| (C_2H_(10)N_2)[Mo_3O_(10)]配合物的水热合成与晶体结构 |
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| 引用本文： | 苏方勇,邓剑平,李勇民.(C_2H_(10)N_2)[Mo_3O_(10)]配合物的水热合成与晶体结构[J].哈尔滨师范大学自然科学学报,2010,26(5):60-62. |
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| 作者姓名： | 苏方勇 邓剑平 李勇民 |
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| 作者单位： | 黑龙江经济管理干部学院 |
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| 摘 要： | 以乙二胺为模板,利用水热技术合成了具有链状结构的新型配合物(C2H10N2)Mo3O10].晶体的X射线衍射分析结果表明,配合物(C2H10N2)Mo3O10]为单斜晶系,其晶胞参数为:a=8.0865(2),b=14.4902(2),c=8.9306(2),β=98.170(1)°,Z=4.(C2H10N2)Mo3O10]由扭曲的MoO6八面体通过共顶点、共边、共面形成平行于a轴的平行长链而形成,乙二胺游离在该链之外,同时并对配合物的热稳定性和电化学性质进行了研究.
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| 关 键 词： | 配合物 水热合成 晶体结构 |
Hydrothermal Synthesis and Crystalline Structure of Coordination Compound(C2 H10 N2) [Mo3O10] |
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| Su Fangyong,Deng Jianping,Li Yongmin.Hydrothermal Synthesis and Crystalline Structure of Coordination Compound(C2 H10 N2) [Mo3O10][J].Natural Science Journal of Harbin Normal University,2010,26(5):60-62. |
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| Authors: | Su Fangyong Deng Jianping Li Yongmin |
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| Institution: | (Heilongjiang Institute of Economic Administrators) |
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| Abstract: | A novel coordination compound of （C2H10N2）Mo3O10] was synthesized With ethylenediamine trimolybdate by hydrothermal methad.It crystallizes in the monoclinic system with a = 8.0865（2）,b = 14.4902（2） ,c=8.9306（2）,β = 98.170（1） °,and Z = 4.Its structure consists of hitherto un-known infnite chains running parallel to the a axis made up of distorted MoO6 octahedra connected by corners,edges,and faces. |
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| Keywords: | Coordination compounds Hydrothermal Synthesis Crystalline structure |
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