| 氰桥配合物[Ni(Ⅱ)Ln]_2[Fe(Ⅱ)(CN)_6]的光谱研究 |
| |
| 引用本文： | 展树中,汤俊明.氰桥配合物[Ni(Ⅱ)Ln]_2[Fe(Ⅱ)(CN)_6]的光谱研究[J].河南师范大学学报(自然科学版),1993,21(2):59-61. |
| |
| 作者姓名： | 展树中 汤俊明 |
| |
| 作者单位： | 河南师范大学化学系，河南师范大学化学系，河南师范大学化学系，河南师范大学分析测试中心 |
| |
| 摘 要： | 亚铁氰化钾水溶液和NiLn]~(2+)(L=H_2dmg和tetren分别表示丁二酮肟和四乙烯五胺)溶液反应得到比较稳定的红棕色晶体。经元素分析、UV-Vis光谱和红外光谱的测试,证明它们是氰桥配合物Ni(Ⅱ)Ln-NC-Fe(Ⅱ)(CN)_4-CN-Ni(Ⅱ)Ln]。
|
| 关 键 词： | 氰桥 亚铁离子 镍离子 |
Spectroscopic Investigation of Cyanide-bridged Complexes |
| |
| Zhan Shuzhong,Gao Shulan,Niu Xinshu,Tang Junming.Spectroscopic Investigation of Cyanide-bridged Complexes[J].Journal of Henan Normal University(Natural Science),1993,21(2):59-61. |
| |
| Authors: | Zhan Shuzhong Gao Shulan Niu Xinshu Tang Junming |
| |
| Institution: | Zhan Shuzhong;Gao Shulan;Niu Xinshu;Tang Junming Department of Chemistry |
| |
| Abstract: | Two kinds of red-brown crystals are generated by mixing aqueous solutions ofNiLn]~(2+)(L=dimethylglyoxime and tetraethylene-pentamine and K_4Fe_3(CN)_4]).The products are deter-mined by elemental analysis、UV-vise spectrometry and IR spectra.It has been established that twokinds of cyanide-bridged complexesNi(Ⅱ)LnNC-Fe(Ⅱ)(CN)_4-CN-Ni(Ⅱ)Ln]are formed. |
| |
| Keywords: | cyanide-bridged ferrous ion nickel ion |
| 本文献已被 CNKI 维普 等数据库收录！ |
