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电沉积法制备Co(OH)_2薄膜及其电化学性能研究
引用本文:胡中爱,付国瑞,金小青,谢莉婧,解玉龙,王耀先.电沉积法制备Co(OH)_2薄膜及其电化学性能研究[J].西北师范大学学报,2010,46(2):64-68.
作者姓名:胡中爱  付国瑞  金小青  谢莉婧  解玉龙  王耀先
作者单位:西北师范大学化学化工学院、甘肃省高分子材料重点实验室,甘肃兰州730070
基金项目:甘肃省自然科学基金资助项目,甘肃省教育厅研究生导师科研基金资助项目 
摘    要:在硝酸钴溶液中,通过电沉积在镍箔基底上制备出了Co(OH)2薄膜.用X射线衍射仪(XRD)和场发射扫描电子显微镜(FESEM)表征了产物的结构和形貌,用红外光谱(FT-IR)对所制样品的组分进行了分析,用循环伏安和恒电流充放电等测试方法对其电化学性能进行了研究.结果表明,具有均匀片状网络形貌的Co(OH)2表现出优良的电化学性能,其单电极比电容值达1042F.g-1,有望成为电化学电容器电极材料.

关 键 词:电沉积  氢氧化钴  比电容

Electrodeposition of cobalt hydroxide film and its electrochemical performances
HU Zhong-ai,FU Guo-rui,JIN Xiao-qing,XIE Li-jing,XIE Yu-long,WANG Yao-xian.Electrodeposition of cobalt hydroxide film and its electrochemical performances[J].Journal of Northwest Normal University Natural Science (Bimonthly),2010,46(2):64-68.
Authors:HU Zhong-ai  FU Guo-rui  JIN Xiao-qing  XIE Li-jing  XIE Yu-long  WANG Yao-xian
Institution:HU Zhong-ai,FU Guo-rui,JIN Xiao-qing,XIE Li-jing,XIE Yu-long,WANG Yao-xian(Key Laboratory of Polymer Materials of Gansu Province,College of Chemistry , Chemical Engineering,Northwest Normal University,Lanzhou 730070,Gansu,China)
Abstract:Cobalt hydroxide film is electrodeposited on nickel foil in Co(NO3)2 aqueous solution.The structure and morphology of Co(OH)2 film are characterized using X-ray diffraction(XRD)and field emission scanning electron microscopy(FESEM),respectively.The component of products is analyzed by FT-IR.The electrochemical performances are investigated by cyclic voltammetry and constant current charge/discharge techniques.The results show that the as-prepared materials are Co(OH)2 with a uniform sheet-like network morph...
Keywords:electrodeposition  cobalt hydroxide  specific capacitance  
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