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石油沥青基中间相炭微球用作锂离子电池负电极时的充、放电性能与微观机制
引用本文:郑洪河,张虎成,徐仲榆.石油沥青基中间相炭微球用作锂离子电池负电极时的充、放电性能与微观机制[J].河南师范大学学报(自然科学版),2002,30(1):60-65.
作者姓名:郑洪河  张虎成  徐仲榆
作者单位:1. 河南师范大学化学与环境科学学院,河南,新乡,453002
2. 湖南大学新型炭材料研究所,湖南,长沙,410082
基金项目:河南省优秀中青年骨干教师基金资助
摘    要:将石油沥青基中间相炭微球(P-MCMB)进行热处理,采用XRD表征了经不同热处理温度(HTTmax)处理过程的P-MCMB试样的微观结构,运用恒电流充、放电法,粉末微电极循环伏安法,考察了HTTmax对P-MCMB试样充放电性能的影响,讨论了试样电化学性能与微观结构间的关系。

关 键 词:锂离子电池  负极材料  石油沥青基MCMB  充电性能  放电性能  微观机制  中间相炭微球
文章编号:1000-2367(2002)01-0060-06
修稿时间:2001年12月7日

The Electrochemical Properties and Mechanisms of Petroleum Pitch-based Meso-carbon Microbeads Used as the Negative Electrode Materials in Lithium Ion Batteries
ZHENG Hong-he ,ZHANG Hu-cheng ,XU Zhong-yu.The Electrochemical Properties and Mechanisms of Petroleum Pitch-based Meso-carbon Microbeads Used as the Negative Electrode Materials in Lithium Ion Batteries[J].Journal of Henan Normal University(Natural Science),2002,30(1):60-65.
Authors:ZHENG Hong-he  ZHANG Hu-cheng  XU Zhong-yu
Institution:ZHENG Hong-he 1,ZHANG Hu-cheng 1,XU Zhong-yu 2
Abstract:Petroleum Pitch Based Mesocarbon Microbeads (P-MCMB) were heated under different maximum heat treatment temperatures (HTT max ). The microstructures of these samples were analyzed by means of XRD techique. The charging-discharging performances of these samples were investigated by the galvanostatic charging-discharging experiments and the powder microelectrode cyclic voltametry experiments. The correlations between their electrochemical performances and the microstructures were discussed.
Keywords:lithium ion batteries  negative electrode materials  petroleum pitch based MCMB  heat-treated temperature
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