| PEO大单体与MMA溶液自由基共聚反应研究 |
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| 引用本文： | 刘锦,谢洪泉.PEO大单体与MMA溶液自由基共聚反应研究[J].湘潭大学自然科学学报,1995(4). |
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| 作者姓名： | 刘锦 谢洪泉 |
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| 作者单位： | 湘潭大学化学系，华中理工大学化学系 |
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| 摘 要： | 本工作研究了末端为甲基丙烯酸酯型的聚环氧乙烷（ＰＥＯ）大分子单体与甲基丙烯酸甲酯（ＭＭＡ）溶液自由基共聚反应．结果表明，大单体的接枝效率及接枝共聚物的分子量与大单体的投料量及分子量、引发剂的含量、溶剂用量、共聚反应温度及时间有关．
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| 关 键 词： | 大分子单体，聚环氧乙烷，自由基共聚，接枝效率 |
A STUDY OF COPOLYMERIZATION CONDITIONS OF POLYOXYETHYLENE MACROMERS WITH MMA |
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| Liu Jin,Xie Hongquan.A STUDY OF COPOLYMERIZATION CONDITIONS OF POLYOXYETHYLENE MACROMERS WITH MMA[J].Natural Science Journal of Xiangtan University,1995(4). |
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| Authors: | Liu Jin Xie Hongquan |
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| Abstract: | Copolymerization conditions of w-methacryloyl polyoxyethylene macromers with methyl(MMA)in benzene using AIBN as initiator was studied. The effects of molecular weight of the macromers, charging ratio of the macromer to MMA, polymerization temperature, total monomer concentration and amount of initiator on the grafting efficiency and molecular weight of the copolymers were reported. |
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| Keywords: | macromer polyoxyethylene radical copolymerization grafting efficing |
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