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混合元素掺杂对Sr_2MgSi_2O_7蓝色长余辉发光材料的影响
引用本文:戴树东,陈英,余金,周文华,林燕美,陈国良,郑子山.混合元素掺杂对Sr_2MgSi_2O_7蓝色长余辉发光材料的影响[J].漳州师院学报,2010(3):62-65.
作者姓名:戴树东  陈英  余金  周文华  林燕美  陈国良  郑子山
作者单位:漳州师范学院化学与环境科学系,福建漳州363000
基金项目:福建省教育厅科技项目(JB08184); 福建省科技厅资助项目(2010H6029 2007F5096); 福建省高校服务海西建设重点项目
摘    要:采用溶胶-凝胶法合成了不同元素混合掺杂Sr2MgSi2O7系列蓝色长余辉发光材料,并对其发光性能进行研究,探讨掺杂元素对材料发光性能的影响规律性.激发发射光谱实验表明其峰均为宽带峰,最大发射峰位于466nm附近,是由典型的Eu2+的4f5d-4f跃迁导致的.所合成的Eu2+,Dy3共掺杂发光材料Sr2MgSi2O7余辉时间可达8hrs以上,具有合适的能级陷阱0.76eV.

关 键 词:溶胶一凝胶法  长余辉  发光材料  Sr2MgSi2O7

Influence of Mixed-element Dopant on the Luminescent Properties of Blue Long Afterglow Materials of Sr_2MgSi_2O_7
DAI Shu-dong,CHEN Ying,CHEN Ying,YU Jin,ZHOU Wen-hua,LIN Yan-mei,CHEN Guo-liang,ZHENG Zi-shan.Influence of Mixed-element Dopant on the Luminescent Properties of Blue Long Afterglow Materials of Sr_2MgSi_2O_7[J].Journal of ZhangZhou Teachers College(Philosophy & Social Sciences),2010(3):62-65.
Authors:DAI Shu-dong  CHEN Ying  CHEN Ying  YU Jin  ZHOU Wen-hua  LIN Yan-mei  CHEN Guo-liang  ZHENG Zi-shan
Institution:(Department of Chemistry and Environmental Science,Zhangzhou Normal University,Zhangzhou,Fujian 363000,China)
Abstract:The sol-gel synthesis was used to prepare long afterglow blue luminescent materials of mixed-elements doped Sr2MgSi2O7.Their luminescent properties were investigated to find the regularity of the influence of mixed-element dopant on the luminescent properties of Sr2MgSi2O7.The excitation and emission spectra show broadband peaks.The emission peak of around 466nm is attributed to the typical transitions of Eu2 + from the 4f5d-4f.Eu2 +,Dy3+ co-doped Sr2MgSi2O7 displays good luminescent properties with decay time of up to more than 8hrs and has the idea energy trap of 0.76eV.
Keywords:sol-gel synthesis  long afterglow  luminescent materials  Sr2MgSi2O7
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