| 甲烷二氧化碳转化制合成气稀土助剂抗积炭性能的研究 |
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| 引用本文： | 宫丽红,史克英,徐恒泳,孙希贤,徐国林.甲烷二氧化碳转化制合成气稀土助剂抗积炭性能的研究[J].哈尔滨师范大学自然科学学报,1999(2). |
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| 作者姓名： | 宫丽红 史克英 徐恒泳 孙希贤 徐国林 |
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| 作者单位： | 哈尔滨师范大学 |
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| 摘 要： | 利用脉冲微型反应色谱装置研究了Ｎｉ－２，Ｎｉ－２－Ｃｅ，Ｎｉ－２－Ｃｅ－Ｍｇ催化剂ＣＨ４脱氢和ＣＯ２消炭反应，结果表明：ＣｅＯ２能够抑制甲烷脱氢积炭反应，增加催化剂表面炭的活性，同时提高ＣＯ２的消炭能力．ＸＲＤ研究表明，加入ＣｅＯ２和ＭｇＯ助剂后，能够提高Ｎｉ的分散度，从而使Ｎｉ－２－Ｃｅ－Ｍｇ具有高活性、选择性而且具有很高的抗积炭性能和稳定性．
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| 关 键 词： | 稀土助剂 催化剂的抗积炭性能 CH_4脱氢 CO_2消炭 |
STUDIES OF REFORMING METHANE WITH CARBON DIOXIDE TO PRODUCE SYNTHESIS
GASSTUDIES OF RARE EARTH PROMOTER RESISTANCE TO CARBON DEPOSITION |
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| Gong,Lihong Shi Keying Xu Hengyong Su Xixian Xu Guolin.STUDIES OF REFORMING METHANE WITH CARBON DIOXIDE TO PRODUCE SYNTHESIS
GASSTUDIES OF RARE EARTH PROMOTER RESISTANCE TO CARBON DEPOSITION[J].Natural Science Journal of Harbin Normal University,1999(2). |
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| Authors: | Gong Lihong Shi Keying Xu Hengyong Su Xixian Xu Guolin |
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| Institution: | Harbin Normal University |
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| Abstract: | The
reaction of methane dehydrogenation carbon dioxide elimination was studied by using a
fixed-bed pulse reactor chromatography.The results showed that CeO 2 could inhibit carbon
deposition of methane dehydrognation,enhance the activity on the surface of catalyst and
increase the ability of carbon dioxide elimination. The studies of XRD showed that existence of
CeO 2 and MgO could improve dispersing degree of Ni,thus making Ni-2-Ce-Mg having not only
high activity and selectivity,but also high stability and good resistance to carbon deposition for
reforming methane with carbon dioxide. |
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| Keywords: | Rare earth promoter Resistance to carbon deposition of catalyst Methane dehydrogenation Carbon dioxide elimination |
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