| 硼氢化钠在水中对羟基(羰基)酯的还原反应研究 |
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| 引用本文： | 危彬,贾鹏昊,葛瑶,师振璞,曹锟,刘青锋,朱磊,王连明,张贵生.硼氢化钠在水中对羟基(羰基)酯的还原反应研究[J].河南师范大学学报(自然科学版),2012,40(3):82-84. |
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| 作者姓名： | 危彬 贾鹏昊 葛瑶 师振璞 曹锟 刘青锋 朱磊 王连明 张贵生 |
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| 作者单位： | 河南师范大学化学与环境科学学院,河南新乡,453007 |
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| 基金项目： | 河南省基础与前沿技术研究计划资助项目，河南师范大学(国家)大学生创新性实验计划资助项目 |
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| 摘 要： | 报道了一种羟基或羰基酯的绿色还原方法.该方法以水为溶剂,硼氢化钠在室温下还原系列羟基或羰基酯高收率生成相应的二醇化合物,具有操作简单、反应条件温和、环境友好等优点.
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| 关 键 词： | 还原 羟基酯 羟基酯水 硼氢化钠 |
Reduction of Hydroxyl (or keto) Esters with Sodium Borohydride in Water |
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| WEI Bin
,
JIA Peng-hao
,
GE Yao
,
SHI Zhen-pu
,
CAO Kun
,
LIU Qing-feng
,
ZHU Lei
,
WANG Lian-ming
,
ZHANG Gui-sheng.Reduction of Hydroxyl (or keto) Esters with Sodium Borohydride in Water[J].Journal of Henan Normal University(Natural Science),2012,40(3):82-84. |
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| Authors: | WEI Bin JIA Peng-hao GE Yao SHI Zhen-pu CAO Kun LIU Qing-feng ZHU Lei WANG Lian-ming ZHANG Gui-sheng |
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| Institution: | (College of Chemistry and Environmental Science,Henan Normal University,Xinxiang 453007,China) |
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| Abstract: | A green reduction method of hydroxyl or keto esters to diols has been developed.A series of hydroxyl or keto esters are reduced by sodium borohydride in water to give corresponding diols at rt in high yields.It has the advantages of operational simplicity,mild reaction condition,and environmental friendiness. |
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| Keywords: | reduction hydroxyl esters keto esters sodium borohydride water |
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