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离子交换火焰原子吸收法测定水中Cr(Ⅲ)和Cr(Ⅵ)
引用本文:高文玲,鲁彬,刘新喜.离子交换火焰原子吸收法测定水中Cr(Ⅲ)和Cr(Ⅵ)[J].河北科技大学学报,1997(4).
作者姓名:高文玲  鲁彬  刘新喜
作者单位:河北师范大学化学系
摘    要:研究了在pH=2~3的条件下,用国产001#强酸性阳离子交换树脂、201×7#强碱性阴离子交换树脂对水中Cr(Ⅲ)和Cr(Ⅵ)进行交换吸附,在Na2SO4存在下,用火焰原子吸收法直接测定交换后溶液中的Cr(Ⅵ)和Cr(Ⅲ)。方法简便易行,快速,特征质量为0.072μg/mL,相对标准偏差为2.7%,回收率为95%~106%

关 键 词:  离子交换树脂  水样分析  火焰原子吸收法

Determination of chromium (Ⅲ) and Chromium (Ⅵ) in Water by lon exchange flame Atomic Absorption Spectrometry
Abstract:The exchange absorption of Cr (Ⅲ) and Cr (Ⅵ) in water was studied with 001 strong acidic cation and 201×7 strong basic anion exchange resin.In the presance of sodium sulfate,Cr (Ⅵ) and Cr (Ⅲ) in the filtrate were directly detected.The method is simple and rapid.The sensitivity of 0.072 uglml (1% absortion),relatire standard deviation of 2.7% and recovery rate of 95%-106% are obtained respectively.
Keywords:chromium  ion exchange resin  atomic absorption spectrometry
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