieved. For lithium storage, the electrode exhibits high capacities of 1136 and 704 mAh·g-1 at 100 and 2000 mA·g-1, respectively. Moreover, the cell holds a capacity of 1104 mAh·g-1 under 100 mA·g-1 over 110 cycles. Simple preparation and remarkable electrochemical properties make the Sb2S3@CNTs electrode a promising anode for both sodium-ion (SIBs) and lithium-ion batteries (LIBs). |
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| Keywords: | amorphous antimony sulfide spheres carbon nanotubes sodium-ion batteries lithium-ion batteries electrochemical performance |
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